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Naslov:Calculation of thermophysical and thermochemical properties during hydrocarbon combustion
Avtorji:Avsec, Jurij (Avtor)
Zgaga, Franc (Avtor)
Marčič, Milan (Avtor)
Datoteke:URL http://www.hthpweb.com/php/onlineaccess.phtml?jrnid=ht&page=paper&paperid=844&year=2002&issue=5&fpage=569&lpage=583
 
Jezik:Angleški jezik
Vrsta gradiva:Neznano ()
Tipologija:1.01 - Izvirni znanstveni članek
Organizacija:FS - Fakulteta za strojništvo
Opis:A mathematical model is presented for computing the chemical and thermophysical properties in the process of combustion of natural gas. To identify the parameters of state of combustion products, their composition hasto be known, which may be determined from chemical equilibrium. The computation is performed with the use of chemical potentials and statistical thermodynamics, featuring all important molecular contributions (translation, rotation, vibration, and intermolecular potential energy). A thermal equation of state with two virial terms is used. The real gas mixture is treated as consisting of four components: carbon dioxide, nitrogen, carbon monoxide, and water. Virial coefficients are dependent on temperature and mole fractions of the real components. Mixed terms are taken into account. The caloric equation of state is based on statistical thermodynamics for an ideal gas. Corrections are made in accordance with the second law of thermodynamics and the thermal equation of state. As the whole computation is based on matrix algebra, increasing the number of components presents no problems. We tested our model in the high-pressure region (100 bar) and the low-pressure region (1 bar), in the temperature range 500 - 6000°K. Our model is compared with other analytical models presented in the literature and shows relatively good agreement. At the same time we tested the influence of real conditions on the chemical and thermophysical properties of combustion products.
Ključne besede:statistical thermodynamics, thermodynamical properties, combustion of natural gas, mathematical models, thermodynamic functions of state, equation of state, virial coefficients
Leto izida:2002
UDK:536.75:66
COBISS_ID:7840790 Novo okno
ISSN pri članku:0018-1544
NUK URN:URN:SI:UM:DK:LQHBENWB
Število ogledov:1550
Število prenosov:104
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Področja:Ostalo
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Gradivo je del revije

Naslov:High Temperatures. High Pressures
Skrajšan naslov:High temp. High press.
Založnik:Pion Limited
ISSN:0018-1544
COBISS.SI-ID:25557504 Novo okno

Sekundarni jezik

Jezik:Angleški jezik
Ključne besede:statistična termodinamika, termofizikalne lastnosti, zgorevanje zemeljskega plina, matematični modeli, termodinamične lastnosti stanja, enačba stanja, virialni koeficienti


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