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Two new zinc(II) acetates with 3- and 4-aminopyridine : syntheses and structural properties
Brina Dojer, Andrej Pevec, Ferdinand Belaj, Matjaž Kristl, 2015, original scientific article

Abstract: The synthesis and characterization of two new zinc(II) coordination compounds with 3- and 4-aminopyridine are reported. They were obtained after adding a water solution of $Zn(CH_3COO)_2$ · $2H_2O$ or dissolving solid $Zn(CH_3COO)_2$ · $2H_2O$ in methanol solutions of 3- and 4-aminopyridine. The products were characterized structurally by single-crystal X-ray diffraction analysis. Colourless crystals of the compound synthesized by the reaction of $Zn(CH_3COO)_2$ · $2H_2O$ and 3-aminopyridine (3-apy), are built of trinuclear complex molecules with the formula $[Zn_3(O_2CCH_3)_6(3- apy)_2(H_2O)_2]$(1). The molecules consists of two terminal $Zn$ atoms, coordinated tetrahedrally, and one central $Zn$ atom, coordinated octahedrally. Colourless crystals, obtained by the reaction of $Zn(CH_3COO)_2$ · $2H_2O$ with 4-aminopyridine (4-apy), consist of a mononuclear complex $[Zn(O_2CCH_3)_2(4-apy)_2]$(2). Hydrogen-bonding interactions in the crystal structures of both complexes are reported.
Keywords: zinc(II) acetate dihydrate, aminopyridine, x-ray crystal structure, hydrogen bonds
Published in DKUM: 30.08.2017; Views: 1176; Downloads: 118
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