| Naslov: | The lipase-catalyzed synthesis of fatty acid fructose esters in organic media and in supercritical carbon dioxide |
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| Avtorji: | ID Šabeder, Saša (Avtor)
ID Leitgeb, Maja (Avtor)
ID Knez, Željko (Avtor) |
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| Datoteke: |  Chemical_Industry_and_Chemical_Engineering_Quarterly_2006_Sabeder,_Habulin,_Knez_The_lipase-catalyzed_synthesis_of_fatty_acid_fructose_e.pdf (392,53 KB)
MD5: 7761DB2C8B979BFF4C1BB5A4D2C63CB4
PID: 20.500.12556/dkum/2cbe105e-5633-4919-85d8-e5ed511c8cf3
 http://www.doiserbia.nb.rs/Article.aspx?ID=1451-93720603147S
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| Jezik: | Angleški jezik |
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| Vrsta gradiva: | Znanstveno delo |
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| Tipologija: | 1.01 - Izvirni znanstveni članek |
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| Organizacija: | FKKT - Fakulteta za kemijo in kemijsko tehnologijo
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| Opis: | Sugar fatty acid esters are biodegradable surface active compounds in foodstuffs and cosmetics or pharmaceuticals. They have potential in replacing pollutant chemically synthesized surfactants. The enzymatic synthesis of fructose palmitate catalyzed by Candida antarctica B lipase was performed in different organic media in a batch react at atmospheric pressure. The influence of the organic solvent and temperature on the esterification was studied. Since supercritical carbon dioxide (SC CO2) has several advantages over organic solvents, such as high reaction rate, high mass transfer, non-toxicity, non flammability and low price, it was also chosen as a reaction medium for fructose palmitate production. The influence of temperature on immobilized lipase activity was studied at 10 MPa and the results were compared to the results obtained from reactions performed at atmospheric pressure under the same reaction conditions. The highest conversion (67%) was obtained after 24 hours of reaction in SC C02 at 80°C. A change of the particle size distribution and morphology of the untreated lipase and lipase treated with 2-methyl 2-butanol and SC C02 was observed.
This article was presented at 1st SEECChE, held in Belgrade, September 25-28, 2005 |
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| Ključne besede: | chemical processing, high pressure technology, supercritical CO2, lipase catalyzed syntheses, esterification, fructose palmitate, biocatalysts, lipase, Candida antarctica B |
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| Status publikacije: | Objavljeno |
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| Verzija publikacije: | Objavljena publikacija |
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| Leto izida: | 2006 |
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| Št. strani: | str. 147-151 |
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| Številčenje: | Letn. 12, št. 3 |
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| PID: | 20.500.12556/DKUM-25756  |
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| ISSN: | 1451-9372 |
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| UDK: | 66.091-987 |
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| COBISS.SI-ID: | 10667030 |
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| DOI: | 10.2298/CICEQ0603147S |
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| ISSN pri članku: | 1451-9372 |
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| NUK URN: | URN:SI:UM:DK:1HESMBSR |
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| Datum objave v DKUM: | 31.05.2012 |
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| Število ogledov: | 2712 |
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| Število prenosov: | 522 |
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| Metapodatki: |    |
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| Področja: | Ostalo
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