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1.
X-ray study of pre-treated regenerated cellulose fibres
Majda Sfiligoj-Smole, Zdenka Peršin, Tatjana Kreže, Karin Stana-Kleinschek, Volker Ribitsch, Susanne Neumayer, 2003, izvirni znanstveni članek

Opis: Regenerated cellulose fibres have had an important role to play in the man-made fibre field. The very special characteristics of different types of regenerated cellulose fibres, e.g. mechanical properties, sorption characteristics, and aesthetics were conditioned by the differences in their fine structure due to fibre formation processes. Additionally, the finishing processes could influence the fibre structure. A study was done of the crystalline structures of a solvent-spun cellulose fibre type (Lenzing Lyocell), made according to the NMMO process, and two conventional cellulosic fibre types, made by the viscose process (Lenzing Viscose and Lenzing Modal). The fibres were pre-treated (bleached and slack mercerised) and structural changes were followed by wide angle and small angle x-ray scattering (WAXS and SAXS), respectively. The periodical structure, determined by long spacing, was nearly the same in all the different types of fibres. A slight increase was observed after the treatment of viscose and modal fibres, but an unpronounced fall of a long period accompanied the pre-treatment of lyocell fibres. Some changes in crystallinity and crystalline orientation occurred due to the treatment conditions. The structural changes were correlated to the iodinesorption and mechanical properties.
Ključne besede: regenerated cellulose fibres, fibre structure, fibre properties, x-ray analysis, WAXS, SAXS, cellulose pre-treatment
Objavljeno: 01.06.2012; Ogledov: 1341; Prenosov: 55
URL Povezava na celotno besedilo

2.
Antimicrobial medical textiles based on chitosan nanoparticles for gynaecological treatment
Tijana Ristić, 2014, doktorska disertacija

Opis: The aim of this dissertation was to develop a novel medical tampon for alternative gynaecological treatment using chitosan nanoparticles as an antimicrobial agent or as a drug delivery system. For this purpose viscose tampon band was used and functionalized with chitosan and trimethyl chitosan nanoparticles. A comprehensive of interactions between chitosan and cellulose as well as characterization of prepared materials were done. At the beginning, chitosan (CS) and trimethyl chitosan (TMC) solutions, as well as nanoparticles synthesised by ionic gelation were studied. Their characterization was focused on determining the charge and antimicrobial properties against common pathogenic microorganism. The influence of cationic charge on the inhibition of microbial growth was confirmed. Since CS and TMC solutions and nanoparticles dispersions exhibited antibacterial activity against Lactobacillus, a detailed investigation in chitosan’s antimicrobial mode of action was performed using a novel diffusion nuclear magnetic resonance (D-NMR). D-NMR allowed the monitoring of intra- and extracellular water exchange from the cells indicating the membrane alteration and leakage of intracellular constituencies. Further, in order to study the adsorption phenomena and molecular interactions between CS/TMC (solution or nanoparticles) and cellulose material, model cellulose surfaces were used, and adsorption was studied by quartz crystal microbalance with dissipation. CS and TMC were favourably deposited onto cellulose model surface at higher ionic strength, higher pH values, i.e. factors causing lower solubility, where the presence of electrostatic interactions was negligible and non-electrostatic interactions were dominant. The knowledge gained from the model surfaces was extremely helpful in characterization of real systems, i.e. functionalized cellulose fibres and for understanding the obtained results. Immobilization of CS and TMC (in the form of solution and/or nanoparticles) onto cellulose viscose fibres was confirmed with several analytical methods. The attachment of chitosan onto fibres was reversible, as endorsed with desorption studies mimicking the conditions of vaginal usage. Evaluation of antimicrobial properties was performed using two different techniques, both revealing a high inhibition of the tested microorganism. In addition, Lactobacillus susceptibility testing has shown that chitosan-coated fibres do not have any negative influence on the resident microbiota. Assessment of in-vitro cytotoxicity demonstrated that samples do not cause a cytotoxic effect in direct contact. Additionally, model drug was incorporated into chitosan nanoparticles and subsequently attached onto fibres in order to create modern, vaginal drug delivery systems. Antimicrobial medical textiles investigated in the scope of this dissertation show the potential for their exploitation in gynaecological field as preventive or curative treatment without triggering any adverse effects for the user.
Ključne besede: chitosan, N, N, N-trimethyl chitosan, nanoparticles, antimicrobial activity, cellulose model films, regenerated cellulose fibres, diffusion nuclear magnetic resonance, quartz crystal microbalance, vaginal infections, drug delivery systems, cytotoxicity
Objavljeno: 13.02.2014; Ogledov: 2192; Prenosov: 94
URL Povezava na celotno besedilo

3.
Hydrophilic/hydrophobic characteristics of different cellulose fibres monitored by tensiometry
Zdenka Peršin, Karin Stana-Kleinschek, Tatjana Kreže, 2002, izvirni znanstveni članek

Opis: Wettability and sorptivity improvements for different textile materials are the major tasks during textile finishing. In order to improve the sorption characteristics of a cellulose fabric, different pre-treatment processes are applied, usually washing, bleaching and mecerisation. Differences in the sorption properties of untreated and pretreated (washed and bleached) regenerated cellulose fibres were obtained using tensiometry and compared with the classical method for determining moisture adsorption. Results show that compared to raw fibres, viscose fibres have the highest moisture and the smallest contact angle whilst modal fibres have the biggest contact angle. Pretreatment increases the sorption abilities and makes the material more accessible to chemicals used in the finishing process. Using the conventional method, it can be confirmed that fibres with the highest moisture have the smallest contact angle (tensiometry).
Ključne besede: textile materials, regenerated cellulose fibres, sorption, pretreatment, tensiometry
Objavljeno: 05.07.2017; Ogledov: 361; Prenosov: 68
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