Iskanje po katalogu digitalne knjižnice

Opis: The presented review summarizes recent studies in the field of electro conductive textiles as an essential part of lightweight and flexible textile-based electronics (so called e-textiles), with the main focus on a relatively simple and low-cost dip-coating technique that can easily be integrated into an existing textile finishing plant. Herein, numerous electro conductive compounds are discussed, including intrinsically conductive polymers, carbon-based materials, metal, and metal-based nanomaterials, as well as their combinations, with their advantages and drawbacks in contributing to the sectors of healthcare, military, security, fitness, entertainment, environmental, and fashion, for applications such as energy harvesting, energy storage, real-time health and human motion monitoring, personal thermal management, Electromagnetic Interference (EMI) shielding, wireless communication, light emitting, tracking, etc. The greatest challenge is related to the wash and wear durability of the conductive compounds and their unreduced performance during the textiles’ lifetimes, which includes the action of water, high temperature, detergents, mechanical forces, repeated bending, rubbing, sweat, etc. Besides electrical conductivity, the applied compounds also influence the physical-mechanical, optical, morphological, and comfort properties of textiles, depending on the type and concentration of the compound, the number of applied layers, the process parameters, as well as additional protective coatings. Finally, the sustainability and end-of-life of e-textiles are critically discussed in terms of the circular economy and eco-design, since these aspects are mainly neglected, although e-textile’ waste could become a huge problem in the future when their mass production starts.
Ključne besede: electro conductive textiles, dip-coating, characterization, functional features, durability, sustainability, recyclability
Objavljeno v DKUM: 27.03.2025; Ogledov: 0; Prenosov: 3
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Opis: The development of new multicomponent nanoparticles is gaining increasing importance due to their specific functional properties, i.e., synthesised new complex concentrated nanoparticles (CCNPs) in the form of powder using ultrasonic spray pyrolysis (USP) and lyophilisation from the initial cast Ag20Pd20Pt20Cu20Ni20 alloy, which was in the function of the material after its catalytic abilities had been exhausted. Hydrometallurgical treatment was used to dissolve the cast alloy, from which the USP precursor was prepared. As a consequence of the incomplete dissolution of the cast alloy and the formation of Pt and Ni complexes, it was found that the complete recycling of the alloy is not possible. A microstructural examination of the synthesised CCNPs showed that round and mostly spherical (not 100%) nanoparticles were formed, with an average diameter of 200 nm. Research has shown that CCNPs belong to the group with medium entropy characteristics. A mechanism for the formation of CCNPs is proposed, based on the thermochemical analysis of element reduction with the help of H2 and based on the mixing enthalpy of binary systems.
Ključne besede: complex concentrated nanoparticles, ultrasonic spray pyrolysis, lyophilisation, characterization, formation mechanism
Objavljeno v DKUM: 24.03.2025; Ogledov: 0; Prenosov: 2
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Opis: Nanotechnologies hold great promise for various applications. To predict and guarantee the safety of novel nanomaterials, it is essential to understand their mechanism of action in an organism, causally connecting adverse outcomes with early molecular events. This is best investigated using noninvasive advanced optical methods, such as high-resolution live-cell fluorescence microscopy, which require stable labeling of nanoparticles with fluorescent dyes. However, as shown here, when the labeling is performed inadequately, unbound fluorescent dyes and inadvertently altered chemical and physical properties of the nanoparticles can result in experimental artefacts and erroneous conclusions. To prevent such unintentional errors, we introduce a tested minimal combination of experimental methods to enable artefact-free fluorescent labeling of metal-oxide nanoparticles—the largest subpopulation of nanoparticles by industrial production and applications—and demonstrate its application in the case of TiO2 nanotubes. We (1) characterize potential changes of the nanoparticles’ surface charge and morphology that might occur during labeling by using zeta potential measurements and transmission electron microscopy, respectively, and (2) assess stable binding of the fluorescent dye to the nanoparticles with either fluorescence intensity measurements or fluorescence correlation spectroscopy, which ensures correct nanoparticle localization. Together, these steps warrant the reliability and reproducibility of advanced optical tracking, which is necessary to explore nanomaterials’ mechanism of action and will foster widespread and safe use of new nanomaterials.
Ključne besede: dye leakage, labeling characterization, artefacts, labeling-induced changes, reliable nanomaterial labeling
Objavljeno v DKUM: 27.08.2024; Ogledov: 68; Prenosov: 4
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Opis: UV-ozone activated polypropylene (PP) food films were subjected to a novel bilayer coating process involving primary or quaternary chitosan (CH/QCH) as the first layer and natural extracts from juniper needles (Juniperus oxycedrus; JUN) or blackberry leaves (Rubus fruticosus; BBL) as the second layer. This innovative approach aims to redefine active packaging (AP) development. Through a detailed analysis by surface characterization and bioactivity assessments (i.e., antioxidant and antimicrobial functionalities), we evaluated different coating combinations. Furthermore, we investigated the stability and barrier characteristics inherent in these coatings. The confirmed deposition, coupled with a comprehensive characterization of their composition and morphology, underscored the efficacy of the coatings. Our investigation included wettability assessment via contact angle (CA) measurements, X-ray photoelectron spectroscopy (XPS), and attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR), which revealed substantial enhancements in surface concentrations of elements and functional groups of CH, QCH, JUN, and BBL. Scanning electron microscopy (SEM) unveiled the coatings' heterogeneity, while time-of-flight secondary ion mass spectrometry (ToF-SIMS) and CA profiling showed moderately compact bilayers on PP, providing active species on the hydrophilic surface, respectively. The coatings significantly reduced the oxygen permeability. Additionally, single-layer depositions of CH and QCH remained below the overall migration limit (OML). Remarkably, the coatings exhibited robust antioxidative properties due to plant extracts and exceptional antimicrobial activity against S. aureus, attributed to QCH. These findings underscore the pivotal role of film surface properties in governing bioactive characteristics and offer a promising pathway for enhancing food packaging functionality.
Ključne besede: chitosan, plant extracts, polypropylene, active packaging, surface characterization, bioactivity
Objavljeno v DKUM: 27.05.2024; Ogledov: 241; Prenosov: 21
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Ključne besede: Saccharomyces, Hardanger, characterization, fermentation, cider, non-volatile compounds, volatile organic compounds, partial least squares regression
Objavljeno v DKUM: 29.02.2024; Ogledov: 292; Prenosov: 8
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