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1.
Razvoj in karakterizacija superhidrofobnega geopolimernega kompozita
Oskar Abram, 2025, diplomsko delo

Opis: Diplomsko delo zajema razvoj trajnostnega superhidrofobnega geopolimernega kompozita za izboljšanje funkcionalnosti tradicionalnih gradbenih materialov, kar je tudi njen namen. Za pripravo geopolimernih mešanic smo uporabili industrijske odpadke, ki imajo nižji ogljični odtis v primerjavi s portlandskim cementom, kot je na primer elektrofiltrski pepel. V eksperimentalnem delu smo pripravili štiri različne mešanice geopolimernega betona, ki smo jim dodajali različne količine polidimetilsiloksana in jih primerjali z referenčno mešanico. Površine vzorčnih materialov smo obdelali s superhidrofobnim premazom na osnovi polidimetilsiloksana, heksana in mikrodelcev (silicijev dioksid). Testirali smo mehanske lastnosti, kontaktne kote in mikrostrukturo površine. Rezultati so pokazali, da se z dodajanjem polidimetilsiloksana in nanosom premaza poveča kontaktni kot nad 150°, kar kaže na uspešno doseženo superhidrofobnost, medtem ko so tlačne trdnosti pri večjih deležih polidimetilsiloksana nekoliko nižje. SEM analiza je potrdila prisotnost hierarhičnih struktur, značilnih za Cassie-Baxterjev režim mokrenja. Rezultati zaključnega dela kažejo, da je z ustrezno kombinacijo materialov in kemikalij možno razviti geopolimerne betone z izboljšanimi funkcionalnostmi in visoko trajnostjo.
Ključne besede: geopolimer, elektrofiltrski pepel, superhidrofobnost, mehanske lastnosti, kontaktni kot
Objavljeno v DKUM: 04.09.2025; Ogledov: 0; Prenosov: 15
.pdf Celotno besedilo (2,78 MB)

2.
Enhancing strength and ▫$CO_2$▫ uptake in lignite-based fly ash geopolymer mortar through supercritical carbonation
Tinkara Marija Podnar, Željko Knez, Gregor Kravanja, 2025, izvirni znanstveni članek

Opis: This study demonstrates the potential of supercritical CO₂ curing to enhance the performance and sustainability of lignite-based fly ash geopolymer mortar offering a promising approach to reducing CO₂ emissions in the construction industry while improving material properties. The research comprehensively compared conventional curing (GEO-REF) with supercritical CO₂ curing (GEO-CO₂), revealing that GEO-CO₂ samples exhibited higher compressive and flexural strengths, achieving peak performance almost immediately after curing. Supercritical CO₂ exposure resulted in enhanced carbonation, with a depth of up to 7.6 mm and a carbonation rate of up to 67 %. XRD confirmed phase changes due to CO₂ curing, with GEO-CO₂ showing additional calcium carbonate-calcite, calcium carbonate-aragonite, and calcium silicate hydroxide compared to GEO-REF. Nitrogen adsorption/desorption studies indicated larger pore diameters but a reduced BET surface area in GEO-CO₂ samples, suggesting structural changes due to CO₂ exposure. TGA analysis revealed that supercritical CO₂ curing reduced water retention and enhanced carbonation, resulting in increased CaCO₃ content and changes in Ca(OH)₂ levels.
Ključne besede: geopolymer, fly ash, carbonation, CO2 fixation, supercritical CO2, high pressure reactor
Objavljeno v DKUM: 25.07.2025; Ogledov: 0; Prenosov: 3
.pdf Celotno besedilo (6,51 MB)

3.
Razvoj toplotnoizolacijskega geopolimera na osnovi elektrofiltrskega pepela z dodatkom perlita
Maša Žlavs, 2025, diplomsko delo

Opis: Diplomsko delo obravnava vpliv perlita na mehanske in toplotnoizolativne lastnosti, ter paroprepustnost geopolimera. Namen raziskave je preučiti, kako različni deleži perlita vplivajo na geopolimerne mešanice ter razviti okolju prijazen toplotnoizolacijski geopolimer na osnovi elektrofiltrskega pepela z dodatkom perlita, ki bi lahko nadomestil nekatere okolju sporne materiale. Eksperimentalni del je vključeval analizo več geopolimernih mešanic z različno količino perlita. Rezultati so pokazali, da dodatek perlita zmanjša mehanske lastnosti (tlačno in upogibno trdnost), a hkrati izboljša toplotnoizolacijske lastnosti geopolimera ter njegovo paroprepustnost. Glede na naraščajočo okoljsko obremenitev gradbeništva in količino odpadkov je razvoj takšnih trajnostnih materialov izredno pomemben.
Ključne besede: geopolimer, perlit, elektrofiltrski pepel, termična konduktivnost, mehanske lastnosti
Objavljeno v DKUM: 24.07.2025; Ogledov: 0; Prenosov: 36
.pdf Celotno besedilo (3,46 MB)

4.
A comprehensive review of the advances, manufacturing, properties, innovations, environmental impact and applications of ultra-high-performance concrete (UHPC)
Gregor Kravanja, Ahmad Rizwan Mumtaz, Stojan Kravanja, 2024, pregledni znanstveni članek

Opis: The article presents the progress and applications of ultra-high-performance concrete (UHPC), a revolutionary material in modern construction that offers unparalleled strength, durability, and sustainability. The overview includes the historical development of UHPC, covering its production and design aspects, including composition and design methodology. It describes the mechanical properties and durability of UHPC and highlights recent innovations and research breakthroughs. The potential integration of multifunctional properties such as self-heating, self-sensing, self-luminescence and superhydrophobicity, is explored. In addition, advances in nanotechnology related to UHPC are addressed. Beyond the actual material properties, the article presents an environmental impact assessment and a life-cycle cost analysis, providing an insight into the wider implications of using UHPC. To illustrate the environmental aspects, the determination of CO2 emissions is explained using three numerical examples. Finally, various applications of UHPC are presented, focusing on the construction of buildings and bridges. By synthesizing the above-mentioned aspects, this review paper captures the dynamic landscape of UHPC and serves as a valuable resource for researchers and engineers in the field of construction materials.
Ključne besede: ultra-high-performance concrete, UHPC, manufacturing, mechanical properties, durability, multifunctionality, environmental impact assessment, life-cycle costs
Objavljeno v DKUM: 02.07.2025; Ogledov: 0; Prenosov: 28
.pdf Celotno besedilo (6,71 MB)
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5.
Vpliv ekspandiranega glinenega agregata na reološke, mehanske in izolativne lasnosti cementnih kompozitov
Nejc Časar, 2025, magistrsko delo

Opis: Magistrsko delo obravnava vpliv ekspandiranega glinenega agregata (LECA) na reološke, mehanske in izolativne lastnosti cementnih kompozitov. Namen raziskave je bil preučiti, kako različne frakcije ekspandirane gline vplivajo na sveže in strjene betonske mešanice, ter identificirati optimalne sestave za uporabo v trajnostnem gradbeništvu. Eksperimentalni del raziskave je vključeval analizo različnih betonskih receptur z različnimi deleži ekspandiranega agregata. Rezultati so pokazali, da dodatek LECA zmanjša gostoto betona, kar omogoča lažjo vgradnjo in zmanjša obremenitev konstrukcij. Hkrati je bila opažena izboljšana toplotna izolacija, kar prispeva k večji energetski učinkovitosti stavb. Vendar pa se je pokazalo tudi zmanjšanje tlačne in upogibne trdnosti, kar je treba upoštevati pri uporabi takšnih materialov v konstrukcijskih elementih. Kljub določenim omejitvam, kot so povečana vpojnost agregata in potencialno slabša trajnost v agresivnih okoljskih razmerah, rezultati raziskave potrjujejo, da je ekspandirana glina obetaven material za razvoj lahkih in izolativnih betonskih kompozitov.
Ključne besede: lahka ekspandirana glina, izolativni beton, nosilnost, morfologija, termična konduktivnost
Objavljeno v DKUM: 18.04.2025; Ogledov: 0; Prenosov: 75
.pdf Celotno besedilo (4,69 MB)

6.
Combined effects of metakaolin and hybrid fibers on self-compacting concrete
Natalija Bede Odorčić, Gregor Kravanja, 2022, izvirni znanstveni članek

Opis: There is a need to develop new construction materials with improved mechanical performance and durability that are low-priced and have environmental benefits at the same time. This paper focuses on the rheological, mechanical, morphological, and durability properties of synthetic and steel fiber reinforced self-compacting concrete (SCC) containing 5–15% metakaolin (M) by mass as a green replacement for Portland cement. Testing of the fresh mixes included a slump-flow test, density, and porosity tests. Mechanical properties were determined through compression and flexural strength. A rapid chloride penetrability test (RCPT) and the chloride migration coefficient were used to assess the durability of the samples. A scanning electron microscope (SEM) with energy dispersion spectrometry (EDS) was used to study the concrete microstructure and the interfacial transition zone (ITZ). The results show that a combination of metakaolin and hybrid fibers has a negative effect on the flowability of SCC. In contrast, the inclusion of M and hybrid fibers has a positive effect on the compressive and flexural strength of SCC. The fracture of SCC samples without fibers was brittle and sudden, unlike the fiber-reinforced SCC samples, which could still transfer a considerable load with increasing crack mouth opening deflection. Overall, the chloride migration coefficients were reduced by up to 71% compared to the control mix. The chloride reduction is consistent with the resulting compact concrete microstructure, which exhibits a strong bond between fibers and the concrete matrix.
Ključne besede: self-compacting concrete, synthetic and steel fibers, metakaolin, rheology, mechanical properties, chloride penetration, SEM-EDS
Objavljeno v DKUM: 12.03.2025; Ogledov: 0; Prenosov: 7
.pdf Celotno besedilo (6,46 MB)
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7.
Thermal, mechanical, and microstructural properties of novel light expanded clay aggregate (LECA)-based geopolymer concretes
Tinkara Marija Podnar, Gregor Kravanja, 2025, izvirni znanstveni članek

Opis: The construction sector’s reliance on traditional cement significantly contributes to CO2 emissions, underscoring the urgent need for sustainable alternatives. This study investigates fine (0–4 mm), rounded, uncoated, porous-surfaced lightweight expanded clay aggregate (LECA)-based geopolymers, which combine the low-carbon benefits of geopolymers with LECA’s lightweight and insulating properties. Geopolymers were synthesized using lignite-rich fly ash with varying ratios of LECA to aggregate. Mechanical testing revealed that the reference mixture without LECA (REF-GEO) achieved the highest compressive strength of 37.89 ± 0.75 MPa and flexural strength of 7.62 ± 0.11 MPa, while complete substitution of the aggregate with LECA (LECA-100%) reduced the compressive strength to 17.31 ± 0.88 MPa and flexural strength to 3.41 ± 0.11 MPa. The density of the samples decreased from 2.06 g/cm3 for REF-GEO to 1.31 g/cm3 for LECA-100%, and thermal conductivity dropped significantly from 1.15 ± 0.07 W/mK to 0.38 ± 0.01 W/mK. Microstructural analysis using XRD and SEM-EDX highlighted changes in the material’s internal structure and the increase in porosity with higher LECA content. Water vapor permeability increases over time, particularly in samples with higher LECA content. These findings suggest that LECA-based geopolymers are suitable for low-load or non-structural elements. They are ideal for sustainable, energy-efficient construction that requires lightweight, insulating, and breathable materials.
Ključne besede: geopolymers, LECA, fly-ash, sustainable composites
Objavljeno v DKUM: 12.02.2025; Ogledov: 0; Prenosov: 21
.pdf Celotno besedilo (3,94 MB)

8.
Development and characterization of novel ultra-high performance concrete with superhydrophobic and self-luminescent properties
Ahmad Rizwan Mumtaz, 2024, doktorska disertacija

Opis: This study explores the potential of using basalt reinforced UHPC by incorporating simulta- neously self-cleaning and self-luminescent features, paving the way for sustainable advancements in civil engineering. New green formulations of UHPC were developed by integrating supplementary cementitious materials and optimizing water to the binder ratio, followed by using basalt fibers to enhance strength and ductility. The fabricated samples with high particle-packing density exhibit sufficient workability and compressive strength up to 136 MPa, and, when incorporating basalt fibers, a notable reduction in brittleness. The inner microstructure of basalt fibers was observed to be smooth, homogeneously distributed, and well adhered to the UHPC matrix. To ensure the desired long-lasting visual appearance of decorative UHPC and reduce future maintenance costs, a time-effective strategy for creating a light-emitting biomimetic surface design was introduced. The samples exhibit high surface roughness, characterized by micro to nano-scale voids, displaying superhydrophobicity with contact angles reaching up to 155.45◦. This is accompanied by roll-off angles decreasing to 7.1◦, highlighting their self-cleaning features. The self-luminescence feature showcased intense initial light emission, offering a potential energy-efficient nighttime lighting solution.
Ključne besede: UHPC, basalt fibers, mechanical properties, morphology, superhydrophobic, self-luminescence
Objavljeno v DKUM: 16.10.2024; Ogledov: 0; Prenosov: 18
.pdf Celotno besedilo (12,91 MB)

9.
Carbonization of Class G well cement containing metakaolin under supercritical and saturated environments
Gregor Kravanja, Željko Knez, 2023, izvirni znanstveni članek

Ključne besede: well cement, carbonization, metakaolin, supercritical CO2, gas saturated solution, CaCo3
Objavljeno v DKUM: 15.04.2024; Ogledov: 187; Prenosov: 89
.pdf Celotno besedilo (14,25 MB)
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10.
Novel ultra-high-performance concrete (UHPC) enhanced by superhydrophobic and self-luminescent features
Ahmad Rizwan Mumtaz, Natalija Bede Odorčić, Núria Garro, Samo Lubej, Andrej Ivanič, Antonio Comite, Marcello Pagliero, Gregor Kravanja, 2024, izvirni znanstveni članek

Opis: This study explores the potential of using basalt reinforced UHPC by incorporating simultaneously self-cleaning and self-luminescent features, paving the way for sustainable advancements in civil engineering. New green formulations of UHPC were developed by integrating supplementary cementitious materials and optimizing water to the binder ratio, followed by using basalt fibers to enhance strength and ductility. The fabricated samples with high particle-packing density exhibit sufficient workability and compressive strength up to 136 MPa, and, when incorporating basalt fibers, a notable reduction in brittleness. The inner microstructure of basalt fibers was observed to be smooth, homogeneously distributed, and well adhered to the UHPC matrix. To ensure the desired long-lasting visual appearance of decorative UHPC and reduce future maintenance costs, a time-effective strategy for creating a light-emitting biomimetic surface design was introduced. The samples exhibit high surface roughness, characterized by micro to nano-scale voids, displaying superhydrophobicity with contact angles reaching up to 155.45°. This is accompanied by roll-off angles decreasing to 7.1°, highlighting their self-cleaning features. The self-luminescence feature showcased intense initial light emission, offering a potential energy-efficient nighttime lighting solutio
Ključne besede: UHPC, basalt fibers, mechanical properties, morphology, superhydrophobic, self-luminescence
Objavljeno v DKUM: 29.01.2024; Ogledov: 368; Prenosov: 457
.pdf Celotno besedilo (14,47 MB)
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