1. Impact of grassland management system intensity on composition of functional groups and soil chemical properties in semi-natural grasslandsUrška Lisec, Maja Prevolnik Povše, Miran Podvršnik, Branko Kramberger, 2025, original scientific article Abstract: Semi-natural grasslands are some of the most species-rich habitats in Europe and provide important ecosystem services such as biodiversity conservation, carbon sequestration and soil fertility maintenance. This study investigates how different intensities of grassland management affect the composition of functional groups and soil chemical properties. Five grassland management systems were analyzed: Cut3—three cuts per year; LGI—low grazing intensity; CG—combined cutting and grazing; Cut4—four cuts per year; and HGI—high grazing intensity. The functional groups assessed were grasses, legumes and forbs, while soil samples from three depths (0–10, 10–20 and 20–30 cm) were analyzed for their chemical properties (soil organic carbon—SOC; soil total nitrogen—STN; inorganic soil carbon—SIC; soil organic matter—SOM; potassium oxide—K2O; phosphorus pentoxide—P2O5; C/N ratio; and pH) and physical properties (volumetric soil water content—VWC; bulk density—BD; and porosity—POR). The results showed that less intensive systems had a higher proportion of legumes, while species diversity, as measured via the Shannon index, was the highest in the Cut4 system. The CG system tended to have the highest SOC and STN at a 0–10 cm depth, with a similar trend observed for SOCstock at a 0–30 cm depth. The Cut4, HGI and CG systems also had an increased STNstock. Both grazing systems had the highest P2O5 content. A tendency towards a higher BD was observed in the top 10 cm of soil in the more intensive systems. Choosing a management strategy that is tailored to local climate and site conditions is crucial for maintaining grassland stability, enhancing carbon sequestration and promoting long-term sustainability in the context of climate change. Keywords: grassland biodiversity, management intensity, composition of functional groups, soil chemical and physical properties, carbon and nitrogen storage, soil C:N ratio, sustainability Published in DKUM: 13.10.2025; Views: 0; Downloads: 8
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2. Cu(II) and Ni(II) adsorption on torrefied wood waste biomassMarjana Simonič, Darko Goričanec, Aleksandra Petrovič, Ilda Silić, Danijela Urbancl, 2025, original scientific article Abstract: The aim of the research was to study the torrefaction processes of wood biomass, compare the product characteristics at different torrefaction temperatures, and assess both moisture adsorption on raw and torrefied samples, as well as metal (Cu(II) and Ni(II)) adsorption on torrefied biomass. The novelty of the research was to investigate whether the presence of adsorbed metals in torrefied biomass significantly affects the energetic properties of the torrefied biomass, compared to torrefied biomass without metals. First, wood samples were torrefied at temperatures of 250 °C, 350 °C, and 400 °C. Following torrefaction, thermogravimetric analysis (TGA) was performed to evaluate mass loss and thermal stability. Next, changes in surface functional groups were examined, and higher heating values (HHV) were measured to assess the energy content. The results showed that torrefaction significantly increased the hydrophobicity of the biomass, leading to reduced moisture adsorption and enhanced material properties. Additionally, the adsorption of Cu(II) and Ni(II) ions on torrefied biomass was investigated. The results showed that the adsorption efficiency for Cu(II) was higher, reaching 62.4%, compared to Ni(II) at 21.2%. The adsorption process followed a pseudo-second-order kinetic model, which indicated that chemisorption was the dominant mechanism. Keywords: adsorption, torrefication, nitrogen atmosphere, metals Published in DKUM: 12.03.2025; Views: 0; Downloads: 6
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3. Gas sensing system based on an all-fiber photothermal microcellMatej Njegovec, Jure Javornik, Simon Pevec, Vedran Budinski, Tomaž Gregorec, Benjamin Lang, Manuel Tanzer, Alexander Bergmann, Denis Đonlagić, 2024, original scientific article Abstract: This article presents an all-fiber, miniature Fabry-Perot gas sensor based on photothermal absorption spectroscopy with a custom-made and cost-efficient interrogation system. The sensing gas microcell has a diameter of 125 μ m and a length of 1 mm, and allows for free gas exchange within the optical resonator through micromachined slits. High light intensity and confinement are ensured by delivering the excitation light directly into the gas microcell through a lead-in single-mode fiber. This enhances the photothermal effect and provides a short system response time. The interrogation system utilizes the modulation of an excitation laser diode with a fixed frequency while locking the probe laser onto the gas microcell’s quadrature point (QP) and observing the variations of the reflected optical power. To show the potential of the proposed system, nitrogen dioxide (NO2 was measured in dry air. Thereby, a limit of detection of 20 ppm could be achieved for 10 s integration time. Furthermore, the small dimensions of the sensor allow for improved dynamic performance with photothermal modulation frequencies as high as 7 kHz. Keywords: Fabry–Perot interferometer, FPI, fiber gas cell, fiber gas sensor, nitrogen dioxide, NO2, photothermal effect Published in DKUM: 29.08.2024; Views: 96; Downloads: 25
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4. Yield performance and agronomic efficiency in oil pumpkins (Cucurbita pepo L. group Pepo) depending on production systems and varietiesManfred Jakop, Silva Grobelnik Mlakar, Martina Bavec, Martina Robačer, Tjaša Vukmanič, Urška Lisec, Franc Bavec, 2017, original scientific article Abstract: In 2013 and 2014, a long-term trial (which was established in 2007) was conducted at the University Agricultural Centre in Pivola near Hoče. It included different production systems (conventional, integrated, organic, biodynamic), carried out in a field trial with oil pumpkins. The aim of the research was to analyse the effects of different production systems, varieties (hybrid and population variety) and years of production, on formation of oil pumpkin yields. The agricultural practice has been carried out in accordance with the applicable legislations and standards for the individual production system. When sowing, before fertilizing with nitrogen in early June and after the harvest, the amount of soil mineral nitrogen was monitored. We evaluated the number and weight of harvestable, unripe and decayed fruits, and yield of oil seed pumpkins and calculated the agronomic efficiency of the applied nutrients. The results showed that the year of production, the production system and the variety have a significant effect on some fruit characteristics and the yield of oil pumpkin seeds. The content of soil mineral nitrogen in May and September was significantly influenced by the production system and the year. In June, only the production system had a significant effect. The hybrid significantly increased the yields of oil pumpkin seeds in all production systems, even in the year that was less suitable for production. The agronomic efficiency of the applied nutrients in the biodynamic and organic production system is higher or equal than in the conventional production system, similarly, agronomic efficiency is higher in the hybrid compared to the oldest population variety efficiently. A comparable oil pumpkin yield can be expected in biodynamic and organic production, when proper nutrition and well carried out cultivation practices are combined with a new variety, when compared to less sustainable production systems, which often cause damage to the environment. Keywords: production systems, variety, oil pumkins, mineral nitrogen, agronomic efficiency, yield Published in DKUM: 10.10.2018; Views: 2139; Downloads: 417
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5. Sweet maize growth and yield response to organic and mineral fertilizers, N rates and soil water regimesFranc Bavec, Martina Bavec, Silva Grobelnik Mlakar, Milojka Fekonja, 2015, original scientific article Abstract: Sweet maize is an underutilized vegetable in European temperate areas, and its consumption is increasing. For better understanding of cultivation practices, this pot experiment aimed to determine the effects of different water regimes and nitrogen (N) rates calculated from N target values. N rates of 0 (control), 0.6 and 2 g N pot$^{-1}$ were applied as organic by-products pumpkin cake and pig manure digestate, and mineral fertilizers CAN 27 and ENTEC®26. Treatments of water supply were based on measured soil matric potentials of 2.8 pF (drought stress), 2.6 pF (optimal water) and 2.4 pF (overwatered). In comparison to mineral fertilizers, pumpkin cake proved to be equal in effectiveness in plant height (155.8 cm), cob (85.8 g), green (124.9 g) and leaf mass per plant (44.2 g), or even better in root (72.3 g) and broom mass per plant (3.0 g). Yield parameters, cob mass (70.1 g), its length (6.3 cm) and diameter (2.0 cm), as well as the residual mineral N (59 mg N kg$^{-1}$) significantly increased at the highest N rate. Significantly lower values of the evaluated morphological parameters and photosynthetic rates (at brooming and harvesting) were associated with drought stress. The matric tension of 2.6 pF was established as an appropriate water regime for sweet maize growth. Keywords: Zea mays L. saccharata Sturt., nitrogen, fertilizers, soil water potential, growth conditions Published in DKUM: 14.11.2017; Views: 2148; Downloads: 636
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6. Modification of PET-polymer surface by nitrogen plasmaRok Zaplotnik, Metod Kolar, Aleš Doliška, Karin Stana-Kleinschek, 2011, original scientific article Abstract: Low pressure weakly nitrogen plasma was applied for incorporation of nitrogen-containing functional groups onto poly(ethylene terephthalate) - PET polymer. Nitrogen plasma was created in an electrode-less radiofrequency discharge at the nominal power of 200 W and the frequency of 27.12 MHz. Nitrogen molecules entered the discharge region were highly excited, partially dissociated and weakly ionized. Transformation into the state of plasma allowed for creation of chemically reactive particles with a high potential energy while the kinetic energy remained close to the value typical for room temperature. The chemical reactivity allowed for rapid functionalization with nitrogen-rich functional groups. The appearance of these groups was monitored by X-ray photoelectron spectroscopy - XPS. The polymer surface was quickly saturated with nitrogen indicating that the modification was limited to an extremely thin surface film. Keywords: poly(ethylene terephthalate), nitrogen plasma, surface modification, functional groups, X-ray photoelectron spectroscopy Published in DKUM: 17.03.2017; Views: 1358; Downloads: 169
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7. The effect of nitrogen-ion implantation on the corrosion resistance of titanium in comparison with oxygen- and argon-ion implantationsT. Sundararajan, Zdravko Praunseis, 2004, original scientific article Abstract: Commercially pure (CP) titanium was surface modified with nitrogen-, argon- and oxygen-ion implantations in order to investigate the material's corrosion resistance in a simulated body fluid. Five doses were chosen for the ions, ranging from 5.1015 cm-2 to 2.5-1017 cm-2. In-vitro open-cyclic potential-timemeasurements and cyclic polarization studies were carried out to evaluate the corrosion resistance of the modified surface in comparison to an unmodified surface. Specimens implanted at 4.1016 cm-2 and 7.1016 cm-2 showed the optimum corrosion resistance, higher doses showed a detrimental effect on the corrosion resistance. Argon- and oxygen-ion implantation at these doses did not show any improved corrosion resistance, indicating the beneficial role of nitrogen on the corrosion resistance of titanium in the simulated body-fluid environment. Grazing-incidence X-ray diffraction (GIXD) was employed on the implanted specimens to determine the phases formed with the increasing doses. X-ray photoelectron spectroscopy (XPS) studies on the passive film of the implanted samples and on the unimplanted samples were analyzed in order to understand the role of nitrogen in improving the corrosion resistance. The results of the present investigation indicated that nitrogen-ion implantation can be used as a viable method for improving the corrosion resistance of titanium. The nature of the surface and the reason for the variation and the improvement in the corrosion resistance are discussed in detail. Keywords: metallurgy, ion implantation, orthopedic implants, corrosion, titanium, nitrogen, oxygen, argon Published in DKUM: 10.07.2015; Views: 2531; Downloads: 103
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8. UV N2 laser ablation of a Cu-Sn-Zn-Pb alloy: microstructure and topography studied by focused ion beamFranc Zupanič, Tonica Bončina, Davor Pipić, Višnja Henč-Bartolič, 2008, original scientific article Keywords: materials investigation, microstructure, topography, copper alloys, laser, focused ion beams, UV nitrogen laser pulses, Scanning Electron Microscopy, laser ablation Published in DKUM: 01.06.2012; Views: 2299; Downloads: 143
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