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1.
A new method for testing the anti-permeability strength of clay failure under a high water pressure
Fu-wei Jiang, Ming-tang Lei, Xiao-zhen Jiang, 2015, izvirni znanstveni članek

Opis: It is difficult to judge the failure of clay seepage under a high water pressure.This paper presents a new method to assess clay failure based on the anti-permeability strength, which is the critical water pressure to destroy the clay. An experiment is designed to test the value that avoids the problem of the time-consuming, traditional method to test clay seepage deformation. The experimental system and the process of testing are introduced in this paper. With a self-designed experimental system and method, 18 groups of sample were tested. The results show that the clay thickness and the seepage paths influence the anti-permeability strength. It also indicates that water infiltrates into the clay under the condition that its pressure exceeds a minimum value (P0).
Ključne besede: clay failure, seepage deformation, anti-permeability strength, high water pressure
Objavljeno v DKUM: 15.06.2018; Ogledov: 871; Prenosov: 43
.pdf Celotno besedilo (249,24 KB)
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2.
Stability of proteinase from Carica papaya latex in dense gases
Maja Leitgeb, Mateja Primožič, Željko Knez, 2005, izvirni znanstveni članek

Opis: Proteinase from Carica papaya latex was tested on its thermal stability at atmospheric pressure and in supercritical carbon dioxide, near-critical propane and dimethyl-ether. In supercritical carbon dioxide at 300 bar thermalactivation of the examined proteinase was improved in the comparison toatmospheric pressure. In propane and dimethyl-ether (300 bar) activity of the examined proteinase decreased. Influence of compressionžexpansion cycles on residual activity of the same proteinase in supercritical carbon dioxide (300 bar and 50 °C) was studied, as well. Different ways of transition from supercritical to low-pressure-state were used which affected residual activityof the proteinase.Addition of water in the system increased activity of proteinase from C. papaya, which was incubated in supercritical carbon dioxide for 24 h. Optimum amount of water was found to be between 0.5 and 0.7 g/L.
Ključne besede: chemical processing, high pressure technology, supercritical CO2, proteinase, thermal stability, pressure stability, enzyme activity, water content, dense gases
Objavljeno v DKUM: 01.06.2012; Ogledov: 1495; Prenosov: 25
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3.
Particle formation using supercritical fluids : a short review
Željko Knez, 2006, pregledni znanstveni članek

Opis: Particle formation and the design of solid particles and powdery composites with unique properties is at the moment one of major the developments of supercritical fluid (synonyms: dense gases, dense fluids, high pressure) applications. Conventional well-known processes for the particle-size redistribution of solid materials are crushing and grinding (which for some compounds are carried out at cryogenic temperatures), air micronization, sublimation, and recrystallization from solution. There are several problems associated with the above-mentioned processes. Some substances are unstable under conventional milling conditions, in recrysfallization processes the product is contaminated with solvent and waste solvent streams are produced. The application of supercritical fluids may overcome the drawbacks of conventional processes, and powders and composites with special characteristics can be produced. Several processes for the formation and design of solid particles using dense gases have been studied intensively. The unique thermodynamic and fluid-dynamic properties of supercritical fluids can also be used for the impregnation of solid particles, for the formation of solid powderous emulsions, particle coatings, e.g. for the formation of solids with unique properties for use in different applications. This review will focus on the fundamentals and on recent advances of particle formation and design processes using supercritical fluids on their applications and the technological advantages and disadvantages of various processes.
Ključne besede: chemical processing, high pressure technology, supercritical CO2, proteinase, thermal stability, pressure stability, enzyme activity, water content, dense gases
Objavljeno v DKUM: 31.05.2012; Ogledov: 2123; Prenosov: 119
.pdf Celotno besedilo (514,21 KB)
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