Iskanje po katalogu digitalne knjižnice

Opis: In the pursuit of environmental sustainability, reduced emissions, and alignment with circular economy principles, bio-epoxy resin nanocomposites have emerged as a promising alternative to traditional petroleum-based resins. This study investigates the development of novel bio-epoxy nanocomposites incorporating iron-oxide nanoparticles (Fe2O3, MnP) as multifunctional fillers at loadings of 0.5 wt.% and 3.0 wt.%. MnP nanoparticles were synthesized and subsequently functionalized with citric acid (MnP-CA) to enhance their surface properties. Comprehensive characterization of MnP and MnP-CA was performed using X-ray diffraction (XRD) to determine the crystalline structure, attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR), thermogravimetric analysis (TGA), and zeta potential measurements to confirm surface functionalization. The bio-epoxy resins matrix (bio-EP), optimized for compatibility with MnP and MnP-CA, was thoroughly analyzed in terms of chemical structure, thermal stability, curing behavior, dynamic–mechanical properties, and surface characteristics. Non-isothermal differential scanning calorimetry (DSC) was employed to evaluate the curing kinetics of both the neat (bio-EP) and the MnP/MnP-CA-reinforced composites, offering insights into the influence of nanoparticle functionalization on the resin system. Surface zeta potential measurements further elucidated the effect of filler content on the surface charge and hydrophilicity. Magnetic characterization revealed superparamagnetic behavior in all MnP- and MnP-CA-reinforced (bio-EP) composites. This research provides a foundational framework for the design of green bio-epoxy nanocomposites, demonstrating their potential as environmentally friendly materials and representing an emerging class of sustainable alternatives. The results underscore the viability of bio-epoxy systems as a transformative solution for advancing sustainable resin technologies across eco-conscious industries.
Ključne besede: bio-based epoxy (nano)composites, curing behavior, dynamic mechanical properties, surface properties
Objavljeno v DKUM: 06.08.2025; Ogledov: 0; Prenosov: 3
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Opis: Interpenetrating phase composites (IPC) are materials with two or more mutually continuous, interconnected phases. This structure allows each phase to retain its properties, while together they exhibit enhanced synergistic properties. In this work, polymer-metal IPCs with Triply Periodical Minimal Surface (TPMS) structures were fabricated and tested for their mechanical properties at different impact velocities (ranging from 0.1 mm/s to 250 m/s). Samples. The samples comprise a stainless steel reinforcement phase and two polymeric matrices (silicone and epoxy). Computed tomography was used to evaluate the internal structure and the fabrication quality. The results showed that the samples were thoroughly infiltrated with polymeric filler, achieving a high degree of homogeneity in the composite. The compression tests of silicone-filled IPCs showed an increase in stiffness. Still, the Specific Energy Absorption (SEA) was not improved due to the non-optimal stiffness ratio between the polymeric matrix and the metallic reinforcement phase. However, using epoxy as the matrix resulted in the SEA enhancement of 38 %. This is attributed to the interlocking mechanism between the two phases, which improved the macroscopic mechanical properties. The compression tests showed significant strain rate hardening due to the base material’s strain rate sensitivity and the inertia effects.
Ključne besede: TPMS, interpenetrating phase composite, polymer filler, hybrid structure, experimental testing, mechanical properties, strain rate effect
Objavljeno v DKUM: 26.05.2025; Ogledov: 0; Prenosov: 13
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Opis: A conventional compound fabric was used to develop a modern, multifunctional material with an auxetic behaviour and a tailored open area for particle filtration. Such material was produced using traditional textile technology and laser cutting, to induce a rotating squares unit geometry. The behaviour was investigated of three different rotating unit cell sizes. The laser slit thickness and the length of the hinges were equal for all three-unit cells. The tensile properties, Poisson’s ratio and auxetic behaviour of the tested samples were investigated, especially the influence of longitudinal displacement on the fabric’s open area and the filtered particle sizes (average and maximum). Results show that the developed compound fabric possesses an average negative Poisson’s ratio of up to −1, depending on the applied auxetic geometry. The larger rotating cell size samples offer a higher average negative Poisson’s ratio and a higher breaking strength due to the induced slits. The findings highlight the usefulness of patterned cuts in conventional textile materials to develop advanced auxetic textile materials with tailored geometrical and mechanical properties.
Ključne besede: compound textile material, auxetic structure, open area, filtration, mechanical properties, Poisson’s ratio
Objavljeno v DKUM: 25.03.2025; Ogledov: 0; Prenosov: 6
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Opis: This study presents the synthesis and characterization of a series of multiblock copolymers, poly(ethylene 2,5-furandicarboxylate)-poly(ε-caprolactone) (PEF-PCL), created through a combination of the two-step melt polycondensation method and ring opening polymerization, as sustainable alternatives to fossil-based plastics. The structural confirmation of these block copolymers was achieved through Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), ensuring the successful integration of PEF and PCL segments. X-ray Photoelectron Spectroscopy (XPS) was employed for chemical bonding and quantitative analysis, providing insights into the distribution and compatibility of the copolymer components. Differential Scanning Calorimetry (DSC) analysis revealed a single glass transition temperature (Tg), indicating the effective plasticizing effect of PCL on PEF, which enhances the flexibility of the copolymers. X-ray Diffraction (XRD) studies highlight the complex relationship between PCL content and crystallization in PEF-PCL block copolymers, emphasizing the need to balance crystallinity and mechanical properties for optimal material performance. Broadband Dielectric Spectroscopy (BDS) confirmed excellent distribution of PEF-PCL without phase separation, which is vital for maintaining consistent material properties. Mechanical properties were evaluated using Nanoindentation testing, demonstrating the potential of these copolymers as flexible packaging materials due to their enhanced mechanical strength and flexibility. The study concludes that PEF-PCL block copolymers are promising candidates for sustainable packaging solutions, combining environmental benefits with desirable material properties.
Ključne besede: poly(ethylene furanoate), poly(ε-caprolactone), block copolymers, thermal properties, molecular dynamics, crystallinity, mechanical properties, flexible packaging
Objavljeno v DKUM: 13.03.2025; Ogledov: 0; Prenosov: 6
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Opis: There is a need to develop new construction materials with improved mechanical performance and durability that are low-priced and have environmental benefits at the same time. This paper focuses on the rheological, mechanical, morphological, and durability properties of synthetic and steel fiber reinforced self-compacting concrete (SCC) containing 5–15% metakaolin (M) by mass as a green replacement for Portland cement. Testing of the fresh mixes included a slump-flow test, density, and porosity tests. Mechanical properties were determined through compression and flexural strength. A rapid chloride penetrability test (RCPT) and the chloride migration coefficient were used to assess the durability of the samples. A scanning electron microscope (SEM) with energy dispersion spectrometry (EDS) was used to study the concrete microstructure and the interfacial transition zone (ITZ). The results show that a combination of metakaolin and hybrid fibers has a negative effect on the flowability of SCC. In contrast, the inclusion of M and hybrid fibers has a positive effect on the compressive and flexural strength of SCC. The fracture of SCC samples without fibers was brittle and sudden, unlike the fiber-reinforced SCC samples, which could still transfer a considerable load with increasing crack mouth opening deflection. Overall, the chloride migration coefficients were reduced by up to 71% compared to the control mix. The chloride reduction is consistent with the resulting compact concrete microstructure, which exhibits a strong bond between fibers and the concrete matrix.
Ključne besede: self-compacting concrete, synthetic and steel fibers, metakaolin, rheology, mechanical properties, chloride penetration, SEM-EDS
Objavljeno v DKUM: 12.03.2025; Ogledov: 0; Prenosov: 3
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