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Title:ODSTRANJEVANJE ARZENA IN KROMA IZ VODE Z MAGHEMITNIMI NANOSTRUKTURAMI
Authors:Jančič, Urška (Author)
Simonič, Marjana (Mentor) More about this mentor... New window
Ban, Irena (Co-mentor)
Files:.pdf UNI_Jancic_Urska_2014.pdf (4,19 MB)
 
Language:Slovenian
Work type:Bachelor thesis/paper (mb11)
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Engineering
Abstract:Namen diplomskega dela je bil s topotaktično transformacijo lepidokrokita sintetizirati dvodimenzionalne magnetne maghemitne nanostrukture, jih okarakterizirati z XRD in BET metodo ter preučiti njihovo uporabo za adsorpcijo As(III) in Cr(VI) ionov iz vode. Pripravljene maghemitne nanostrukture smo suspendirali v vodi z znano koncentracijo As(III) in Cr(VI) ionov. S spreminjanjem različnih eksperimentalnih parametrov (mase adsorbenta, pH, časa, koncentracije As(III) in Cr(VI) ionov) smo ugotavljali učinkovitost maghemitnega nanoadsorbenta za odstranjevanje As(III) in Cr(VI) ionov iz vode. Rezultati kažejo, da smo uspešno sintetizirali maghemitne nanostrukture, katerih BET površina je 118,79 m2/g, volumen por 0,258 cm3/g in povprečni premer por 8,684 nm. Pripravljeni maghemitni nanoadsorbent ima zelo dobre adsorpcijske sposobnosti za odstranjevanje As(III) ionov, manj primeren je za odstranjevanje Cr(VI) ionov. Adsorpcija poteka hitro, pri optimalnih pogojih se ravnotežje vzpostavi že po 20 minutah in takrat je učinkovitost adsorpcije As(III) ionov najmanj 90 %. Zaradi magnetnih lastnosti adsorbenta je možna tudi njegova ponovna uporaba.
Keywords:arzen, krom, maghemitne nanostrukture, adsorpcija, nanomateriali, čiščenje vode
Year of publishing:2014
Publisher:[U. Jančič]
Source:Maribor
UDC:628.161.3(043.2)
COBISS_ID:18219798 Link is opened in a new window
NUK URN:URN:SI:UM:DK:IJU7CSRE
Views:1142
Downloads:229
Metadata:XML RDF-CHPDL DC-XML DC-RDF
Categories:KTFMB - FKKT
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Secondary language

Language:English
Title:REMOVAL OF ARSENIC AND CHROMIUM FROM WATER BY MAGHEMITE NANOSHEETS
Abstract:The purpose of the diploma was the synthesis of two-dimensional magnetic maghemite nanostructures in the form of nanosheeets by topotactic transformation, characterization of nanosheets by XRD and BET method and the investigation of potential applications of maghemite nanosheets for adsorption of As(III) and Cr(VI) ions from water. Prepared maghemite nanosheets were suspended in water with a known concentration of As(III) and Cr(VI) ions. By changing various experimental parameters (time, weight of the adsorbent, pH, concentration of As(III) and Cr(VI) ions) we determine the effectiveness of maghemite nanosheests to remove As(III) and Cr(VI) ions from water. The results show that we have successfully synthesized maghemite nanoadsorbent with BET surface area 118.79 m2/g, a pore volume 0.258 cm3/g and an average pore diameter 8.684 nm. Prepared maghemite nanosheets have a very good adsorption capacity for removal of As (III) ions, but are less suitable for removal of Cr (VI) ions. Adsorption is fast and under optimal conditions the equilibrium is established after 20 minutes with adsorption efficiency at least 90 % for As(III) ions. It is also possible to reuse adsorbent, because of its magnetic properties.
Keywords:arsenic, chromium, maghemite nanosheets, adsorption, nanomaterials, water purification


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