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1.
Tuning of poly(ethylene terephtalate)(PET)surface properties by oxygen plasma treatment
Aleš Doliška, Metod Kolar, 2011, izvirni znanstveni članek

Opis: Modification of surface properties of poly(ethyleneterephtalate) (PET) thin films by treatment with weakly ionized oxygen plasma was studied by contact angles of water and diiodomethane (DIM) drops. Samples were exposed to oxygen plasma with the ion density of 5 x 1015/m[sup]3 and the neutral oxygen atom density of 3 x 1021/m[sup]3. Just after the treatment they were characterized by contact angle measurements. Results showed a quick decrease of the water contact angle in the first few seconds of plasma treatment, while prolonged treatment did not cause any substantiated modification. The contact angles of DIM, on the other hand, remained rather constant for the first several secondsof plasma treatment, and increased after prolonged treatment. It was found that the dispersion component of the surface free energy decreased with increasing treatment time, while the polar component increased with treatment time. The results were explained by surface functionalization as well as by roughness effects.
Ključne besede: poly(ethylene terephtalante), PET, oxygen plasma, contact angle, hydrophilic, functionalization
Objavljeno: 01.06.2012; Ogledov: 1433; Prenosov: 43
.pdf Celotno besedilo (329,87 KB)
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2.
Acrylic acid "reversed" polyHIPEs
Peter Krajnc, Dejan Štefanec, Irena Pulko, 2005, izvirni znanstveni članek

Opis: An oil-in-water high internal phase emulsion consisting of acrylic acid, water, and a crosslinker (N,N-methylene bisacrylamide) as the water phase, and toluene as the oil phase was successfully stabilised to sustain thermal initiation of radical polymerisation resulting in porous open-cellular monolithic material. The type of initiator used influenced the average pore size ranging from approx. 708 nm to approx. 1 087 nm, as determined by mercury porosimetry.
Ključne besede: hydrophilic polymers, macroporous polymers, poly (acrylic acid), polyHIPE, supports
Objavljeno: 01.06.2012; Ogledov: 1718; Prenosov: 80
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