141. Influence of temperature and pressure during PGSS[sup]TM micronization and storage time on degree of crystallinity and crystal forms of monostearate and tristearateZoran Mandžuka, Željko Knez, 2008, izvirni znanstveni članek Opis: For controlling the degree of crystallinity and crystal form during particle formation using supercritical fluids, knowledge of pressure influence on solid-liquid-gas (S-L-G) equilibrium and solubility data of the system is crucial. S-L-G equilibrium data were determined in pressure range from 50 to 600 bar for systems monostearate/CO2 and tristearate/CO2 using a high-pressure view cell. Results showed a temperature minimum for both systems.The solubilities of CO2 in liquid glycerides were high: maximum solubilities, which were determined at temperatures 70 and 90 °C and pressure range from 50 to 450 bar, were from 50 to 90 mol%. Physical characteristics of micronized monostearate and tristearate samples were studied in detail after micronization and after 3 months of storage at 20 °C. Ključne besede: chemical processing, high pressure technology, supercritical fluids, micronization, fine particles, Particles from Gas Saturated Solution, degree of crystallinity Objavljeno v DKUM: 31.05.2012; Ogledov: 2958; Prenosov: 59 Povezava na celotno besedilo |
142. Absorptive and transformative capacities in nanotechnology innovation systemsKrsto Pandža, Robin Holt, 2007, izvirni znanstveni članek Opis: We identify managerial challenges offered by an emergent nanotechnology innovation system in which knowledge is dispersed, asymmetric and contested. We argue the proposed models of knowledge absorption and transformation enhance existing theories of knowledge and emergent technology by recognizing how and why knowledge flows among the actors in emergent technology innovationsystem. We base our argument on combined research evidence from a Delphi study concerning the future of European manufacturing, from which a selected statement has been analyzed, and from analysis of the NanoManufacturing Institute at Leeds University, UK; specifically its work in building ties between different actors associated with nanotechnology. We conclude our paper with suggestions for future research. Ključne besede: technology management, nanotehnology, innovation systems, knowledge flows, absorptive capacity, transformative capacity Objavljeno v DKUM: 31.05.2012; Ogledov: 1848; Prenosov: 98 Povezava na celotno besedilo |
143. Supercritical fluid extraction of chammomile flower head flowers: comparison with conventional extraction, kinetics and scale-upPetra Kotnik, Mojca Škerget, Željko Knez, 2007, objavljeni znanstveni prispevek na konferenci Opis: Supercritical fluid extraction of chamomile flower heads was performed on semicontinuous extraction apparatus in the lab scale using carbon dioxide as solvent. The results of high pressure experiments were compared with those obtained with Soxhlet extraction, steam distillation and maceration. The obtained extracts were analysed by HPLC on ?-bisabolol, matricine and chamazulene content and by gravimetrical method on essential oil and waxes content. The highest content of active components in extracts and highest extraction yield were obtained using SFE at 250 bar and 40 °C. At this extraction conditions the two step separation was used to optimize the separation of essential oil from unwanted components. Dynamic behaviour of theSFE with single step separation runs were analysed using two mathematical models for describing the constant rate period and subsequent falling rate period. Based on the experimental data, external mass transfer coefficient, diffusion coefficient and diffusivity in solid phase were estimated. Results showed acceptable agreement of calculated and experimental data. Based on theparameters determined in the lab scale, the extraction process was successfully transferred to pilot scale. Ključne besede: chemical processing, high pressure technology, supercritical extraction, chamomile, matricine, chamazulen, scale-up Objavljeno v DKUM: 31.05.2012; Ogledov: 2249; Prenosov: 63 Povezava na celotno besedilo |
144. Fuzzy Logic Model for the performance benchmarking of sugar plants by considering best available techniquesDamjan Krajnc, Miro Mele, Peter Glavič, 2007, izvirni znanstveni članek Opis: This paper deals with the problem of performance benchmarking of traditional beet sugar plants, by considering Best Available Techniques (BAT) for beet sugar production, as determined by the Integrated Pollution Prevention and Control (IPPC) Directive. A Fuzzy Logic Model, based on fuzzy set theory, was constructed for this purpose, in order to compare the performances of sugar plants within the sector's best standards, as expressed in the Reference Document on BAT. The effectiveness of the model was tested in the case study,in which three sugar plants were benchmarked against the BAT regarding the consumption of energy, water, raw materials and the production of wastes, wastewater, by-products and the main product. The model was recognized as helpful for the benchmarking needs of sugar plants. In addition, by integrating BAT Reference Document analysis into the model, it provides IPPC permitting authorities with an objective method and uniform BAT benchmarks to manage permitting process. Ključne besede: chemical processing, beet sugar production, sugar industry, clean technologies, performance benchmarking, IPPC Directive, technology performance assessment, fuzzy set theory, best available techniques, IPPC permitting process Objavljeno v DKUM: 31.05.2012; Ogledov: 2648; Prenosov: 95 Povezava na celotno besedilo |
145. Proteinase-catalyzed hydrolysis of casein at atmospheric pressure and in supercritical mediaMateja Primožič, Maja Leitgeb, Željko Knez, 2006, izvirni znanstveni članek Opis: In the presented work, reaction parameters for hydrolysis of casein, catalyzed by Carica papaya latex at atmospheric and high pressure, were optimized. Casein is a remarkably efficient nutrient, supplying not only essential amino acids, but also some carbohydrates, calcium, phosphorus and therefore is very important for the food industry. Different reaction parameters such as temperature, stirring rate, casein and enzyme concentration were studied to found the optimal conditions for the reaction. Reactions were performed at atmospheric pressure; an influence of temperature/pressure on the casein hydrolysis in supercritical carbon dioxide (SC CO2) was also investigated to improve the reaction rates. Higher conversions were achieved when the reactions were performed in SC CO2, even though casein was not soluble in this medium. Ključne besede: chemical processing, high pressure technology, supercritical CO2, enzymatic reactions, proteinase, Carica papaya latex Objavljeno v DKUM: 31.05.2012; Ogledov: 2249; Prenosov: 48 Povezava na celotno besedilo |
146. The lipase-catalyzed synthesis of fatty acid fructose esters in organic media and in supercritical carbon dioxideSaša Šabeder, Maja Leitgeb, Željko Knez, 2006, izvirni znanstveni članek Opis: Sugar fatty acid esters are biodegradable surface active compounds in foodstuffs and cosmetics or pharmaceuticals. They have potential in replacing pollutant chemically synthesized surfactants. The enzymatic synthesis of fructose palmitate catalyzed by Candida antarctica B lipase was performed in different organic media in a batch react at atmospheric pressure. The influence of the organic solvent and temperature on the esterification was studied. Since supercritical carbon dioxide (SC CO2) has several advantages over organic solvents, such as high reaction rate, high mass transfer, non-toxicity, non flammability and low price, it was also chosen as a reaction medium for fructose palmitate production. The influence of temperature on immobilized lipase activity was studied at 10 MPa and the results were compared to the results obtained from reactions performed at atmospheric pressure under the same reaction conditions. The highest conversion (67%) was obtained after 24 hours of reaction in SC C02 at 80°C. A change of the particle size distribution and morphology of the untreated lipase and lipase treated with 2-methyl 2-butanol and SC C02 was observed.
This article was presented at 1st SEECChE, held in Belgrade, September 25-28, 2005 Ključne besede: chemical processing, high pressure technology, supercritical CO2, lipase catalyzed syntheses, esterification, fructose palmitate, biocatalysts, lipase, Candida antarctica B Objavljeno v DKUM: 31.05.2012; Ogledov: 2712; Prenosov: 502 Celotno besedilo (392,53 KB) Gradivo ima več datotek! Več... |
147. Particle formation using supercritical fluids : a short reviewŽeljko Knez, 2006, pregledni znanstveni članek Opis: Particle formation and the design of solid particles and powdery composites with unique properties is at the moment one of major the developments of supercritical fluid (synonyms: dense gases, dense fluids, high pressure) applications. Conventional well-known processes for the particle-size redistribution of solid materials are crushing and grinding (which for some compounds are carried out at cryogenic temperatures), air micronization, sublimation, and recrystallization from solution. There are several problems associated with the above-mentioned processes. Some substances are unstable under conventional milling conditions, in recrysfallization processes the product is contaminated with solvent and waste solvent streams are produced. The application of supercritical fluids may overcome the drawbacks of conventional processes, and powders and composites with special characteristics can be produced. Several processes for the formation and design of solid particles using dense gases have been studied intensively. The unique thermodynamic and fluid-dynamic properties of supercritical fluids can also be used for the impregnation of solid particles, for the formation of solid powderous emulsions, particle coatings, e.g. for the formation of solids with unique properties for use in different applications. This review will focus on the fundamentals and on recent advances of particle formation and design processes using supercritical fluids on their applications and the technological advantages and disadvantages of various processes. Ključne besede: chemical processing, high pressure technology, supercritical CO2, proteinase, thermal stability, pressure stability, enzyme activity, water content, dense gases Objavljeno v DKUM: 31.05.2012; Ogledov: 2888; Prenosov: 162 Celotno besedilo (514,21 KB) Gradivo ima več datotek! Več... |
148. Kinetics of supercritical carbon dioxide extraction of borage and evening primrose seed oilPetra Kotnik, Mojca Škerget, Željko Knez, 2006, izvirni znanstveni članek Opis: In the present work, high-pressure extraction of borage (Borago officinalis L.) and evening primrose (Oenothera biennis L.) seed oil, containing the valuable -linolenic acid (GLA), has been investigated. Extraction was performed with supercritical carbon dioxide on a semi-continuous flow apparatus at pressures of 200 and 300 bar, and at temperatures of 40 and 60 °C. A constant flow rate of carbon dioxide in the range from 0.17 to 0.20 kgžhwas maintained during extraction. The extraction yields obtained using dense CO2 were similar to those obtained with conventional extraction using hexane as solvent. The composition of extracted crude oil was determined by GCanalysis. The best results were obtained at 300 bar and 40 °C for both seed types extracted, where the quality of oil was highest with regard to GLA content. The evening primrose seed oil extracted with supercritical fluid extraction was particularly rich in unsaturated fatty acidsČ up to 89.7 wt-% of total free fatty acids in the oil. The dynamic behavior of the extraction runs was analyzed using two mathematical models for describing the constant rate period and the subsequent falling rate period. Based on the experimental data, external mass transfer coefficients, diffusion coefficients and diffusivity in solid phase were estimated. Results showed good agreement between calculated and experimental data. Ključne besede: chemical processing, high pressure technology, supecritical CO2, seed oil extraction, evening primrose, borage, free fatty acids, kinetics, modeling Objavljeno v DKUM: 31.05.2012; Ogledov: 2348; Prenosov: 109 Povezava na celotno besedilo |
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150. Core technological, marketing and complementary competencies as determinants of innovative performance : ph.d. dissertationTanja Rajkovič, 2009, doktorska disertacija Opis: In this thesis a model of technological, marketing and complementary competencies in relation to firms’ innovative performance is developed and validated drawing from competence based theory of competitive advantage with regard to new product development and innovation activity. Research is based on a cross-industry survey and tested on a sample of 65 product lines belonging to 50 established Slovenian manufacturing firms, both large and middle-sized. Segmentation of firms is carried out using the variables of innovative performance by means of the clustering method and identifies three firm segments – technology-leaders, technology-followers with strong competencies and technology-followers with weak competencies. The model is tested by applying the partial least squares structural modelling tool SmartPLS. A positive link between the constructs is confirmed; however, competencies differ according to the innovative strategy pursued by the firms, namely incremental innovation, radical innovation and trend-setting. I further confirm that innovative performance has a positive effect on a firm’s business performance and show that environmental effects – technological and marketing turbulence – have a limited influence on the relationship. The implications of the findings are valuable to firms aligning their competencies with their strategy, as well as to policy makers in technology-following countries. Ključne besede: industrial enterprises, innovations, technology, competence, competition, competitive advantage, market, models, analysis Objavljeno v DKUM: 30.05.2012; Ogledov: 2340; Prenosov: 95 Povezava na celotno besedilo |