1. Modeling of a premixed hydrogen-air combustion in a gas condensing boilerMarc Jäger, 2025, doktorska disertacija Opis: This work addresses the urgent need for decarbonization of heating sector, focusing
on the potential of hydrogen-air combustion in gas condensing boilers. In the field of
gas condensing boilers, groups of holes or slits can be used in perforated burner
surfaces, providing a possible solution to the challenge of hydrogen air combustion.
Real burners are always adjacent to an area with non-existent combustion, which can
lead to a disturbed flame pattern. For this reason, a comparison between single-slit
and multi-slit perforated flame holders with a significantly reduced structure
temperature with a hydrogen-air premix is carried out as part of this study. Using Ansys
Fluent, a 2D simulation approach is employed to analyze laminar flame stability behind
a perforated flame holder. Inlet conditions consider fully premixed and homogenous
distributed mixtures as well as non-homogeneous premixed mixtures, with variations
in pressure, velocity, and mixing degree. The model examines various slit-burner
configurations and flashback behaviors based on an actual geometric shape used in a
gas heating device. It has been found that with finite multi-slit burners, the bulk flow
rates at the critical flashback point are 30-50% higher compared to infinitely
symmetrical burners. A further deterioration of 32% is to be expected due to real
mixture quality fluctuations and inhomogeneous inflow conditions.
The numerical model was validated using a prototype heat exchanger and a
production-ready mixture preparation system in combination with various burner
geometries.
From a practical standpoint, the results provide clear guidance for burner design. Long
and narrow holes with moderate spacing -ideally at least one diameter apart- promote
flame stability while maintaining a compact configuration. In clustered geometries,
optimizing the number of flow passages can prevent local overheating and enhance
operational robustness. For complex or thermally sensitive geometries, the use of 3D
CFD simulations with conjugate heat transfer (CHT) coupling is strongly advised to
ensure accurate and safe designs. Additionally, at higher air excess ratios, the current
numerical model becomes less accurate due to intensified preferential diffusion and
Soret effects, highlighting the need for a 3D CFD approach using the Konnov reaction
mechanism.
Finally, the findings demonstrate the model's potential for designing efficient surface
stabilized burners and lay the groundwork for future 3D simulations in the pursuit of
sustainable heating solutions. Ključne besede: CFD, hydrogen combustion, flashback, flame stability, perforated flame holder, gas condensing boiler, experimental flashback measurements Objavljeno v DKUM: 20.01.2026; Ogledov: 0; Prenosov: 4
Celotno besedilo (11,49 MB) |
2. Fuel gas operation management practices for reheating furnace in iron and steel industryD. M. Chen, 2020, izvirni znanstveni članek Opis: How to evaluate the fuel gas operation (FGO) of various working groups (WGs) and working shifts (WSs) in reheating furnace is still ambiguous problem. In this paper, a novelty time-series FGO evaluation model was proposed. The strategy mainly included: Firstly, the fuel gas per ton steel (FGTS) was calculated in certain time interval; Secondly, the FGTS time-series data set was formulated in statistical period; Thirdly, the FGTS time-series data set was divided according to working schedule; Lastly, the FGO evaluation model was established. Case study showed that: i) The fuel gas operation evaluation results of various WGs in different WSs were accorded with normal distribution; ii) For various WGs, A WG performed best, followed by C WG and D WG. The performance of B WG was the worst due to its violent fluctuation of fuel gas operation evaluation results in three WSs; iii) For different WSs, the day WS and swing WS performed well, whereas the performance of night WS was unsatisfactory. Discussion results showed that the improvement of working skills, working responsibility and working passion, which were effective measure to achieve energy saving in terms of operation, should be enhanced through skills training and the reward and punishment system. Generally, this novelty time-series FGO evaluation method could also be applied to other industrial equipment. Ključne besede: Iron industry, steel Industry, fuel gas operation management, FGO evaluation model, reheating furnace, fuel gas per ton steel time-series, working groups Objavljeno v DKUM: 15.01.2026; Ogledov: 0; Prenosov: 0
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3. A review of analytical techniques for the analysis of oral smokeless products and heated tobacco productsMatjaž Rantaša, David Majer, Matjaž Finšgar, 2025, pregledni znanstveni članek Opis: The increasing popularity in recent years of oral smokeless products (OSPs) and heated tobacco products (HTPs) has raised significant public health and regulatory concerns. Although these products are often marketed as less harmful alternatives to traditional cigarettes, they differ considerably in both design and, more importantly, in their chemical composition. Notably, they contain potentially dangerous compounds such as tobacco-specific nitrosamines, flavorings, heavy metals, and nicotine, which can be addictive and harmful to human health at certain concentrations. This work provides an overview of the analytical techniques and methods used to analyze OSPs and HTPs, including the determination of moisture content and pH, the extraction of various compounds, the generation of HTP aerosol, and non-targeted analysis, as well as the quantification of extracted compounds using gas chromatography, liquid chromatography, and spectroscopy. Identifying and quantifying the chemical composition of OSPs and HTPs is essential for assessing their health impact and developing proper regulatory standards regarding these products. Ključne besede: gas chromatography, heated tobacco products, liquid chromatography, nicotine, oral smokeless products Objavljeno v DKUM: 13.11.2025; Ogledov: 0; Prenosov: 4
Celotno besedilo (1,70 MB) |
4. A framework to establish and operate a global logistics energy hub : doktorska disertacijaMahmoud Ahmed Abd Ellatif Hammad, 2024, doktorska disertacija Opis: Energy is an essential component of our daily lives. Despite the expanded use of new and renewable energy sources, oil and gas remain the primary sources of energy. Recently, oil and gas sources have become more vulnerable due to their limited and uncertain availability, as well as geopolitical issues that threaten the security of their supply chains. As a result, securing energy sources in general and oil and gas in particular at reasonable prices and reliable supplies has become a major global concern. As a result, the establishment and operation of energy hubs along energy transit routes between producing and consuming countries is crucial for the security and sustainability of the energy supply. These energy hubs can facilitate the trade and exchange of energy by offering logistics services such as transportation, storage, processing, and distribution. This means that establishing and operating such energy hubs necessitates some logistics requirements. However, previous studies did not tackle the logistics requirements for establishing and operating energy hubs in a single, comprehensive framework. Accordingly, the purpose of this study is to address the logistics requirements of energy hubs, with a focus on oil and gas, and to develop a comprehensive framework for establishing and operating GLEH through conducting an empirical study on the Egyptian oil and gas industry.
The study was carried out through seven sequential phases. The study conducted a systematic review of the previous literature using the PRISMA flow diagram and visual bibliometric analysis via VOSviewer software to identify the main research gap and develop an integrated theoretical framework for creating and operating a GLEH. The study then adopted mixed research methods to reap the benefits of both qualitative and quantitative methods. The qualitative technique was used to convert the theoretical framework into a practical framework by conducting semi-structured interviews with key stakeholders. The quantitative method was applied to examine the relationships between the variables and validate the study’s hypotheses in the Egyptian context through a survey.
The study set out an applied framework to help establish and operate GLEHs that can improve the security of energy supplies. It also highlighted the key challenges that might face the establishment and operation of GLEHs and suggested strategies to deal with them.
The study would contribute to science by developing a unique and comprehensive framework for establishing and operating GLEHs, considering both theoretical and empirical aspects. At a practical level, the proposed framework can help improve the global energy supply chain and its sustainability, especially for oil and gas. It can also be used as a model by other countries and regions to establish and operate logistics hubs for energy and other sectors. Furthermore, the framework can be used in further research to develop the performance of energy hubs. Ključne besede: Energy supply chain, energy sustainability and security, global logistics energy hub, oil and gas, Egypt Objavljeno v DKUM: 27.08.2025; Ogledov: 0; Prenosov: 13
Celotno besedilo (9,35 MB) |
5. The numerical analysis of flame stability in case of premixed hydrogen-air combustionMarc Jaeger, Matjaž Hriberšek, Niko Samec, Yang Guo, Xuebin Wang, Filip Kokalj, 2025, izvirni znanstveni članek Opis: This study addresses the urgent need for decarbonization of heating sector, focusing on the potential of hydrogen-air combustion in gas condensing boilers. In the field of gas condensing boilers, groups of holes or slits can be used in perforated burner surfaces, providing a possible solution to the challenge of hydrogen air combustion. Real burners are always adjacent to an area with non-existent combustion, which can lead to a disturbed flame pattern. For this reason, a comparison between single-slit and multi-slit perforated flame holders with a significantly reduced structure temperature with a hydrogen-air premix is carried out as part of this study. Using Ansys Fluent, a 2D simulation approach is employed to analyze laminar flame stability behind a perforated flame holder. Inlet conditions consider fully premixed and homogenous distributed mixtures as well as nonhomogeneous premixed mixtures, with variations in pressure, velocity, and mixing degree. The model examines various slit-burner configurations and flashback behaviors based on an actual geometric shape used in a gas heating device. It has been found that with finite multi-slit burners, the bulk flow rates at the critical flashback point are 30–50% higher compared to infinitely symmetrical burners. A further deterioration of 32% is to be expected due to real mixture quality fluctuations and inhomogeneous inflow conditions. Finally, the findings demonstrate the model’s potential for designing efficient surface-stabilized burners and lay the groundwork for future 3D simulations in the pursuit of sustainable heating solutions. Ključne besede: hydrogen combustion, flashback, flame stability, perforated flame holder, gas condensing boiler Objavljeno v DKUM: 19.05.2025; Ogledov: 0; Prenosov: 9
Celotno besedilo (6,29 MB) Gradivo ima več datotek! Več... |
6. Improving electricity generation during the product reaction loop and the use of exhaust gas for co-product production using polyethylene waste and flue gas or woodAnita Kovač Kralj, 2022, izvirni znanstveni članek Opis: More energy-efficient industries could reduce the problems of pollution, global warming,
energy security, and fossil fuel depletion, including processing waste into raw materials and more
efficient energy cogeneration. This research project considers the novelties of the upgraded electricity
cogeneration technique, including one open gas turbine during the high-pressure product reaction
loop and a second turbine during the exhaust gas for co-product production with only one compressor.
The upgraded electricity cogeneration was carried out in two steps and based on the productive use of
otherwise useless polyethylene waste, flue gas, and wood. The first step can simulate the simulation
model from the existing product production with well-known technology and process units using
the Aspen Plus® simulator. The maximum available electricity cogeneration can previously be
determined from the thermodynamics of the products and co-products, and an existing energy unit’s
characteristic capacity. In the second step, conventional natural gas can be replaced with waste
as the raw materials by using the same simulated model from the first step, including electricity
cogeneration using the gas turbines during the high-pressure reaction loop, and the exhaust gas as the
co-product with only one compressor. This research on electricity generation is based on processes
that include the pressure drop during the product reaction loop. This approach is illustrated using an
existing methanol production process, using wastes as sustainable raw materials, including electricity
cogeneration during the reaction loop and exhaust gas, generating a possible increase in annual profit
of 7.28 MEUR/a. Ključne besede: waste recovery, cogeneration, exothermic reactor, gas turbine, exhaust gas, combined compressor Objavljeno v DKUM: 15.05.2025; Ogledov: 0; Prenosov: 8
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7. Thermogravimetric, kinetic and thermodynamic behaviour of raw and hydrothermally pretreated oil cakes during pyrolysis and TG-FTIR analysis of the gaseous productsAleksandra Petrovič, Sabina Vohl, Sven Gruber, Klemen Rola, Tjaša Cenčič, Lidija Čuček, Danijela Urbancl, 2025, izvirni znanstveni članek Opis: The pyrolysis of raw and hydrothermally (HTC) pretreated pumpkin (PC) and hemp (HC) oilseed cakes was investigated for the first time using thermogravimetric, kinetic and thermodynamic analyses. The influence of the HTC pretreatment and the type of reaction liquid (whey or water) on the pyrolysis was investigated and the pyrolysis gases were analysed. The HTC pretreatment increases the biochar yield with values of up to 44 wt.% compared to raw oil cakes (∼27 wt.%). The HTC pretreatment with whey resulted in a higher energy and biochar yield and better biochar properties than the pretreatment with water. The tested oil cakes provided comparable energy yields, although HC provided higher biochar yields, while PC biochar showed higher hydrophobicity. The kinetic modelling shows that the activation energies () for the pyrolysis of the raw oil cakes varied between 93.6 and 529.9 kJ/mol for PC and between 71.3 and 669.9 kJ/mol for the HC sample. HTC pretreatment in water media increased the values, while the use of whey led to a decrease in the values. TG-FTIR analysis of the emitted gases showed that the HTC treatment affected the release of CO2 and hydrocarbons as well as the pyrolysis mechanism and reaction pathways Ključne besede: oilseed cake, hydrochar, pyrolysis, thermogravimetric analysis, kinetic analysis, gas emissions Objavljeno v DKUM: 25.04.2025; Ogledov: 0; Prenosov: 17
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8. Compatibilization of polylactide/poly(ethylene 2,5-furanoate) (PLA/PEF) blends for sustainable and bioderived packagingGiulia Fredi, Andrea Dorigato, Alessandro Dussin, Eleftheria Xanthopoulou, Dimitrios Bikiaris, Luigi Botta, Vincenzo Fiore, Alessandro Pegoretti, 2022, izvirni znanstveni članek Opis: Despite the advantages of polylactide (PLA), its inadequate UV-shielding and gas-barrier
properties undermine its wide application as a flexible packaging film for perishable items. These
issues are addressed in this work by investigating the properties of melt-mixed, fully bioderived
blends of polylactide (PLA) and poly(ethylene furanoate) (PEF), as a function of the PEF weight
fraction (1–30 wt %) and the amount of the commercial compatibilizer/chain extender Joncryl ADR
4468 (J, 0.25–1 phr). J mitigates the immiscibility of the two polymer phases by decreasing and
homogenizing the PEF domain size; for the blend containing 10 wt % of PEF, the PEF domain size
drops from 0.67 ± 0.46 µm of the uncompatibilized blend to 0.26 ± 0.14 with 1 phr of J. Moreover,
the increase in the complex viscosity of PLA and PLA/PEF blends with the J content evidences
the effectiveness of J as a chain extender. This dual positive contribution of J is reflected in the
mechanical properties of PLA/PEF blends. Whereas the uncompatibilized blend with 10 wt % of
PEF shows lower mechanical performance than neat PLA, all the compatibilized blends show higher
tensile strength and strain at break, while retaining their high elastic moduli. The effects of PEF
on the UV- and oxygen-barrier properties of PLA are also remarkable. Adding only 1 wt % of PEF
makes the blend an excellent barrier for UV rays, with the transmittance at 320 nm dropping from
52.8% of neat PLA to 0.4% of the sample with 1 wt % PEF, while keeping good transparency in the
visible region. PEF is also responsible for a sensible decrease in the oxygen transmission rate, which
decreases from 189 cc/m2
·day for neat PLA to 144 cc/m2
·day with only 1 wt % of PEF. This work
emphasizes the synergistic effects of PEF and J in enhancing the thermal, mechanical, UV-shielding,
and gas-barrier properties of PLA, which results in bioderived blends that are very promising for
packaging applications. Ključne besede: polylactide, furanoates, poly(ethylene furanoate), blends, compatibilization, gas-permeability, UV-shielding Objavljeno v DKUM: 24.03.2025; Ogledov: 0; Prenosov: 9
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9. A review of analytical techniques for the determination of e-liquid and electronic cigarette aerosol compositionMatjaž Rantaša, David Majer, Matjaž Finšgar, 2025, pregledni znanstveni članek Opis: Since the introduction of electronic cigarettes (ECs) to the global market, the composition of e-liquids has been a controversial topic. While some consider ECs to be an effective tool for quitting smoking, their primary criticism lies in the uncertain and varied composition of e-liquids. Manufacturers create the desired formulations by mixing different ratios of humectants, flavorings, nicotine, cannabinoids, and cooling agents. However, the health effects of inhaling these compounds are still not well understood. Regular analytical control of e-liquids and aerosols is crucial to gain valuable insights into e-liquid composition, generating new compounds during aerosolization, and the potential impact on human health. This work presents an overview of the analytical techniques used for the qualitative and quantitative determination of e-liquid and aerosol compounds, including a description of the methods used for aerosol collection. Gas and liquid chromatography are the most used analytical techniques for compound determination, followed by nuclear magnetic resonance spectroscopy. Additionally, inductively coupled plasma-mass spectrometry and inductively coupled plasma-optical emission spectroscopy are the most frequently used analytical techniques for elemental determination in e-liquids and their aerosols. Ključne besede: electronic cigarettes, e-liquids, aerosol, gas chromatography, high-performance liquid chromatography, inductively coupled plasma mass spectrometry Objavljeno v DKUM: 21.03.2025; Ogledov: 0; Prenosov: 9
Celotno besedilo (2,11 MB) |
10. Gas sensing system based on an all-fiber photothermal microcellMatej Njegovec, Jure Javornik, Simon Pevec, Vedran Budinski, Tomaž Gregorec, Benjamin Lang, Manuel Tanzer, Alexander Bergmann, Denis Đonlagić, 2024, izvirni znanstveni članek Opis: This article presents an all-fiber, miniature Fabry-Perot gas sensor based on photothermal absorption spectroscopy with a custom-made and cost-efficient interrogation system. The sensing gas microcell has a diameter of 125 μ m and a length of 1 mm, and allows for free gas exchange within the optical resonator through micromachined slits. High light intensity and confinement are ensured by delivering the excitation light directly into the gas microcell through a lead-in single-mode fiber. This enhances the photothermal effect and provides a short system response time. The interrogation system utilizes the modulation of an excitation laser diode with a fixed frequency while locking the probe laser onto the gas microcell’s quadrature point (QP) and observing the variations of the reflected optical power. To show the potential of the proposed system, nitrogen dioxide (NO2 was measured in dry air. Thereby, a limit of detection of 20 ppm could be achieved for 10 s integration time. Furthermore, the small dimensions of the sensor allow for improved dynamic performance with photothermal modulation frequencies as high as 7 kHz. Ključne besede: Fabry–Perot interferometer, FPI, fiber gas cell, fiber gas sensor, nitrogen dioxide, NO2, photothermal effect Objavljeno v DKUM: 29.08.2024; Ogledov: 96; Prenosov: 33
Celotno besedilo (15,77 MB) Gradivo ima več datotek! Več... |