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Title:Phase equilibira of permethrin and dicofol with carbon dioxide
Authors:ID Kotnik, Petra (Author)
ID Perva, Amra (Author)
ID Škerget, Mojca (Author)
ID Knez, Željko (Author)
Files:URL http://dx.doi.org/10.1021/je0495379
Work type:Unknown
Typology:1.01 - Original Scientific Article
Organization:FKKT - Faculty of Chemistry and Chemical Engineering
Abstract:The solubilities of pesticides (permethrin and dicofol) in CO2 were measured by a static-analytic method at pressures ranging from 10.0 MPa to 25.0 MPa andtemperatures of 293.2 K, 303.2 K, and 313.2 K. Due to the nonconventional shape of some solubility isotherms, solid-liquid transitions of pesticides under pressure of CO2 were determined using a modified capillary method. Sincethe solubilities depend on solvent density, the experimental binary solid-fluid equilibrium data were correlated as a function of solvent density by two different models.
Keywords:chemical processing, high pressure technology, CO2, pesticides, phase equilibria, solubility
Year of publishing:2005
PID:20.500.12556/DKUM-27082 New window
ISSN on article:0021-9568
COBISS.SI-ID:10027798 New window
Publication date in DKUM:01.06.2012
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Record is a part of a journal

Title:Journal of chemical and engineering data
Shortened title:J. chem. eng. data
Publisher:American Chemical Society
COBISS.SI-ID:25714944 New window

Secondary language

Keywords:kemijska procesna tehnika, visokotlačna tehnologija, CO2, pesticidi, fazna ravnotežja, topnost


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