Raziskave formiranja asimetričnih poroznih membran v ternarnem sistemu poli(metilmetakrilat)/N,N-dimetilformamid/voda (PMMA/DMF/voda) : diplomsko deloIris Gnjidič
, 2001, diplomsko delo
Ključne besede: organska kemija, membrane, polimetilmetakrilat, PMMA, dimetilformamid, DMF, mokra fazna separacija, asimetrične porozne membrane
Objavljeno: 26.07.2007; Ogledov: 2505; Prenosov: 0
Monolithic magneto-optical nanocomposites of barium hexaferrite platelets in PMMAGregor Ferk
, Peter Krajnc
, Anton Hamler
, Alenka Mertelj
, Federico Cebollada
, Mihael Drofenik
, Darja Lisjak
, 2015, izvirni znanstveni članek
Opis: The incorporation of magnetic barium hexaferrite nanoparticles in a transparent polymer matrix of poly(methyl methacrylate) (PMMA) is reported for the first time. The barium hexaferrite nanoplatelets doped with Sc3+, i.e., BaSc0.5Fe11.5O12 (BaHF), having diameters in the range 20 to 130 nm and thicknesses of approximately 5 nm, are synthesized hydrothermally and stabilized in 1-butanol with dodecylbenzenesulfonic acid. This method enables the preparation of monolithic nanocomposites by admixing the BaHF suspension into a liquid monomer, followed by in-situ, bulk free-radical polymerization. The PMMA retains its transparency for loadings of BaHF nanoparticles up to 0.27 wt.%, meaning that magnetically and optically anisotropic, monolithic nanocomposites can be synthesized when the polymerization is carried out in a magnetic field. The excellent dispersion of the magnetic nanoparticles, coupled with a reasonable control over the magnetic properties achieved in this investigation, is encouraging for the magneto-optical applications of these materials.
Ključne besede: polymer composites, nanoparticles, polymethyl methacrylate, PMMA
Objavljeno: 23.06.2017; Ogledov: 363; Prenosov: 170
Celotno besedilo (1,10 MB)
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Synthesis of PMMA/ZnO nanoparticles composite used for resin teethDanica Popović
, Rajko Bobovnik
, Silvester Bolka
, Miroslav Vukadinovič
, Vojkan Lazić
, Rebeka Rudolf
, 2017, izvirni znanstveni članek
Opis: Wear resistance is one of the most important physical properties of the artificial teeth used in acrylic dentures. The goal of this research was to synthesize a new composite material made of matrix Poly-(methyl methacrylate)-PMMA with different percentages (2 % and 3 % of volume fractions) of zinc-oxide nanoparticles (ZnO NPs) as reinforcing elements, to improve its mechanical properties. The dynamic mechanical behaviour of this composite was studied through the DMA method in comparison to the pure PMMA supported by the characterization of their microstructures. Then the wear resistance was analysed on the samples, which were prepared in the form of teeth. In this context their vertical height loss was measured after 100,000 chewing cycles on a chewing simulator, before and after the artificial thermal ageing. Investigations showed that the PMMA/ZnO NP composites dampened the vibrations better than the pure PMMA, which could be assigned to the homogenous distribution of ZnO NPs in the PMMA matrix. It was found that the mean vertical height loss for the pure PMMA teeth was significantly higher (more than 4 times) compared to composite teeth made with ZnO NPs. Introducing the thermal artificial ageing led to the finding that there was no effect on the height loss by the composite material with 3 % of volume fractions of ZnO NPs. Based on this it was concluded that PMMA/ZnO NPs composites showed improved in-vitro wear resistance compared to acrylic-resin denture teeth, so this new composite material should be preferred when occlusal stability is considered to be of high priority.
Ključne besede: poly-methyl methacrylate, PMMA, zinc-oxide nanoparticles, composite, resin teeth
Objavljeno: 12.12.2017; Ogledov: 329; Prenosov: 202
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