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Influence of temperature and pressure during PGSS[sup]TM micronization and storage time on degree of crystallinity and crystal forms of monostearate and tristearateZoran Mandžuka,
Željko Knez, 2008, izvirni znanstveni članek
Opis: For controlling the degree of crystallinity and crystal form during particle formation using supercritical fluids, knowledge of pressure influence on solid-liquid-gas (S-L-G) equilibrium and solubility data of the system is crucial. S-L-G equilibrium data were determined in pressure range from 50 to 600 bar for systems monostearate/CO2 and tristearate/CO2 using a high-pressure view cell. Results showed a temperature minimum for both systems.The solubilities of CO2 in liquid glycerides were high: maximum solubilities, which were determined at temperatures 70 and 90 °C and pressure range from 50 to 450 bar, were from 50 to 90 mol%. Physical characteristics of micronized monostearate and tristearate samples were studied in detail after micronization and after 3 months of storage at 20 °C.
Ključne besede: chemical processing, high pressure technology, supercritical fluids, micronization, fine particles, Particles from Gas Saturated Solution, degree of crystallinity
Objavljeno v DKUM: 31.05.2012; Ogledov: 2958; Prenosov: 58
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