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Valorization of biomass through anaerobic digestion and hydrothermal carbonization : integrated process flowsheet and supply chain network optimization
Sanja Potrč, Aleksandra Petrovič, Jafaru Musa Egieya, Lidija Čuček, 2025, izvirni znanstveni članek

Opis: Utilization of biomass through anaerobic digestion and hydrothermal carbonization is crucial to maximize resource efficiency. At the same time, supply chain integration ensures sustainable feedstock management and minimizes environmental and logistical impacts, enabling a holistic approach to a circular bioeconomy. This study presents an integrated approach to simultaneously optimize the biomass supply chain network and process flowsheet, which includes anaerobic digestion, cogeneration, and hydrothermal carbonization. A three-layer supply chain network superstructure was hence developed to integrate the optimization of process variables with supply chain features such as transportation modes, feedstock supply, plant location, and demand location. A mixed-integer nonlinear programming model aimed at maximizing the economic performance of the system was formulated and applied to a case study of selected regions in Slovenia. The results show a great potential for the utilization of organic biomass with an annual after tax profit of 23.13 million USD per year, with the production of 245.70 GWh/yr of electricity, 298.83 GWh/yr of heat, and 185.08 kt/yr of hydrochar. The optimal configuration of the supply chain network, including the selection of supply zones, plant locations and demand locations, transportation links, and mode of transportation is presented, along with the optimal process variables within the plant.
Ključne besede: anaerobic digestion, hydrothermal carbonization, supply chain optimization, process flowsheet optimization, mathematical programming
Objavljeno v DKUM: 07.02.2025; Ogledov: 0; Prenosov: 6
.pdf Celotno besedilo (2,71 MB)

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Sustainable hydrothermal co-carbonization of residues from the vegetable oil industry and sewage sludge : hydrochar production and liquid fraction valorisation
Aleksandra Petrovič, Tjaša Cenčič, Jelena Parlov Vuković, Tomislav Jednačak, Silvo Hribernik, Sabina Vohl, Danijela Urbancl, Marina Tišma, Lidija Čuček, 2024, izvirni znanstveni članek

Opis: In this study, the hydrothermal co-carbonization (co-HTC) of residues from the vegetable oil industry (pumpkin oil cake– PC, hemp oil cake– HC) and sewage sludge (SS) was investigated for the first time. The co-HTC was performed at 250 C and atreatment time of 5 h. The effects of the mass ratio of the feedstocks (1:1, 1:3 and 3:1) on the properties of the HTC products were investigated using various analytical methods (NMR, XRD, 3D-EEM, FTIR, etc.). The co-HTC of SS with oil cakes resulted in improved fuel properties of the hydrochar and an increase in C content from 36.9 to 53.7 wt%, and an increase in the higher heating value (HHV) from 14.8 to 23.6 MJ/kg. The combination with HC gave hydrochars with a higher HHV and higher C content than the combination with PC. The hydrochar yield varied in the range of 39.4–55.3 wt%. NMR analysis revealed a higher proportion of aliphatic (~60 %) than aromatic compounds (~35 %) in the hydrochars, as well as a high content of orthophosphate and unsaturated fatty acids. The liquid fractions were rich in nutrients and organic compounds, but toxic to aquatic organisms. The hydrochars and liquid fractions performed well in the germination test with plant species.
Ključne besede: hydrothermal co-carbonization, sewage sludge, vegetable oil industry residues, hydrochar, liquid fraction, valorisation
Objavljeno v DKUM: 17.01.2025; Ogledov: 0; Prenosov: 10
.pdf Celotno besedilo (8,68 MB)

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Assessing energy potential and chemical composition of food waste thermodynamic conversion products: a literature review
Andreja Škorjanc, Darko Goričanec, Danijela Urbancl, 2024, izvirni znanstveni članek

Opis: This study examines the considerable volume of food waste generated annually in Slovenia, which amounted to over 143,000 tons in 2020. The analysis shows that 40% of food waste consists of edible parts, highlighting the potential for reduction through increased consumer awareness and attitudes towards food consumption. The study shows that the consumption phase contributes the most to waste food (46%), followed by primary production (25%) and processing/manufacture (24%). The study addresses various thermodynamic processes, in particular, thermal conversion methods, such as torrefaction pyrolysis and hydrothermal carbonization, which optimize energy potential by reducing the atomic ratio (H/C) and (O/C), thereby increasing calorific value and facilitating the production of solid fuels. The main results show the effectiveness of torrefaction, pyrolysis and hydrothermal carbonization (HTC) in increasing the energy potential of food waste.
Ključne besede: energy, thermodynamic conversions, pyrolysis, torrefaction, hydrothermal carbonization, food waste, energy potential, chemical composition
Objavljeno v DKUM: 28.08.2024; Ogledov: 53; Prenosov: 11
.pdf Celotno besedilo (591,41 KB)

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Carbonization of Class G well cement containing metakaolin under supercritical and saturated environments
Gregor Kravanja, Željko Knez, 2023, izvirni znanstveni članek

Ključne besede: well cement, carbonization, metakaolin, supercritical CO2, gas saturated solution, CaCo3
Objavljeno v DKUM: 15.04.2024; Ogledov: 187; Prenosov: 74
.pdf Celotno besedilo (14,25 MB)
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