1. Correlating nickel functionalities to selectivity for hydrogen peroxide electrosynthesisMiha Nosan, Dušan Strmčnik, Vasiliy Brusko, Maria Kirsanova, Matjaž Finšgar, Ayrat M. Dimiev, Boštjan Genorio, 2023, izvirni znanstveni članek Ključne besede: nickel oxide, heat-treated graphene oxide, selectivity, oxygen reduction reaction, peroxide formation Objavljeno v DKUM: 10.05.2024; Ogledov: 231; Prenosov: 12
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2. Recombination of oxygen atoms on the surface of oxidized polycrystalline nickel : temperature and pressure dependencesDomen Paul, Miran Mozetič, Rok Zaplotnik, Jernej Ekar, Alenka Vesel, Gregor Primc, Denis Đonlagić, 2023, izvirni znanstveni članek Opis: The recombination of neutral oxygen atoms in the ground state on the oxidized nickel samples was studied experimentally in the range of pressures where the maximum density occurs in weakly ionized low-pressure oxygen plasma, i.e. between 40 and 200 Pa. The recombination coefficient was determined in the flowing afterglow. The source of oxygen atoms was plasma sustained in a quartz tube of inner diameter 4.7 mm by a microwave discharge in the surfatron mode. The recombination coefficient was determined in the afterglow chamber, which was a Pyrex tube with an inner diameter of 36 mm. The density of oxygen atoms in the afterglow chamber was varied by adjusting the discharge power, the gas flow, the pressure, and the position of a recombinator. Such flexibility of the experimental system enabled adjustment of the temperature of the oxidized nickel samples independently from the O-atom density in its vicinity or other parameters. The density of oxygen atoms in the afterglow chamber at various system parameters was determined by the Šorli method, which is reliable, and has an accuracy of about 20%. The recombination coefficient was determined by calorimetry. The coefficient was inversely proportional to the square root of the pressure and exponentially to the sample temperature. Systematic measurements performed at various pressures and temperatures enabled empirical formula, which were explained qualitatively by recombination kinetics.
Ključne besede: heterogenous surface recombination, recombination coefficient, nickel, nickel oxide, temperature Objavljeno v DKUM: 25.03.2024; Ogledov: 243; Prenosov: 21
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3. EXAFS and IR analysis of electrochromic $NiO_x$/$NiO_xH_y$ thin filmsJana Padežnik Gomilšek, Romana Cerc Korošec, Peter Bukovec, Alojz Kodre, 2008, izvirni znanstveni članek Opis: Electrochromic (EC) thin films of $NiO_x$ and $NiO_xH_y$ are prepared by sol-gel method from nickel chloride precursor and deposited onto a suitable substrate by dip-coating technique. The development of the structure with thermal treatment is investigated by EXAFS and IR spectroscopy in two series of films, with high and low concentration of chloride as counter ions. In the former, the predominant structure before thermal treatment is nickel hydroxide. The baking induces condensation, yet with no trace of NiO. In the latter group, colloidal particles are indicated, on which acetate groups are adsorbed or coordinated. At the maximum EC-response the formation of NiO grains is established by EXAFS and IR. Ključne besede: electrochromism, thin films, nickel oxide, nickel hydroxide, EXAFS Objavljeno v DKUM: 18.08.2017; Ogledov: 1423; Prenosov: 106
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