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1.
Influence of internal disorder on the superconducting state in the organic layered superconductor [kappa]-(BEDT-TTF)[sub]2Cu[N(CN)[sub]2]Br
Marko Pinterić, Silvija Tomić, Mladen Prester, Đuro Drobac, Kazumi Maki, 2002, izvirni znanstveni članek

Opis: We report high-sensitivity AC susceptibility measurements of the penetration depth in the Meissner state of the layered organic superconductor ▫$kappa$▫-(BEDT-TTF)▫$_2$▫Cu[N(CN)▫$_2$▫]Br. We have studied nominally pure single crystals from the two different syntheses and employed controlled cooling procedures in order to minimize intrinsic remnant disorder at low temperatures associated with the glass transition, caused by ordering of the ethylene moieties in BEDT-TTF molecule at ▫$T_{text{G}}$▫ = 75°K. We find that the optimal cooling procedures (slow cooling of -0.2°K/h or annealing for 3 days in the region of ▫$T_{text{G}}$▫) needed to establish the ground state, depend critically on the sample origin indicating different relaxationtimes of terminal ethylene groups. We show that, in the ground state, the behavior observed for nominally pure single crystals from both syntheses is consistent with unconventional $d$-wave order parameter. The in-plane penetration depth ▫$lambda_{text{in}}(T)$▫ is strongly linear, whereas the out-of-plane component ▫$lambda_{text{out}}(T)$▫ varies as ▫$T^2$▫. In contrast, the behavior of single crystals with long relaxation times observed after slow (-0.2°K/h) cooling is as expected for a $d$-wave superconductor with impurities (textit{i.e.} ▫$lambda_{text{in}}(T) proptolambda_{text{out}}(T) propto T^2$▫) or might be also reasonably welldescribed by the ▫$s$▫-wave model. Our results might reconcile the contradictory findings previously reported by different authors.
Ključne besede: solid state physics, organic superconductors, magnetic measurements
Objavljeno: 01.06.2012; Ogledov: 960; Prenosov: 19
URL Povezava na celotno besedilo

2.
Synthesis, crystal structure and magnetic properties of a new hydroxylammonium fluoroferrate
Brina Dojer, Matjaž Kristl, Zvonko Jagličić, Amalija Golobič, Marta Kasunič, Mihael Drofenik, 2012, izvirni znanstveni članek

Opis: This paper reports on the synthesis of a new hydroxylammonium fluoroferrate, with the formula $(NH_3OH)_3FeF_6$, obtained after dissolving iron powder in hydrofluoric acid and adding solid $NH_3OHF$. This new compound has been characterized by chemical and thermal analysis, single-crystal X-ray diffraction, and magnetic measurements. The title compound crystallizes trigonal, R3c, with cell parameters a = 11.4154(2) Å, c = 11.5720(2) Å, Z = 6. The structure consists of $NH_3OH^+$ cations and isolated $FeF_6^{3–}$ octahedra in which the central ion lies on a threefold axis. The oxygen and nitrogen atoms of the hydroxylammonium cations are donors of hydrogen bonds to fluoride anions, resulting in a network of hydrogen bonds between counterions. The effective magnetic moment $µ_{eff}$ = 5.8 BM was calculated and perfectly matches the expected value of high-spin Fe(III) ions. The thermal decomposition of the compound was studied by TG, DSC, and X-ray powder diffraction.
Ključne besede: inorganic chemistry, crystallography, coordination compounds, synthesis, crystal structure, characterization of compounds, determination of the structure of compounds, X-ray diffraction, magnetic measurements, thermal analysis, TG, DSC, hydrogen bond, metal complexes, hydroxylammonium fluoromethalatehydroxylammonium, fluoroferrate
Objavljeno: 25.08.2017; Ogledov: 727; Prenosov: 36
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