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Effects of surfactants and their mixtures on inhibition of the corrosion process of ferritic stainless steel
Regina Fuchs-Godec, 2009, izvirni znanstveni članek

Opis: The corrosion inhibition characteristics regarding mixtures of cationic/zwitterionic types of surfactant (Myristyltrimethylammonium bromide/Palmitylsulfo-betaineas), and non-ionic surfactant TRITON-X-405 mixed with 1 mM of KBr, as corrosion inhibitors for stainless steel (SS) (type X4Cr13) in aqueous solutions of 2 M H2SO4 were investigated using potentiodynamic polarisation measurements. The polarisation data showed that mixtures of the surfactants used in this study acted as mixed-type inhibitors, adsorbing on the stainless steel surface in agreement with the Flory-Huggins adsorption isotherm. The tensiometric results of this study suggest the existence of a second state of aggregation for zwitterionic/cationic surfactant mixtures. From these values of the free energy of adsorption, which in both mixtures decreased with respect to a single surfactant, we concluded that the adsorption in mixtures was stronger. The mixtures studied here showed good inhibition properties for ferritic stainless steel type X4Cr13 in 2 M H2SO4 solution.
Ključne besede: corrosion inhibitor, cationic surfactant, Zwitterionic surfactant, Flory-Huggins isotherm, Sulphuric acid
Objavljeno: 01.06.2012; Ogledov: 1116; Prenosov: 100
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