Naslov: | Donnan equilibrium and osmotic pressure in hollow polyelectrolyte microcapsules |
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Avtorji: | ID Haložan, David (Avtor) ID Sukhorukov, Gleb B. (Avtor) ID Brumen, Milan (Avtor) ID Donath, Edwin (Avtor) ID Möhwald, Helmuth (Avtor) |
Datoteke: | Acta_Chimica_Slovenica_2007_Halozan_et_al._Donnan_equilibrium_and_osmotic_pressure_in_hollow_polyelectrolyte_microcapsules.pdf (141,11 KB) MD5: 43520345193951020000991C8A572F91 PID: 20.500.12556/dkum/a1afab03-3987-4f5f-a5c3-b7fc0bca8c7a
http://acta-arhiv.chem-soc.si/54/54-3-598.pdf
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Jezik: | Angleški jezik |
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Vrsta gradiva: | Znanstveno delo |
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Tipologija: | 1.01 - Izvirni znanstveni članek |
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Organizacija: | FNM - Fakulteta za naravoslovje in matematiko
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Opis: | A simple theoretical model of the Donnan equilibrium is applied to studies of distributions of ions between the external and internal volumes of hollow polyelectrolyte capsules as well as of concomitant osmotic pressure load on a capsule wall resulting from these distributions and the presence of polyanion. The model system consist of dispersed polyelectrolyte capsules in an electrolyte solution whereby two cases are considered with respect to the presence of the polyanion, either in the inner or external solution. It is assumed that the capsule wall is impermeable to polyanion, but water and all ions can freely penetrate. The model predictions are summarized by presenting the difference between the external pH, the pH of the inner solution and the osmotic pressure difference across the capsule wall, both in the dependence of sodium chloride concentration. |
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Ključne besede: | biophysics, polyelectrolytes, polyelectrolyte capsules, Donnan equilibrium, osmotic pressure |
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Status publikacije: | Objavljeno |
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Verzija publikacije: | Objavljena publikacija |
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Leto izida: | 2007 |
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Št. strani: | str. 598-604 |
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Številčenje: | Letn. 54, št. 3 |
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PID: | 20.500.12556/DKUM-35857  |
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UDK: | 577 |
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COBISS.SI-ID: | 15589128  |
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ISSN pri članku: | 1318-0207 |
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NUK URN: | URN:SI:UM:DK:XFRVXKJU |
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Datum objave v DKUM: | 07.06.2012 |
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Število ogledov: | 2176 |
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Število prenosov: | 134 |
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Metapodatki: |  |
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Področja: | Ostalo
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