1. Metallisation of textiles and protection of conductive layers: An overview of application techniquesAlenka Ojstršek, Olivija Plohl, Selestina Gorgieva, Manja Kurečič, Urška Jančič, Silvo Hribernik, Darinka Fakin, 2021, pregledni znanstveni članek Opis: The rapid growth in wearable technology has recently stimulated the development of
conductive textiles for broad application purposes, i.e., wearable electronics, heat generators, sensors,
electromagnetic interference (EMI) shielding, optoelectronic and photonics. Textile material, which
was always considered just as the interface between the wearer and the environment, now plays
a more active role in different sectors, such as sport, healthcare, security, entertainment, military,
and technical sectors, etc. This expansion in applied development of e-textiles is governed by a
vast amount of research work conducted by increasingly interdisciplinary teams and presented
systematic review highlights and assesses, in a comprehensive manner, recent research in the field of
conductive textiles and their potential application for wearable electronics (so called e-textiles), as
well as development of advanced application techniques to obtain conductivity, with emphasis on
metal-containing coatings. Furthermore, an overview of protective compounds was provided, which
are suitable for the protection of metallized textile surfaces against corrosion, mechanical forces,
abrasion, and other external factors, influencing negatively on the adhesion and durability of the
conductive layers during textiles’ lifetime (wear and care). The challenges, drawbacks and further
opportunities in these fields are also discussed critically. Ključne besede: metallization, conductive textiles, e-textiles, coatings techniques, protective coatings, durability Objavljeno v DKUM: 16.06.2025; Ogledov: 0; Prenosov: 5
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2. Addressing the needs of the rapidly aging society through the development of multifunctional bioactive coatings for orthopedic applicationsTinkara Mastnak, Uroš Maver, Matjaž Finšgar, 2022, pregledni znanstveni članek Opis: The unprecedented aging of the world’s population will boost the need for orthopedic
implants and expose their current limitations to a greater extent due to the medical complexity of
elderly patients and longer indwelling times of the implanted materials. Biocompatible metals with
multifunctional bioactive coatings promise to provide the means for the controlled and tailorable
release of different medications for patient-specific treatment while prolonging the material’s lifespan
and thus improving the surgical outcome. The objective of this work is to provide a review of several
groups of biocompatible materials that might be utilized as constituents for the development of
multifunctional bioactive coatings on metal materials with a focus on antimicrobial, pain-relieving,
and anticoagulant properties. Moreover, the review presents a summary of medications used in
clinical settings, the disadvantages of the commercially available products, and insight into the latest
development strategies. For a more successful translation of such research into clinical practice, extensive knowledge of the chemical interactions between the components and a detailed understanding
of the properties and mechanisms of biological matter are required. Moreover, the cost-efficiency of
the surface treatment should be considered in the development process. Ključne besede: biomaterials, orthopedic implants, multifunctional coatings, drug delivery, antimicrobial, pain relief Objavljeno v DKUM: 09.04.2025; Ogledov: 0; Prenosov: 6
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3. Synthesis of Ni/Y2O3 nanocomposite through USP and lyophilisation for possible use as coatingTilen Švarc, Srečko Stopić, Žiga Jelen, Matej Zadravec, Bernd Friedrich, Rebeka Rudolf, 2022, izvirni znanstveni članek Opis: The Ni/Y2O3 catalyst showed high catalytic activity. Based on this, the aim of this study
was to create Ni/Y2O3 nanocomposites powder with two innovative technologies, Ultrasonic Spray
Pyrolysis (USP) and lyophilisation. In the USP process, thermal decomposition of the generated
aerosols in an N2/H2 reduction atmosphere caused a complete decomposition of the nickel (II) nitrate
to elemental Ni, which became trapped on the formed Y2O3 nanoparticles. The Ni/Y2O3 nanocomposite particles were captured via gas washing in an aqueous solution of polyvinylpyrrolidone (PVP)
in collection bottles. PVP was chosen for its ability to stabilise nano-suspensions and as an effective
cryoprotectant. Consequently, there was no loss or agglomeration of Ni/Y2O3 nanocomposite material during the lyophilisation process. The Ni/Y2O3 nanocomposite powder was analysed using
ICP-MS, SEM-EDX, and XPS, which showed the impact of different precursor concentrations on the
final Ni/Y2O3 nanocomposite particle composition. In a final step, highly concentrated Ni/Y2O3
nanocomposite ink (Ni/Y2O3 > 0.140 g/mL) and test coatings from this ink were prepared by applying them on a white matte photo paper sheet. The reflection curve of the prepared Ni/Y2O3
nanocomposite coating showed a local maximum at 440 nm with a value of 39% reflection. Given that
Ni is located on the surface of the Ni/Y2O3 nanocomposite in the elemental state and according to the
identified properties, tests of the catalytic properties of this coating will be performed in the future. Ključne besede: Ultrasonic Spray Pyrolysis (USP), lyophilisation, Ni/Y2O3 nanocomposite, characterisation, coatings Objavljeno v DKUM: 20.03.2025; Ogledov: 0; Prenosov: 11
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4. Microstructure and surface topography study of nanolayered TiAlN/CrN hard coatingPeter Panjan, Peter Gselman, Matjaž Panjan, Tonica Bončina, Aljaž Drnovšek, Mihaela Albu, Miha Čekada, Franc Zupanič, 2022, izvirni znanstveni članek Opis: The microstructure and surface topography of PVD hard coatings are among the most
important properties, as they significantly determine their mechanical, tribological and other properties. In this study, we systematically analyzed the microstructure and topography of a TiAlN/CrN
nanolayer coating (NL-TiAlN/CrN), not only because such coatings possess better mechanical and
tribological properties than TiAlN and CrN monolayer coatings, mainly because the contours of the
individual layers, in the cross-sectional STEM or SEM images of such coatings, make it easier to
follow topographic and microstructural changes that occurred during its growth. We investigated
the effects of the substrate rotation modes on the microstructure and surface topography of the
NL-TiAlN/CrN coating, as well as on the periodicity of the nanolayer structure. The influence of the
substrate material and the ion etching methods were also studied, while special attention was given to
the interlayer roughness and influence of non-metallic inclusions in the steel substrates on the growth
of the coating. The topographical features of the NL-TiAlN/CrN coating surface are correlated with
the observations from the cross-sectional TEM and FIB analysis. Selected non-metallic inclusions,
covered by the NL-TiAlN/CrN coating, were prepared for SEM and STEM analyses by the focused
ion beam. The same inclusions were analyzed prior to and after deposition. We found that substrate
rotation modes substantially influence the microstructure, surface topography and periodicity of the
NL-TiAlN/CrN layer. Non-metallic inclusions in the substrates cause the formation of shallow craters
or protrusions, depending on their net removal rates during the substrate pretreatment (polishing
and ion etching), as compared to the matrix. Ključne besede: magnetron sputtering, nanolayer hard coatings, growth defects, surface topography, interlayer roughness, non-metallic inclusion, focused ion beam (FIB), scanning electron microscopy (SEM), scanning transmission electron microscopy (STEM) Objavljeno v DKUM: 19.03.2025; Ogledov: 0; Prenosov: 7
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5. Synergic effect of large MXene nanosheets and protective coatings on improved electroconductivity and wash durability of MXene/polymer-modified cotton fabricLaura Jug, Silvo Hribernik, Alenka Ojstršek, 2025, izvirni znanstveni članek Opis: E-textiles and their wearable analogues are finding applications in a myriad of sectors, ranging from sensors to health and sports applications. The development of a truly functional and reusable textile substrate presents a challenging task; its design encompasses the fabrication of optimal functional conductive particles, as well as devising strategies for their application that will ensure their functional properties (e.g. conductivity) are retained in an undiminished state for a foreseeable period. In the presented study, we tackled these two aspects in an interdependent way: i) The enhancement of the electrical conductivity of MXene-modified cotton fabric by increasing the lateral size of nanosheets during the Ti3C2TX synthesis, and ii) The improvement of washing durability of MXenes on the fabric surface by selecting suitable protective coatings. The results of Scanning Electron Microscopy (SEM), X-ray powder Diffraction (XRD), Dynamic Light Scattering (DLS) and Atomic Force Microscopy (AFM) revealed the successful synthesis of large and stable MXene nanosheets with ultrathin flakelike nanostructures, high colloidal stability and delamination yields. Using multiple application procedures of dipping and drying, the MXene nanosheets formed extensive adhesion areas on the cotton fabric and overlapped the fibre pores, thus reducing the interfacial resistance between the sheets and improving the coating uniformity and, consequently, increasing electrical conductivity. Weaker adhesion and depletion of large nanosheets were further effectively prevented by protective polymer coatings. The MXene-coated/protected fabrics had sufficient electrical conductivity, even after 20 laundering cycles. Moreover, the surface hydrophobicity was negligibly reduced, preventing water accessibility and, thus, increasing the oxidation stability of the applied MXenes. Ključne besede: Ti3C2TX MXene, synthesis parameters, cotton fabric, electrical conductivity, protective coatings, washing durability Objavljeno v DKUM: 10.03.2025; Ogledov: 0; Prenosov: 15
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6. Alginate coatings suppress unspecific protein adhesion on PVCMatej Bračič, Alenka Vesel, Lidija Fras Zemljič, 2025, izvirni znanstveni članek Opis: This study involved oxygen plasma activation of PVC and its effect on alginate coating adhesion, analyzed using a quartz crystal microbalance with dissipation (QCM-D). The results demonstrated improved adhesion of alginate on plasma-activated PVC due to an increase of oxidized functional groups. Wettability measurements, conducted using optical contact angle goniometry and QCM-D, showed a significant increase in the wettability of PVC after alginate coating, with contact angles decreasing from 81.4 ± 1.1◦ to 37.3 ± 3.1◦ 3D-profilometry mapping revealed a uniform distribution of alginate on the PVC film. Real-time antifouling studies using QCM-D with two model proteins, bovine serum albumin and bovine fibrinogen, were performed to elucidate the surface interactions involved in protein inhibition. The results indicated a substantial reduction in protein adhesion on alginate-coated PVC. This reduction in protein adhesion is attributed to the high hydrophilicity of the alginate coatings and partial removal of the alginate, which together contribute to poor protein adhesion. This comprehensive approach advances the development of effective solutions for mitigating biofilm-related issues on PVC-based medical devices, offering significant implications for improving patient outcomes. Ključne besede: alginate, coatings, polyvinyl chloride, biofouling, quartz crystal microbalance, protein adhesion Objavljeno v DKUM: 10.03.2025; Ogledov: 0; Prenosov: 10
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7. Digital transformation reduces costs of the paints and coatings development processTomaž Kern, Eva Krhač Andrašec, Benjamin Urh, Marjan Senegačnik, 2020, izvirni znanstveni članek Opis: An essential characteristic of the new product development process is to develop a new marketable product in the shortest possible time with the lowest reasonable costs. Therefore, the key factor of the process is efficiency. The paints and coatings industry development process contain numerous laboratory tests to determine the appropriateness of new formulation. It is proven that digital transformation can reduce the number of laboratory tests and consequently shorten the throughput time of the development process. This raised the question of whether the faster development process also reduces the process’ cost, or they even increase due to information and communication technology implementation. Therefore, the research’s purpose was to determine whether reducing the number of laboratory tests, based on the implementation of information and communication technology (ICT), affects reducing costs in the paints and coatings development process. The conventional process and the redesigned process of paints and coatings development were used as the basis of the research. The comparative analysis of the costs incurred during the development process was made. The analysis compares the types and amount of incurred costs. The article proves that digital transformation has a significant impact on up to 48% on reducing costs of the paints and coatings development process. Ključne besede: coatings industry, digital transformation, development process, process redesign, technical enabler, implementation cost, rentability threshold Objavljeno v DKUM: 24.01.2025; Ogledov: 0; Prenosov: 10
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8. Nanodelci hitozana kot potencialni protimikrobni premazZdenka Peršin Fratnik, Uroš Maver, Metod Kolar, Olivera Šauperl, Lidija Fras Zemljič, Boštjan Vihar, 2024, izvirni znanstveni članek Opis: Namen študije je bil ugotoviti protimikrobno učinkovitost hitozanskih nanodelcev v primerjavi s hitozansko raztopino in sled temu njihovo učinkovito rabo na medicinskih tekstilnih materialih. Ključne besede: chitosan, nanoparticles, antimicrobial activity, coatings, medical textile materials Objavljeno v DKUM: 07.01.2025; Ogledov: 0; Prenosov: 25
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9. Antithrombogenic polysaccharide coatings to improve hemocompatibility, protein-repellence, and endothelial cell responseMatej Bračič, Bence M. Nagy, Olivija Plohl, Florian Lackner, Tobias Alexander Steindorfer, Roland Fischer, Thomas Heinze, Andrea Olschewski, Karin Stana-Kleinschek, Chandran Nagaraj, Tamilselvan Mohan, 2024, izvirni znanstveni članek Opis: Polyester biomaterials play a crucial in vascular surgery, but suffer from unspecific protein adsorption,
thrombogenicity, and inadequate endothelial cell response, which limit their success. To address these issues, we investigated the functionalization of polyester biomaterials with antithrombogenic polysaccharide coatings. A two-step and water-based method was used to coat cationized polycaprolactone with
different sulfated polysaccharides (SPS), which resulted in long-term stability, tunable morphology,
roughness, film thickness, chemical compositions, zeta potential, and water content. The coatings significantly increased the anticoagulant activity and reduced the thrombogenicity of polycaprolactone, particularly with highly sulfated heparin and cellulose sulfate. Less SPS, such as chondroitin sulfate, fucoidan,
and carrageenan, despite showing reduced anticoagulant activity, also exhibited lower fibrinogen adsorption. The adhesion and viability of human primary endothelial cells cultured on modified polycaprolactone
correlated with the type and sulfate content of the coatings. Ključne besede: polyester biomaterials, vascular surgery, antithrombogenic polysaccharide coatings Objavljeno v DKUM: 10.09.2024; Ogledov: 65; Prenosov: 22
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10. Implementation of the digital sales channel in the coatings industryEva Krhač Andrašec, Marjan Senegačnik, Benjamin Urh, Tomaž Kern, 2021, izvirni znanstveni članek Opis: The development process in the coatings industry can be shortened by digital transformation, and its costs can be reduced using a technical enabler. However, formulators need up-to-date and comprehensive data on existing and potential ingredients to develop the formulation. We were curious about how to supply formulators with data. The idea was that suppliers of ingredients provide data using the “common enabling technology”. We hypothesize that direct data entry compensates suppliers because they can shorten the sales process and increase sales. We used a survey to select key sales channels in the industry. Detailed process models were designed using structured interviews. We analyzed models using structural and operational indicators. Finally, we formed a new digital sales process and verified it. The results show that the digitally formatted sales process can be shortened by up to 32%. Simultaneously, more potential customers can be accessed using the common technology. Existing sales channels would not be closed down. Nevertheless, the digital sales channel is expected to prove its worth over time and gradually increase its share. The suppliers of ingredients can thus avoid a radical process transformation and the immediate integration of additional information technology into the company information system in such an evolutionary way. Ključne besede: digital sales channel, process analyses and improvement, digital transformation, technical enabler, coatings industry, process simulation Objavljeno v DKUM: 06.08.2024; Ogledov: 103; Prenosov: 10
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