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1.
The influence of thread twist on alterations in fibers` mechanucl properties
Andreja Rudolf, Jelka Geršak, 2006, izvirni znanstveni članek

Opis: In order to design high-quality threads, it is necessary to know the properties of threads and fibers, as well as the loadings and deformations which may occur during the sewing process. Thread properties depend on the mechanical properties of the fiber and the constructional parameters of the thread and its surface treatment, which directly influence sewing performance.The mechanical properties of a thread primarily depend on the fiber mechanical properties and the amount of twist. Knowledge of the thread dynamic loadings during the sewing process, depending on the number of turns and the lubrication method, is important for planning the required processing properties of the thread. This paper presents research into the influence of thread twist and the lubrication method on the mechanical properties and dynamic load of PES core-spun thread and its fibers. Research into the mechanical properties of the different twisted and surface treated threads, and separated fibers was carried out for this purpose. The influence of threaddynamic load during a sewing process was also researched regarding any alterations in the mechanical properties of the threads and separated fibers. Analyses of the results show that the amount of twist depends on the mechanical properties of the thread and its constituent fibers, whilst the method of surface treatment is based on the specific mechanical properties of the thread. A dynamic load causes greater or smaller thread deformations, which is reflected in changes in the thread and fiber mechanical properties. The occurred changes depend on dynamic load, amount of twist, and the lubrication method, which is confirmed with statistical analysis of the measured results.
Ključne besede: garment manufacturing, sewing, threads, textile fibres, surface treatment, dynamic loads, mechanical properties, amount of twist
Objavljeno: 30.05.2012; Ogledov: 1605; Prenosov: 20
URL Povezava na celotno besedilo

2.
The interaction ability of cellulosic materials as a function of fine structure and Helmholtz surface energy
Tatjana Kreže, Karin Stana-Kleinschek, Volker Ribitsch, Zdenka Peršin, Majda Sfiligoj-Smole, 2005, izvirni znanstveni članek

Opis: Many chemical or physical modification processes significantly influence the accessibility of fiber forming polymers by causing structural changes. The wettability and sorption ability improvements of polymeric materials are major tasks during finishing processes. Different pre-treatment processes are used in order to improve the accessibility of dissociable groups, hydrophilicity, dyeability, and whiteness. These are usually alkaline purification, chemical bleaching and mercerization. In a previous paper we presented the data for structural characteristics (density, crystallinity index, molecular orientation, void volume, diameter and the specific inner surface of void, etc.) of untreated regenerated cellulose fibers (viscose, modal and lyocell) [41]. We now compare the influence of different pre-treatment processes on fiber structure and the accessibility of the chemical groups of these fibers. In order to improve the accessibility, two pre-treatment processes were used: chemical bleaching of fibers and tensionless alkali treatment. The influence of these pre-treatment processes on the structure parameters was evaluated using viscosity measurements (determination of polymerization degree (DIN 54 270)) and iodine sorption ability measurements according to the Schwertassek method (determination of crystallinity index) [13, 16]. The reactivity and accessibility in a polar environment was determined using tensiometry. Contact angles between the fibers and liquids of different polarities were determined using the powder contact angle method and calculated from a modified Washburn equation [26, 28]. The surface free (Helmholtz) energy of differently treated fibers was determined from the contact angle data using the Owens-Wendt-Raeble-Kaelble approximation [30, 33, 35]. The differences in the accessibility of raw and pre-treated regenerated cellulose fibers obtained using tensiometry are compared with the results of the conventional method used to determine moisture adsorption (DIN 54 351, DIN 53 802). In regard to raw fibers, viscose shows the most hydrophilic characteristic: adsorbs the highest amount of moisture, has the fastest penetration velocities (Fig. 6), the smallest contact angle, and the highest SFE (Fig. 8). Modal fibers have the largest contact angle, the lowest SFE, and they adsorb the smallest amount of water vapor. Pre-treatments increase the sorption ability and the surface free (Helmholtz) energy while they decrease the contact angle. This makes the material more accessible to water and chemicals used in the finishing processes although the crystallinity index increases. The main modification in polymer properties caused by the treatments is an increase in the fiber SFE caused by an increase of the fiber surfaces because of swelling in the alkaline medium (washing, slack-mercerization), and due to an increase of accessible OH- and COOH-groups (bleaching). This enables the formation of an increased number of hydrogen bridges between the water molecules and the OH- and COOH-groups. Our investigations confirm the results published earlier thatthe main property necessary for the proper sorption behavior of cellulose materials are the accessible, less ordered regions and not the degree of crystallinity.
Ključne besede: regenerated cellulose fibers, fiber pre-treatment, iodine sorption, cristallinity, tensiometry, contact angle, Helmholtz surface energy, water adsorption
Objavljeno: 01.06.2012; Ogledov: 1796; Prenosov: 43
URL Povezava na celotno besedilo

3.
Protein adsorption on various plasma-treated polyethylene-terephthalate substrates
Nina Recek, Morana Jaganjac, Metod Kolar, Lidija Milković, Miran Mozetič, Karin Stana-Kleinschek, Alenka Vesel, 2013, izvirni znanstveni članek

Opis: Protein adhesion and cell response to plasma-treated polymer surfaces were studied. The polymer polyethylene terephthalate (PET) was treated in either an oxygen plasma to make the surface hydrophilic, or a tetrafluoromethane CF4 plasma to make the surface hydrophobic. The plasma source was radiofrequency (RF) discharge. The adsorption of albumin and other proteins from a cell-culture medium onto these surfaces was studied using a quartz crystal microbalance (QCM), X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). The cellular response to plasma-treated surfaces was studied as well using an MTT assay and scanning electron microscopy (SEM). The fastest adsorption rate was found on the hydrophilic oxygen plasma-treated sample, and the lowest was found on the pristine untreated sample. Additionally, the amount of adsorbed proteins was higher for the oxygen-plasma-treated surface, and the adsorbed layer was more viscoelastic. In addition, cell adhesion studies support this finding because the best cell adhesion was observed on oxygen-plasma-treated substrates.
Ključne besede: oxygen and fluorine plasma treatment, polymer surface modification, protein adsorption, cell adhesion, quartz crystal microbalance, QCM
Objavljeno: 22.06.2017; Ogledov: 342; Prenosov: 222
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