| Naslov: | Ammoniumbis(hydroxylammonium) pentafluoridooxidovanadate(IV) : synthesis and characterisation of a new fluorovanadate |
|---|
| Avtorji: | ID Dojer, Brina (Avtor)
ID Kristl, Matjaž (Avtor)
ID Jagličić, Zvonko (Avtor)
ID Drofenik, Mihael (Avtor)
ID Meden, Anton (Avtor) |
|---|
| Datoteke: |  Acta_Chimica_Slovenica_2008_Dojer_et_al._Ammoniumbis_(hydroxylammonium)_Pentafluoridooxidovanadate(IV)_Synthesis_and_Characterisation_of.pdf (218,95 KB)
MD5: A5EA7E29674D97E8946D32FF6A05005E
PID: 20.500.12556/dkum/86612acd-10f0-412b-ad8f-3aa058e040d3
 http://acta-arhiv.chem-soc.si/55/55-4-834.pdf
|
|---|
| Jezik: | Angleški jezik |
|---|
| Vrsta gradiva: | Znanstveno delo |
|---|
| Tipologija: | 1.01 - Izvirni znanstveni članek |
|---|
| Organizacija: | FKKT - Fakulteta za kemijo in kemijsko tehnologijo
|
|---|
| Opis: | Turquoise crystals of a new hydroxylammonium compound with the formula $NH_4(NH_3OH)_2[VOF_5]$ have been synthesized by the reaction of solid $NH_3OHF$ and the aqueous solution of vanadium in HF. The compound crystallizes monoclinic, $P2_1/n$, with cell parameters: a = 10.5658(2) Å, b = 6.6143(1) Å, c = 11.6618(2) Å, β = 96.282(1). Magnetic susceptibility was measured using a SQUID device over a temperature range 2–300 K at magnetic field $10^3 Oe$ giving the result $µ_{eff}$ = 1.65 BM. The thermal decomposition was studied by TG and DSC analysis. $NH_4(NH_3OH)_2[OF_5V]$ decomposes above 354 K in three steps, obtaining $NH_4VOF_3$ after the first step and $V_2O_5$ as the final residue. |
|---|
| Ključne besede: | hydroxylammonium fluorovanadates, x-ray powder diffraction, x-ray structure determination, thermal analysis |
|---|
| Status publikacije: | Objavljeno |
|---|
| Verzija publikacije: | Objavljena publikacija |
|---|
| Leto izida: | 2008 |
|---|
| Št. strani: | str. 834-840 |
|---|
| Številčenje: | Letn. 55, št. 4 |
|---|
| PID: | 20.500.12556/DKUM-67417  |
|---|
| ISSN: | 1318-0207 |
|---|
| UDK: | 546.881.022.057:543.442.3:543.57 |
|---|
| COBISS.SI-ID: | 30084101 |
|---|
| ISSN pri članku: | 1318-0207 |
|---|
| NUK URN: | URN:SI:UM:DK:LDDRZRBV |
|---|
| Datum objave v DKUM: | 17.08.2017 |
|---|
| Število ogledov: | 1850 |
|---|
| Število prenosov: | 112 |
|---|
| Metapodatki: |    |
|---|
| Področja: | Ostalo
|
|---|
|
:
|
Kopiraj citat |
|---|
| | | | Skupna ocena: | (0 glasov) |
|---|
| Vaša ocena: | Ocenjevanje je dovoljeno samo prijavljenim uporabnikom. |
|---|
| Objavi na: |  |
|---|
Postavite miškin kazalec na naslov za izpis povzetka. Klik na naslov izpiše
podrobnosti ali sproži prenos. |
