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DKUM
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Title:
Atrazine removal by covalent bonding to piperazine functionalized PolyHIPEs
Authors:
ID
Pulko, Irena
(Author)
ID
Kolar, Mitja
(Author)
ID
Krajnc, Peter
(Author)
Files:
http://dx.doi.org/10.1016/j.scitotenv.2007.06.032
Language:
English
Work type:
Unknown
Typology:
1.01 - Original Scientific Article
Organization:
FKKT - Faculty of Chemistry and Chemical Engineering
Abstract:
The removal of atrazine from water by a solid phase extraction technique usinginsoluble polymers is described. Porous crosslinked polymers bearing piperazine moieties were prepared in a one step reaction from the precursor 4-nitrophenylacrylate incorporating polymers (PolyHIPE type prepared by the polymerization of the continuous phase of a high internal phase emulsion and polymer beads prepared by suspension polymerization). Polymers were applied tosequester atrazine from aqueous solutions with a concentration of 33 ppb andirreversible covalent bonding to the polymers was achieved. GC/MS/MS was used to monitor the dynamics of atrazine uptake and it was found that almost complete removal of atrazine was acomplished with an excess of polymer after 48 hours at room temperature. For comparison, polymer beads of identical chemistry but lower porosity were also used and showed significantly slower action (near complete removal after 72 hours).
Keywords:
polymer supports
,
polymer scavengers
,
monoliths
,
emulsion polymerisation
,
solid-phase synthesis
Year of publishing:
2007
PID:
20.500.12556/DKUM-25952
UDC:
547:678
ISSN on article:
0048-9697
COBISS.SI-ID:
11508246
NUK URN:
URN:SI:UM:DK:S8GFDVNS
Publication date in DKUM:
31.05.2012
Views:
2624
Downloads:
104
Metadata:
Categories:
Misc.
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Record is a part of a journal
Title:
Science of the total environment
Shortened title:
Sci. total environ.
Publisher:
Elsevier
ISSN:
0048-9697
COBISS.SI-ID:
26369024
Secondary language
Language:
English
Keywords:
polimerni nosilci
,
polimerni lovilci
,
monolitni polimeri
,
emulzijska polimerizacija
,
sinteza na trdni fazi
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