| Naslov: | Porous beads from multiple emulsions with thiol-ene polymerisation : magistrsko delo |
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| Avtorji: | ID Kramer, Stanko (Avtor)
ID Krajnc, Peter (Mentor) Več o mentorju... 
ID Paljevac, Muzafera (Komentor) |
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| Datoteke: |  MAG_Kramer_Stanko_2019.pdf (3,56 MB)
MD5: C8CF8D79638D64E73927D951F2A92DE8
PID: 20.500.12556/dkum/dfecadb4-a9b0-4b3e-b914-373e0f22b768
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| Jezik: | Angleški jezik |
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| Vrsta gradiva: | Magistrsko delo/naloga |
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| Tipologija: | 2.09 - Magistrsko delo |
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| Organizacija: | FKKT - Fakulteta za kemijo in kemijsko tehnologijo
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| Opis: | This thesis aims to explain the process of porous bead synthesis. The porous beads were prepared from a multiple emulsion water-in-oil-in-water (W/OW) system. The W/O/W multiple emulsion was made up of a High Internal Phase Emulsion (HIPE (primary emulsion)) and a suspension phase. The HIPE consisted of pentaerythritol tetrakis (3 mercaptopropionate) (TT) in combination with either divinyl adipate (DVA) or trimethylolpropane triacrylate (TMPTA) and an internal phase volume fraction of 80 %. The suspension phase consisted of an aqueous phase with dissolved surfactants which stabilised the secondary emulsion. The surfactants which stabilised the secondary emulsion were polyvinylpyrrolidone K30 (PVP K30) and polyvinylpyrrolidone K90 (PVP K90).
The polymerisation was carried out thermally at first for 24 hours and later under UV light and daylight, as the thermally initiated polymerisation was unsuccessful due to coalesence. The beads that were obtained using the photoinitiated polymerisation were porous with a mostly bicontinuous structure and varying diameters. The viscosity of the primary emulsion (HIPE) had the greatest influence on the stability of the entire W/O/W emulsion. By adding more than 5 wt. % of toluene to the primary emulsion, the emulsion broke down and did not successfully polymerise. Another important factor was the ratio of the functional groups in the case of TT-co-TMPTA, which greatly affected the yield and structure of the obtained beads.
The diameters of the spherical particles were dependent on the viscosity, monomer ratio and surfactant used in the suspension phase. The inner structure of the beads was mostly bicontinuous with occasional pores that resembled a polyHIPE structure.
The obtained beads had a yield of up to 80 % in the case of TT-co-DVA and a yield of up to 90 % in the case of TMPTA-co-DVA |
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| Ključne besede: | polyHIPE, thiol-ene, suspension polymerisation, porous beads, HIPE |
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| Kraj izida: | Maribor |
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| Kraj izvedbe: | Maribor |
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| Založnik: | [S. Kramer] |
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| Leto izida: | 2019 |
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| Št. strani: | XI, 51 str. |
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| PID: | 20.500.12556/DKUM-74426 |
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| UDK: | 66.095.262(043.2) |
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| COBISS.SI-ID: | 22600982 |
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| NUK URN: | URN:SI:UM:DK:KYQKUC1P |
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| Datum objave v DKUM: | 17.09.2019 |
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| Število ogledov: | 1592 |
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| Število prenosov: | 236 |
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| Metapodatki: |    |
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| Področja: | KTFMB - FKKT
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