Iskanje po katalogu digitalne knjižnice

Opis: Bio-based poly(lactic acid) (PLA) composite films were produced using unmodified soda micro- or nano-lignin as a green filler at four different contents, between 0.5 wt% and 5 wt%. The PLA– lignin composite polymers were synthesized by solvent casting to prepare a masterbatch, followed by melt mixing. The composites were then converted into films, to evaluate the effect of lignin content and size on their physicochemical and mechanical properties. Differential scanning calorimetry (DSC), supported by polarized light microscopy (PLM), infrared spectroscopy (FTIR-ATR), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were employed to investigate the PLA crystallization and the interactions with Lignin (L) and Nanolignin (NL). The presence of both fillers (L and NL) had a negligible effect on the glass transition temperature (chain diffusion). However, it resulted in suppression of the corresponding change in heat capacity. This was indicative of a partial immobilization of the PLA chains on the lignin entities, due to interfacial interactions, which was slightly stronger in the case of NL. Lignin was also found to facilitate crystallization, in terms of nucleation; whereas, this was not clear in the crystalline fraction. The addition of L and NL led to systematically larger crystallites compared with neat PLA, which, combined with the higher melting temperature, provided indications of a denser crystal structure in the composites. The mechanical, optical, antioxidant, and surface properties of the composite films were also investigated. The tensile strength and Young’s modulus were improved by the addition of L and especially NL. The UV-blocking and antioxidant properties of the composite films were also enhanced, especially at higher filler contents. Importantly, the PLA–NL composite films constantly outperformed their PLA–L counterparts, due to the finer dispersion of NL in the PLA matrix, as verified by the TEM micrographs. These results suggest that bio-based and biodegradable PLA films filled with L, and particularly NL, can be employed as competitive and green alternatives in the food packaging industry.
Ključne besede: poly(lactic acid), PLA, lignin, nanolignin, composite films, nucleation, mechanical properties, antioxidant activity, food packaging
Objavljeno v DKUM: 26.03.2025; Ogledov: 0; Prenosov: 0
Celotno besedilo (9,96 MB)
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Opis: Štore Steel Ltd. is one of the biggest flat spring steel producers in Europe. The main motive for this study was to study the influences of non-metallic inclusions on mechanical properties obtained by tensile testing. From January 2016 to December 2021, all available tensile strength data (472 cases–472 test pieces) of 17 low alloy steel grades, which were ordered and used by the final user in rolled condition, were gathered. Based on the geometry of rolled bars, selected chemical composition, and average size of worst fields non-metallic inclusions (sulfur, silicate, aluminium and globular oxides), determined based on ASTM E45, several models for tensile strength, yield strength, percentage elongation, and percentage reduction area were obtained using linear regression and genetic programming. Based on modeling results in the period from January 2022 to April 2022, five successively cast batches of 30MnVS6 were produced with a statistically significant reduction of content of silicon (t-test, p < 0.05). The content of silicate type of inclusions, yield, and tensile strength also changed statistically significantly (t-test, p < 0.05). The average yield and tensile strength increased from 458.5 MPa to 525.4 MPa and from 672.7 MPa to 754.0 MPa, respectively. It is necessary to emphasize that there were no statistically significant changes in other monitored parameters.
Ključne besede: mechanical properties, tensile test, tensile strength, yield strength, percentage elongation, percentage reduction area, low alloy steel, modeling, linear regression, genetic programming, industrial study, steel making, optimization
Objavljeno v DKUM: 24.03.2025; Ogledov: 0; Prenosov: 0
Celotno besedilo (3,72 MB)
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Opis: In this paper, the Conditional Average Estimator artificial neural network (CAE ANN) was used to analyze the influence of chemical composition in conjunction with selected process parameters on the yield strength and elongation of an extruded 6082 aluminum alloy (AA6082) profile. Analysis focused on the optimization of mechanical properties as a function of casting temperature, casting speed, addition rate of alloy wire, ram speed, extrusion ratio, and number of extrusion strands on one side, and different contents of chemical elements, i.e., Si, Mn, Mg, and Fe, on the other side. The obtained results revealed very complex non-linear relationships between all of these parameters. Using the proposed approach, it was possible to identify the combinations of chemical composition and process parameters as well as their values for a simultaneous increase of yield strength and elongation of extruded profiles. These results are a contribution of the presented study in comparison with published research results of similar studies in this field. Application of the proposed approach, either in the research and/or in industrial aluminum production, suggests a further increase in the relevant mechanical properties.
Ključne besede: AA6082, hot extrusion, mechanical properties, yield strength, elongation, artificial neural networks, analysis
Objavljeno v DKUM: 12.03.2025; Ogledov: 0; Prenosov: 0
Celotno besedilo (4,40 MB)
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Opis: Furanoate polyesters are an extremely promising new class of materials for packaging applications, particularly furanoate-based nanocomposites, which have gained a high interest level in research and development in both academia and industries. The monomers utilised for the synthesis of furanoate-based polyesters were derived from lignocellulosic biomass, which is essential for both eco-friendliness and sustainability. Also, these polyesters have a lower carbon footprint compared to fossil-based plastics, contributing to greenhouse gas reduction. The furanoate-based nanocomposites exhibit enhanced performance characteristics, such as high thermal stability, excellent mechanical strength, superior barrier resistance, and good bacteriostatic rate, making them suitable for a wide range of industrial applications, especially for food-packaging applications. This paper reviews the recent trends in the synthesis routes of monomers, such as the various catalytic activities involved in the oxidation of 5(hydroxymethyl)furfural (HMF) into 2,5-furandicarboxylic acid (FDCA) and its ester, dimethyl furan-2,5-dicarboxylate (DMFD). In addition, this review explores the fabrication of different furanoate-based nanocomposites prepared by in situ polymerization, by melt mixing or solvent evaporation methods, and by using different types of nanoparticles to enhance the overall material properties of the resulting nanocomposites. Emphasis was given to presenting the effect of these nanoparticles on the furanoate polyester’s properties.
Ključne besede: 2, 5-furandicarboxylic acid, dimethyl furan-2, 5-dicarboxylat, furanoate polyesters, furanoate nanocomposites, thermal properties, mechanical properties, antibacterial properties, sustainable packaging
Objavljeno v DKUM: 10.03.2025; Ogledov: 0; Prenosov: 4
Celotno besedilo (4,54 MB)
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Opis: This work aimed to produce bio-based poly(ethylene furanoate) (PEF) with a high molecular weight using 2,5-furan dicarboxylic acid (FDCA) or its derivative dimethyl 2,5-furan dicarboxylate (DMFD), targeting food packaging applications. The effect of monomer type, molar ratios, catalyst, polycondensation time, and temperature on synthesized samples’ intrinsic viscosities and color intensity was evaluated. It was found that FDCA is more effective than DMFD in producing PEF with higher molecular weight. A sum of complementary techniques was employed to study the structure– properties relationships of the prepared PEF samples, both in amorphous and semicrystalline states. The amorphous samples exhibited an increase in glass transition temperature of 82–87 ◦C, and annealed samples displayed a decrease in crystallinity with increasing intrinsic viscosity, as analyzed by differential scanning calorimetry and X-ray diffraction. Dielectric spectroscopy showed moderate local and segmental dynamics and high ionic conductivity for the 2,5-FDCA-based samples. The spherulite size and nuclei density of samples improved with increased melt crystallization and viscosity, respectively. The hydrophilicity and oxygen permeability of the samples were reduced with increased rigidity and molecular weight. The nanoindentation test showed that the hardness and elastic modulus of amorphous and annealed samples is higher at low viscosities due to high intermolecular interactions and degree of crystallinity.
Ključne besede: bio-based polymers, poly(ethylene furanoate), polycondensation, thermal properties, mechanical properties, oxygen transmission rates
Objavljeno v DKUM: 13.02.2025; Ogledov: 0; Prenosov: 3
Celotno besedilo (13,28 MB)
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