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A rational design of isoindigo-based conjugated microporous n-type semiconductors for high electron mobility and conductivity
Kayaramkodath C. Ranjeesh, Ayman Rezk, Jose Ignacio Martinez, Safa Gaber, Areej Merhi, Tina Škorjanc, Matjaž Finšgar, Gisha Elizabeth Luckachan, Ali Trabolsi, Bilal R. Kaafarani, 2023, izvirni znanstveni članek

Opis: The development of n-type organic semiconductors has evolved significantly slower in comparison to that of p-type organic semiconductors mainly due to the lack of electron-deficient building blocks with stability and processability. However, to realize a variety of organic optoelectronic devices, high-performance n-type polymer semiconductors are essential. Herein, conjugated microporous polymers (CMPs) comprising isoindigo acceptor units linked to benzene or pyrene donor units (BI and PI) showing n-type semiconducting behavior are reported. In addition, considering the challenges of deposition of a continuous and homogeneous thin film of CMPs for accurate Hall measurements, a plasma-assisted fabrication technique is developed to yield uniform thin films. The fully conjugated 2D networks in PI- and BI-CMP films display high electron mobility of 6.6 and 3.5 cm2 V−1 s−1, respectively. The higher carrier concentration in PI results in high conductivity (5.3 mS cm−1). Both experimental and computational studies are adequately combined to investigate structure–property relations for this intriguing class of materials in the context of organic electronics.
Ključne besede: conjugated microporous polymers, isoindigo, semiconductors, conductivity, electron mobility
Objavljeno v DKUM: 03.04.2024; Ogledov: 219; Prenosov: 15
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A Survey on the State-of-the-Art and Future Trends of Multilevel Inverters in BEVs
Alenka Hren, Mitja Truntič, Franc Mihalič, 2023, pregledni znanstveni članek

Opis: All electric vehicles are the only way to decarbonize transport quickly and substantially. Although multilevel inverters have already been used in some transportation modes, they are rarely used in road transportation, especially in light-duty passenger BEVs. With the transition to a high 800-V DC link to extend the driving range and enable extreme fast charging, the possibility of using multilevel inverters in commercial light-duty passenger BEVs becomes feasible. Higher efficiency, higher power density, better waveform quality, lower switching frequency, the possibility of using low-rated switches, and inherent fault tolerance are known advantages of multilevel inverters that make them an efficient option for replacing 2-level inverters in high DC link passenger BEVs. This paper discusses high DC link voltage benefits in light-duty passenger BEVs, presents the state-of-the-art of different conventional multilevel inverter topologies used in BEVs, and compares them with conventional 2-level inverters from different aspects and limitations. Based on commercial upper-class passengers’ BEV data and a review of multilevel inverters on the market, future trends and possible research areas are identified.
Ključne besede: multilevel inverters, MLI, electric vehicle, EV, passengers’ battery electric vehicle, BEV, extreme fast charging, XFC, higher voltage batteries, WBG semiconductors
Objavljeno v DKUM: 26.03.2024; Ogledov: 273; Prenosov: 25
Celotno besedilo (2,07 MB)
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