Iskanje po katalogu digitalne knjižnice

Opis: Cellulose nanofibrils (CNFs) are promising materials for flexible and green supercapacitor electrodes, while Ti3C2Tx MXene exhibits high specific capacitance. However, the diffusion limitation of ions and chemical instability in the generally used highly basic (KOH, MXene oxidation) or acidic (H2SO4, CNF degradation) electrolytes limits their performance and durability. Herein, freestanding CNF/MXene cryogel membranes were prepared by deep freeze-casting (at −50 and −80 ◦C), using different weight percentages of components (10, 50, 90), and evaluated for their structural and physico-chemical stability in other less aggressive aqueous electrolyte solutions (Na2/Mg/Mn/K2-SO4, Na2CO3), to examine the influence of the ions transport on their pseudocapacitive properties. While the membrane prepared with 50 wt% (2.5 mg/cm2 ) of MXene loading at −80 ◦C shrank in a basic Na2CO3 electrolyte, the capacitance was performed via the forming of an electroactive layer on its interface, giving it high stability (90% after 3 days of cycling) but lower capacitance (8 F/g at 2 mV/s) than in H2SO4 (25 F/g). On the contrary, slightly acidic electrolytes extended the cations’ transport path due to excessive but still size-limited diffusion of the hydrated ions (SO4 2− > Na+ > Mn2+ > Mg2+) during membrane swelling, which blocked it, reducing the electroactive surface area and lowering conductivities (<3 F/g).
Ključne besede: cellulose nanofibrils, Ti3C2Tx MXene, freeze-casting, aqueous electrolytes, physico-chemical properties, electric double layer, pseudocapacitance
Objavljeno v DKUM: 07.04.2025; Ogledov: 0; Prenosov: 5
Celotno besedilo (7,94 MB)
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Opis: In this investigation, strips of an experimental Al-Mn-Cu-Be alloy were manufactured by high-speed single-roll and twin-roll casting to stimulate the formation of a quasicrystalline phase during solidification. The strips were characterised by light microscopy, scanning and transmission electron microscopy, microchemical analysis, and X-ray diffraction. Indentation testing was used to determine the mechanical responses of the strips in different areas. A smooth surface was achieved on both sides of the twin-roll-cast strip, while the free surface of the single-roll-cast strip was rough. The microstructures in both strips consisted of an Al-rich solid solution matrix embedding several intermetallic phases Θ-Al2Cu, Be4Al (Mn, Cu), Al15Mn3Be2 and icosahedral quasicrystalline phase (IQC). The microstructure of the single-roll-cast strip was more uniform than that of the twin-roll-cast strip. Coarse Al15Mn3Be2 particles appeared in both alloys, especially at the centre of the twinroll strip. These coarse particles adversely affected the strength and ductility. Nevertheless, both casting methods provided high-cooling rates, enabling the formation of metastable phases, such as quasicrystals. However, improvements in alloy composition and casting procedure are required to obtain enhanced microstructures and properties.
Ključne besede: single-roll casting, twin roll casting, microstructure, quasicrystal, hardness, aluminium, characterisation
Objavljeno v DKUM: 24.03.2025; Ogledov: 0; Prenosov: 4
Celotno besedilo (10,68 MB)
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Opis: The fabrication of biomaterials to be used in segmental bone defects, mimicking the bone's organic-inorganic architecture and mechanical properties to induce osteogenesis, persists as a key challenge. The purpose of this study was to elucidate the effect of a lightweight, morphologically graded, and multiphase self-standing scaffold structure prepared from a combination of gelatine (Gel), collagen type 1 (Col) and/or hydroxyapatite (HAP) nanoparticles by a unidirectional freeze-casting process at different temperatures (−20, −40, −60 °C), followed by carbodiimide induced cross-linking, on their in-vitro mechanical stability and bioactive properties. In addition, the rheological study of differently formulated Gel solutions has been performed to determine the effect of Col and HAP content on their microstructural arrangement, which, together with the freezing kinetic, affects Gel/Col orientation and cross-linking, and, thus, the scaffold's mechanical strength and stability. A bone-like anisotropic, interconnected, and graded porosity (from 120 to a few μm) scaffold structure with up to 30% total porosity and ~61 μm average pores' diameter is obtained by using a higher Col content (Col: Gel = 2:5) and freezing temperature (−20 °C) while forming a few μm thick close-to-parallel lamellae, separated with a 10–100 μm space when prepared at −60 °C. Such a structure influenced in-vitro stability strongly (lower swelling without weight loss), being accompanied with a ~76% increase of compression strength (to 37 kPa) and ~67% decrease of elastic modulus (to 17 kPa) when prepared with HAP and incubated in HBSS for 7 days. On the other hand, a significant reduction of both strength (~78%, to 15 kPa) and elasticity (~95%, to 5 kPa) was noted for a scaffold prepared with HAP at −60 °C, being related to faster degradation and the formation of a highly opened structure on the bottom, required to stimulate the bone ingrowth, while a more closed network structure on the top to adhere with the surrounding soft tissue. None of the scaffolds induced cytotoxicity to human bone-derived osteoblasts, even after 19 days of incubation, but rather improved their viability while promoting cells' adhesions, proliferation, and differentiation, being supported with an increased alkaline phosphatase activity and rod-like CaP formation.
Ključne besede: biomimetic scaffolds, rheology, unidirectional freeze-casting, morphology, compression properties, bioactivity
Objavljeno v DKUM: 10.03.2025; Ogledov: 0; Prenosov: 3
Celotno besedilo (22,97 MB)
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Opis: Štore Steel Ltd. produces more than 200 different types of steel with a continuous caster installed in 2016. Several defects, mostly related to thermomechanical behaviour in the mould, originate from the continuous casting process. The same casting speed of 1.6 m/min was used for all steel grades. In May 2023, a project was launched to adjust the casting speed according to the casting temperature. This adjustment included the steel grades with the highest number of surface defects and different carbon content: 16MnCrS5, C22, 30MnVS5, and 46MnVS5. For every 10 °C deviation from the prescribed casting temperature, the speed was changed by 0.02 m/min. During the 2-month period, the ratio of rolled bars with detected surface defects (inspected by an automatic control line) decreased for the mentioned steel grades. The decreases were from 11.27 % to 7.93 %, from 12.73 % to 4.11 %, from 16.28 % to 13.40 %, and from 25.52 % to 16.99 % for 16MnCrS5, C22, 30MnVS5, and 46MnVS5, respectively. Based on the collected chemical composition and casting parameters from these two months, models were obtained using linear regression and genetic programming. These models predict the ratio of rolled bars with detected surface defects and the length of detected surface defects. According to the modelling results, the ratio of rolled bars with detected surface defects and the length of detected surface defects could be minimally reduced by 14 % and 189 %, respectively, using casting speed adjustments. A similar result was achieved from July to November 2023 by adjusting the casting speed for the other 27 types of steel. The same was predicted with the already obtained models. Genetic programming outperformed linear regression.
Ključne besede: continuous casting of steel, surface defects, automatic control, machine learning, modelling, optimisation, prediction, linear regression, genetic programming
Objavljeno v DKUM: 25.03.2024; Ogledov: 284; Prenosov: 19
Celotno besedilo (1,19 MB)
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Opis: Conducting a comprehensive research of the casting process of wear resistant parts (white hard casting), a significant correlation is established between the technological parameters (temperature, aging time in the mold and coolant flow) and the final product hardness. The fundamental theory of Box-Wilson's gradient method marked the baseline for the foreseen researches. The method defines the coherence of the process parameters, since their dispersion in the examined process is relatively small. Main target of the experiment was a definition of the optimal casting conditions. Therefore the different technological routes are identified and the casting process is modified until the best outcome is achieved. Target function was initially in a hypothesized form, while later on evolved into a consistent form due to the application of experiment-statistics, process optimization and process management based on empirical feedback.
Ključne besede: casting, mathematical model, quality management, wear resistance
Objavljeno v DKUM: 11.07.2017; Ogledov: 1231; Prenosov: 123
Celotno besedilo (595,79 KB)
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