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1.
Combined effect of build orientation and energy density on density and mechanical properties of selectively laser melted Co-Cr-W-Si
Snehashis Pal, Igor Drstvenšek, 2022, izvirni znanstveni članek

Opis: The selective laser melting (SLM) process for manufacturing metals continues to be challenging in terms of achieving the maximum metallurgical properties that the process can provide. There are a variety of manufacturing parameters in the process that have individual characteristics, and when combined with other variables, the characteristics can be varied. However, in this study, the two most important manufacturing parameters, namely build direction and laser power, were considered to investigate their effects on density and tensile properties. Previously, the best scanning speed, hatch spacing, and layer thickness were determined, which directly affect the volumetric energy density in the SLM process. In this study, three different orientations and three different laser powers were selected, namely the X, Y, and Z directions and 55 W, 75 W, and 95 W laser power, respectively. Significant differences in product density were observed for the samples fabricated in the different orientations and with the different laser powers. The specimens fabricated in the Z direction always exhibit higher strength and ductility, which are significantly different from the specimens fabricated in the X and Y directions, while the laser power was 75 W and 95 W, respectively
Ključne besede: cobalt-chromium alloy, orientation, density, tensile strength, ductility, selective laser melting
Objavljeno v DKUM: 25.09.2024; Ogledov: 0; Prenosov: 8
.pdf Celotno besedilo (998,89 KB)
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2.
Pretransitional effects of the isotropic liquid-plastic crystal transition
Aleksandra Drozd-Rzoska, Szymon Starzonek, Sylwester Rzoska, Joanna M. Łoś, Zdravko Kutnjak, Samo Kralj, 2021, izvirni znanstveni članek

Opis: We report on strong pretransitional effects across the isotropic liquid–plastic crystal melting temperature in linear and nonlinear dielectric response. Studies were carried out for cyclooctanol (C8H16O) in the unprecedented range of temperatures 120 K < T < 345 K. Such pretransitional effects have not yet been reported in any plastic crystals. Results include the discovery of the experimental manifestation of the Mossotti Catastrophe behavior, so far considered only as a hypothetical paradox. The model interpretations of experimental findings are proposed. We compare the observed pretransitional behavior with the one observed in octyloxycyanobiphenyl (8OCB), typical liquid crystal (LC), displaying a reversed sequence of phase transitions in orientational and translational degrees of order on varying temperature. Furthermore, in its nematic phase, we demonstrate first-ever observed temperature-driven crossover between regions dominated by isotropic liquid and smectic A pretransitional fluctuations. We propose a pioneering minimal model describing plastic crystal phase behavior where we mimic derivation of classical Landau-de Gennes-Ginzburg modeling of Isotropic-Nematic-Smectic A LC phase behavior.
Ključne besede: plastic crystal, melting, pretransitional behavior, nonlinear dielectric effect, dielectric constant, Mossotti Catastrophe
Objavljeno v DKUM: 12.08.2024; Ogledov: 60; Prenosov: 8
.pdf Celotno besedilo (1,76 MB)
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3.
Investigation of the best manufacturing orientation of Co-Cr-W-Si dental prosthetic elements in the selective laser melting process
Snehashis Pal, Janez Gotlih, Igor Drstvenšek, 2022, izvirni znanstveni članek

Opis: It is well known that Selective Laser Melting (SLM) does not provide the same mechanical properties in all directions of the part. This is due to the microstructural grain orientation and pore shape in SLM products. Therefore, depending on the direction of the pressure applied to the SLM product, a different manufacturing orientation is required to achieve the best mechanical properties. Changing the microstructural grain orientation is difficult through SLM, but a process to reduce the size and number of the pores can be discovered through different combinations of manufacturing parameters. In prosthodontics, pressure is usually applied in the vertical direction, which leads to compression and bending of crowns with bridges. The compressive load can be easily absorbed in the crowns, but the bending force has a significant effect here. Therefore, a product with high tensile strength and high ductility is needed to survive longer. Considering these requirements, this study determined the best parameters for laser processing by SLM method to reduce porosity and improve mechanical strength and ductility of Co-CrW-Si alloy products. The result is a relative product density of 100% for cubic specimens and a yield strength, ultimate tensile strength, and elongation at break of the tensile specimens of 900 MPa, 1200 MPa, and 15%, respectively, obtained in specimen build-up in the Z direction with a laser power of 60 W and a scanning speed of 450 mm/s. Eventually, the best orientation for the production of dental prosthetic elements using the SLM process was determined.
Ključne besede: cobalt-chromium alloy, dental implant, density, tensile strength, ductility, selective laser melting
Objavljeno v DKUM: 03.07.2024; Ogledov: 78; Prenosov: 12
.pdf Celotno besedilo (640,47 KB)
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4.
Dimensional deviations in Ti-6Al-4V discs produced with different process parameters during selective laser melting
Snehashis Pal, Marijana Milković, Riad Ramadani, Janez Gotlih, Nenad Gubeljak, Radovan Hudak, Igor Drstvenšek, Matjaž Finšgar, Tomaž Brajlih, 2023, izvirni znanstveni članek

Opis: When manufacturing complicated products where both material and design play a role, especially thin and curved components, it is difcult to maintain accurate dimensions in Selective Laser Melting. Considering these difculties, this article presents the dimensional errors in the fabrication of Ti-6Al-4V discs and their thermomechanics during manufacturing. Various combinations of laser processing parameters were used to fabricate the 2.00 mm thick discs with a diameter of 5.70 mm. It was found that the thickness shortened and the round shape changed to an oval shape for most of the discs. The thickness decreased along the build-up direction from the bottom to the top and formed a taper that increased with increasing energy density (ED). The horizontal diameter of the discs changed slightly, while the vertical diameters changed remarkably with increasing ED. On the other hand, reducing the laser power resulted in a reduction of the roundness error, while it caused a reduction of the thickness. The hatch spacing signifcantly afected the volume of the melt pool and caused a change in the vertical diameter. The central part of the curved surface of the discs became concave and the concavity increased due to the increasing ED.
Ključne besede: dimension, Ti-6Al-4V, lase power, scanning speed, hatch spacing, selective laser melting
Objavljeno v DKUM: 29.03.2024; Ogledov: 219; Prenosov: 9
.pdf Celotno besedilo (4,48 MB)
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6.
Melting point of dried gold nanoparticles prepared with ultrasonic spray pyrolysis and lyophilisation
Žiga Jelen, Marcin Krajewski, Franc Zupanič, Peter Majerič, Tilen Švarc, Ivan Anžel, Jernej Ekar, Sz-Chian Liou, Jerzy Kubacki, Mateusz Tokarczyk, Rebeka Rudolf, 2023, izvirni znanstveni članek

Opis: A coupled process of ultrasonic spray pyrolysis and lyophilisation was used for the synthesis of dried gold nanoparticles. Two methods were applied for determining their melting temperature: uniaxial microcompression and differential scanning calorimetry (DSC) analysis. Uniaxial microcompression resulted in sintering of the dried gold nanoparticles at room temperature with an activation energy of 26–32.5 J/g, which made it impossible to evaluate their melting point. Using DSC, the melting point of the dried gold nanoparticles was measured to be around 1064.3°C, which is close to pure gold. The reason for the absence of a melting point depression in dried gold nanoparticles was their exothermic sintering between 712 and 908.1°C.
Ključne besede: gold nanoparticles, melting point, ultrasonic spray pyrolysis, characterisation
Objavljeno v DKUM: 08.12.2023; Ogledov: 448; Prenosov: 30
.pdf Celotno besedilo (2,83 MB)
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7.
The use of selective laser melting in mandibular retrognathia correction
Andrej Čretnik, Anita Fekonja, 2022, izvirni znanstveni članek

Opis: Digitalization and additive manufacturing offer new possibilities in the manufacturing of individualized medical and dental products. In the paper we present the results of the first 30 consecutive growing patients (15 males and 15 females), with a mean age of 13.69 years (SD = 1.26), who were treated for mandibular retrognathia (skeletal Class II malocclusion), using fixed sagittal guidance (FSG) appliance, individually manufactured by selective laser melting (SLM). Lateral cephalometric radiographs were taken before (T0) and after (T1) treatment and a detailed cephalometric analysis was performed. with a special focus on a time period for malocclusion correction. The analyzed data were compared with the control group (CG; treated with intermaxillary Class II elastics) that was matched for pretreatment age and pretreatment cephalometric measurements. Both methods were effective in the correction of Class II malocclusion, but the time period of correction was significantly shorter (16.03 ± 1.09 months vs. 20.65 ± 4.12 months) with the FSG appliance. After treatment visual skeletal and dentoalveolar effects were achieved, with statistically significant differences measured in mandibular incisors inclination (0.45° in FSG and 2.84° in CG) and distance (−0.61 mm in FSG and 0.13 mm in CG), in mandibular first molar inclination (−1.07° in FSG and 1.18° in CG) and overbite (−3.82 mm in FSG and −2.46 mm in CG), all in favor of FSG appliance. After the final mean treatment time of 16.03 ± 1.09 months, visual skeletal and dentoalveolar effects were achieved, with significant differences in sagittal (SNB angle, SNPg angle, mandibular length (CoGn) and consequently decrease in ANB angle) as well as in vertical (lower anterior facial height (LAFH) and gonial angle) measurements noted, with no reported complications. As the time needed for malocclusion correction was comparable with the reports in the traditional use of the functional appliance and as all the cosmetical and functional changes in all the treated patients remained stable after a 2-year observational period, growing patients with Class II malocclusion could benefit with this type of treatment. As all the cosmetical and functional changes in all the treated patients remained stable after a 2-year observational period, growing patients with Class II malocclusion could benefit from the treatment with FSG appliance.
Ključne besede: selective laser melting, individualized manufacturing technology, mandibular retrognathia
Objavljeno v DKUM: 18.09.2023; Ogledov: 513; Prenosov: 31
.pdf Celotno besedilo (1,80 MB)
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8.
Comparative study of the microstructure and properties of cast-fabricated and 3D-printed laser-sintered Co–Cr alloys for removable partial denture frameworks
Dejan Stamenković, Miljana Popović, Rebeka Rudolf, Milorad Zrilić, Karlo Raić, Kosovka Obradović-Đuričić, Dragoslav Stamenković, 2023, izvirni znanstveni članek

Opis: Since additive technologies in dentistry are gradually replacing metal casting technology, it is necessary to evaluate new dental constructions intended for the development of removable partial denture frameworks. The aim of this research was to evaluate the microstructure and mechanical properties of 3D-printed, laser-melted and -sintered Co–Cr alloys, and perform a comparative study with Co–Cr castings for the same dental purposes. The experiments were divided into two groups. The first group consisted of samples produced by conventional casting of the Co–Cr alloy. The second group consisted of 3D-printed, laser-melted and -sintered specimens produced from a Co–Cr alloy powder divided into three subgroups, depending on the technological parameters chosen for manufacturing (angle, location and heat treatment). Examination of the microstructure was carried out by classical metallographic sample preparation, using optical microscopy and scanning electron microscopy with energy dispersive X-ray spectroscopy (EDX) analysis. A structural phase analysis was also performed by XRD. The mechanical properties were determined using a standard tensile test. The microstructure observation showed a dendritic character in the case of castings, while in the case of 3D-printed, laser-melted and -sintered Co–Cr alloys, the microstructure was typical for additive technologies. The XRD phase analysis confirmed the presence of Co–Cr phases (ε and γ). The results of the tensile test showed remarkably higher yield and tensile strength values and slightly lower elongation of the 3D-printed, laser-melted and -sintered samples than those produced by conventional casting.
Ključne besede: Co–Cr dental alloys, 3D printing, laser melting and sintering, casting, microstructure, mechanical properties, characterization
Objavljeno v DKUM: 21.04.2023; Ogledov: 459; Prenosov: 45
.pdf Celotno besedilo (16,55 MB)
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9.
Vpliv izdelovalnih parametrov na lastnosti izdelkov iz Ti-6Al-4V, narejenih s selektivnim laserskim taljenjem in plastenje površine z bioaktivnim polimerom
Snehashis Pal, 2019, doktorska disertacija

Opis: Technological parameters included in energy density (ED) are the more powerful tools in selective laser melting (SLM) technology which can be used in the time of fabrication to regulate chemical, metallurgical, and mechanical properties of a product. The volumetric Energy Density (ED) depends on the energy input employed by the laser power, scanning speed, hatch spacing, and the layer thickness. Density, microstructure, surface morphology, dimension accuracy, strength and porosity including the number of pores, place of the pore, size of a pore shape of a pore, inclusions of pores of an SLM product depends on the processing parameters. As the powder material fusion process is done by track by track and layer by layer, the architecture of the microstructure in a product is oriented as the direction of building up too. The research has emphasized on metallurgical properties, tensile properties, and producing the non-porous products from Ti-6Al-4V alloy powder and surface modification using bioactive polymer for orthopedic application. The research has followed four steps to study the metallurgical properties and finding out the combinations of technological parameters in producing non-porous products. The purpose of the first step of the study was to examine the effects of ED on the product properties and to obtain an optimum ED as well as the optimal range of scanning speed. The second step of the study has focused on the influences of laser power. The third step of the study has investigated the effect of amounts of track overlapping and hatch spacing. Almost a zero-porosity product has been able to produce by following these three steps of the ongoing research. The fourth step has studied the metallurgical properties emphasizing on re-melting of every layer. High-density products have been found in the fourth step where a small amount of very small sized pores are present as a result of keyhole effect and gaseous bubble entrapment mainly. Four buildup orientations have been selected for each ED in the first step of the study to examine the tensile properties of the products. The best buildup orientation has been seen in longitudinally vertical tensile specimens considering tensile properties. The tensile properties have also been studied in the second and third step of the study with best build up orientation of the tensile specimens. The alterations of metallurgical and tensile properties have also been investigated after heat-treatment of the specific samples. Dimensional accuracies were also invigilated on the cubic, and tensile specimens over the studies and consequently, inaccuracies have been noticed. The fifth step of the study has observed the pore properties, adhesion properties, the compressive strength of gelatin coating manufactured using unidirectional freezing and the freeze-drying process of three different gelatin concentrations on four different surfaced Ti-6Al-4V alloy substrates. The results indicate that the coating properties depend on the substrate’s surface texture as well as the concentration of gelatin. Above 80% of porosity, interconnected and well-aligned pores of 75-200 μm have been obtained which is required to stimulate bone ingrowth histologically.
Ključne besede: selective laser melting, unidirectional freezing, fabricating parameters, porosity, microstructure, mechanical strength
Objavljeno v DKUM: 01.04.2019; Ogledov: 1896; Prenosov: 147
.pdf Celotno besedilo (10,52 MB)

10.
High resolution melting curve analysis for high-throughput SNP genotyping in IL23R gene and association of IL23R with Slovenian inflammatory bowel diseases patients
Mitja Mitrovič, Uroš Potočnik, 2010, izvirni znanstveni članek

Opis: Single nucleotide polymorphism (SNP) analysis is important tool in the studies of genetic factors associated with complex diseases and with genetically influenced response to drug therapy (pharmacogenetics). Recently, a new generation of generic dsDNA binding dyes (LCGreen$^{TM}$) contributed to the development of fast and low-cost method for SNP detection and/or genotyping based on high resolution melting (HRM) analysis. The aim of our study was to develop HRM assay for IL23R gene (rs7517847) and to perform association study in Slovenian inflammatory bowel diseases (IBD) patients. We genotyped 345 Slovenian healthy controls and 295 IBD patients including 159 with Crohn's disease (CD) and 136 with ulcerative colitis (UC) for rs7517847 polymorphism in IL23R gene using standard RFLP and optimized HRM methods. In this study, we showed, that HRM is a simple, fast and reliable method for genotyping of clinical samples where homozygotes (GG and TT) were determined by Tm calling method and difference between homozygotes and heterozygotes was determined by different melting curve shape using gene scanning method. With combination of results from Tm calling and gene scanning methods, we achieved 98,6% concordance between PCR-RFLP and PCRHRM results, based on the analysis of 640 samples. We found statistically significant association of IL23R polymorphism with Slovenian Crohn's disease patients when comparing genotype and allele frequencies between CD patients and controls. Allele frequency of minor allele G was 0,46 in controls and was reduced to 0,33 in CD patients (p < 0,001, OR = 0,588). The frequency of T/T genotype carriers was higher in CD patients (50,3%) than in controls (26,7%, p = 0,002, OR = 2,558). We found weak association between IL23R polymorphism and Slovenian UC patients. Carriers of T/T genotype have higher risk for UC (p = 0,035, OR = 1,599). These results suggest IL23R plays important role in CD and UC development in Slovenian patients.
Ključne besede: SNP genotyping, high resolution melting, DNA dyes, inflammatory bowel diseases, LC Green Plus
Objavljeno v DKUM: 18.08.2017; Ogledov: 1939; Prenosov: 112
.pdf Celotno besedilo (232,19 KB)
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