1. The ǂeffect of fuel quality on cavitation phenomena in common-rail diesel injector—a numerical studyLuka Kevorkijan, Ignacijo Biluš, Eloisa Torres Jiménez, Luka Lešnik, 2024, izvirni znanstveni članek Opis: Plastic is one of the most widely used materials worldwide. The problem with plastic
arises when it becomes waste, which needs to be treated. One option is to transform plastic waste
into synthetic fuels, which can be used as replacements or additives for conventional fossil fuels
and can contribute to more sustainable plastic waste treatment compared with landfilling and other
traditional waste management processes. Thermal and catalytic pyrolysis are common processes
in which synthetic fuels can be produced from plastic waste. The properties of pyrolytic oil are
similar to those of fossil fuels, but different additives and plastic stabilizers can affect the quality
of these synthetic fuels. The quality of fuels and the permissible particle sizes and number density
are regulated by fuel standards. Particle size in fuels is also regulated by fuel filters in vehicles,
which are usually designed to capture particles larger than 4 µm. Problems can arise with the
number density (quantity) of particles in synthetic fuels compared to that in fossil fuels. The present
work is a numerical study of how particle size and number density (quantity) influence cavitation
phenomena and cavitation erosion (abrasion) in common-rail diesel injectors. The results provide
more information on whether pyrolysis oil (synthetic fuel) from plastic waste can be used as a
substitute for fossil fuels and whether their use can contribute to more sustainable plastic waste
treatments. The results indicate that the particle size and number density slightly influence cavitation
phenomena in diesel injectors and significantly influence abrasion.
Ključne besede: plastic waste, synthetic fuels, pyrolytic oil, common rail, cavitation, erosion, particles
Objavljeno v DKUM: 05.07.2024; Ogledov: 131; Prenosov: 10
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2. Obtaining the synthetic fuels from waste plastic and their effect on cavitation formation in a common-rail diesel injectorLuka Kevorkijan, Amalia Palomar-Torres, Eloisa Torres Jiménez, Carmen Mata, Ignacijo Biluš, Luka Lešnik, 2023, izvirni znanstveni članek Opis: The presented paper addresses two significant issues of the present time. In general, the studies of the effect of synthetic fuels on cavitation formation and cavitation erosion prediction in the nozzle tip of common-rail diesel injectors were addressed. The first problem is plastic waste, which can have a significant negative environmental impact if not treated properly. Most plastic waste has high energy value, so it represents valuable material that can be used in resource recovery to produce various materials. One possible product is synthetic fuel, which can be produced using thermal and catalytic pyrolysis processes. The first issue addressed in the presented paper is the determination of fuel properties since they highly influence the fuel injection process, spray development, combustion, etc. The second is the prediction of cavitation development and cavitation erosion in a common-rail diesel injector when using pyrolytic oils from waste plastic. At first, pyrolytic oils from waste high- and low-density polyethylene were obtained using thermal and catalytic pyrolysis processes. Then, the obtained oils were further characterised. Finally, the properties of the obtained oils were implemented in the ANSYS FLUENT computational program and used in the study of the cavitation phenomena inside an injection nozzle hole. The cavitating flow in FLUENT was calculated using the Mixture Model and Zwart-Gerber-Belamri cavitation model. For the modelling of turbulence, a realisable k–ε model with Enhanced Wall Treatment was used, and an erosion risk indicator was chosen to compare predicted locations of cavitation erosion. The results indicate that the properties of the obtained pyrolytic oils have slightly lower density, surface tension and kinematic viscosity compared to conventional diesel fuel, but these minor differences influence the cavitation phenomenon inside the injection hole. The occurrence of cavitation is advanced when pyrolytic oils are used, and the length of cavitation structures is greater. This further influences the shift of the area of cavitation erosion prediction closer to the nozzle exit and increases its magnitude up to 26% compared to diesel fuel. All these differences have the potential to further influence the spray break-up process, combustion process and emission formation inside the combustion chamber.
Ključne besede: plastic waste, synthetic fuels, pyrolytic oils, common-rail, cavitation, erosion, transient simulation
Objavljeno v DKUM: 18.03.2024; Ogledov: 299; Prenosov: 14
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3. Degradation of polyvinyl chloride (PVC) waste with supercritical waterMaja Čolnik, Petra Kotnik, Željko Knez, Mojca Škerget, 2022, izvirni znanstveni članek Opis: The chemical degradation of PVC waste in SCW between 400 and 425 °C and reaction times from 30 to 60 min was studied. The PVC waste in SCW decomposed into the gas, oil, water soluble, and solid phases. The highest yield of the gas and oil phases was achieved at the temperature of 425 °C after 60 min. By increasing the reaction time at 400 °C, the yield of chloride ions in the aqueous phase increased and reached the maximum at 60 min. The gas and oil phases contained many valuable compounds similar to crude oil. Alkanes and chloroalkanes; alkenes, alicyclic, and aromatic hydrocarbons; as well as alcohols were the main groups of hydrocarbons in the oil phase, while the gas phase contained only light hydrocarbons (C1–C6), CO2, and small amounts of H2. This confirmed that the largest chlorine content remains in the aqueous phase and does not pass into the gas phase. It can be concluded that SCW presents effective decomposition media for plastic waste.
Ključne besede: polyvinyl chloride, supercritical water, chemical recycling, plastic waste
Objavljeno v DKUM: 18.09.2023; Ogledov: 513; Prenosov: 26
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