Iskanje po katalogu digitalne knjižnice

Opis: Due to its complex composition and toxicity, the waste liquid from hydrothermal carbonization (HTC) poses a serious environmental challenge that must be addressed before disposal. In this study, the photochemical treatment of HTC liquid in a microreactor flow system was investigated. The effects of wavelength, the presence of atmospheric oxygen, oxidizing agent (H2O2) and catalyst (FeSO4), residence time and pH on the efficiency of the photo-treatment were investigated. In addition, the influence of the addition of deep eutectic solvent (DES) on photo-treatment was studied. The results showed that the photochemical treatment was more efficient at 365 nm than at 420 nm, and that the acidic conditions gave better results than the basic ones. UV365 treatment in the presence of H2O2 (at a dosage of 1 vol%) resulted in removal efficiencies of 31.6% for COD, 17.6% for TOC, 16.9% for NH4-N and 17.2% for PO4-P. The addition of FeSO4 caused coagulation/flocculation effects, but improved phosphorus removal. The addition of DES resulted in slight discolouration of the liquid and proved unsuccessful in COD removal. The GC-MS analysis and 3D-EEM spectra showed significant changes in the fate of organics and in the fluorescence intensity of aromatic proteins and humic acid-like substances. Photochemical treatment in a microreactor flow system in the presence of H2O2 under the selected operating conditions reduced the content of organics and nutrients in the HTC liquid, but the process liquids still showed toxic effects on the organisms V. fischeri and Daphnia magna.
Ključne besede: hydrothermal treatment, waste process liquid, photochemical treatment, hydrogen peroxide, microreactor flow system
Objavljeno v DKUM: 25.09.2025; Ogledov: 0; Prenosov: 3
Celotno besedilo (2,64 MB)

Opis: The study aimed to investigate the effectiveness of biochar application on fertile soils in a temperate climate during the first year of application. The field trial was conducted on a nutrient-rich silt loam soil at two experimental sites in north-eastern Slovenia (Biš and Skorba). The effect of biochar applied alone or in combination with compost or mineral fertiliser on soil properties and yield of white cabbage was studied. In addition to the control (C), the soil received five treatments including biochar (B; 1.5 t/ha), compost (CO; 1.5 t/ha), biochar-mixed compost (BCO; 3.0 t/ha), standard mineral fertilisers (NPK; NPK 0.35 t/ha, potassium sulphate 0.25 t/ha and calcium ammonium nitrate 0.25 t/ha) and combined application of half the amount of NPK and BCO (NPK+BCO). The results showed that the applied treatments had no significant influence on the measured soil chemical parameters, except for the amount of total organic carbon, electrical conductivity and pH in Biš and total carbon in Skorba. All investigated parameters (cabbage head weight, head circumference, total and market yield) were higher at the experimental site Skorba. Statistically significant differences were found only at the experimental site Biš, where the treatment influenced all parameters (p < 0.01), except for the head circumference of the cabbage. The NPK and NPK+BCO treatments produced significantly higher total yields (66.7 t/ha and 65.8 t/ha, respectively) and marketable yields (53.2 t/ha and 51.8 t/ha, respectively) compared to the other treatments (41.3-52.6 t/ha and 30.5-42.4 t/ha, respectively). Although the differences between the other treatments were insignificant, a trend of decreasing cabbage yields towards CO > BCO > B was observed. Similar results were also obtained when analysing the average data of the two experimental sites.
Ključne besede: biochar, soil amendments, fertilisers, soil chemical properties, cabbage yield
Objavljeno v DKUM: 23.04.2025; Ogledov: 0; Prenosov: 2
Povezava na datoteko

Opis: The petroleum industry is often faced with accidental spills and discharges that pollute valuable natural resources such as soil. The purpose of this study was to assess bioremediation potential of an on-site landfarming unit (LU), a highly economical solution that complies with the zero-waste policy, for bioremediation of the contaminated soil after an actual diesel fuel leakage in a fuel depot. The first aim was to evaluate the effects of different climates on hydrocarbon bioremediation. For this reason, a part of the contaminated soil was moved from the initial location with a sub-Mediterranean climate to an LU at another location with a temperate continental climate. Our results demonstrated that remediation in sub-Mediterranean climate is less effective than the remediation in a temperate continental climate. The second aim of this study was to evaluate the effect of different plant species on the microbial population during bioremediation. For that purpose, 365-day monitoring of phospholipid fatty acids (PLFA) was performed. Our results support the hypothesis that plant-assisted bioremediation can diminish toxic effects of diesel-polluted soil and that the changes in plant species during bioremediation cause changes in the microbial population.
Ključne besede: bioremediation, climatic effect, contamined soil, microbial community, petroleum hydrocarbons
Objavljeno v DKUM: 21.02.2025; Ogledov: 0; Prenosov: 8
Celotno besedilo (2,18 MB)

Opis: In this study, the hydrothermal co-carbonization (co-HTC) of residues from the vegetable oil industry (pumpkin oil cake– PC, hemp oil cake– HC) and sewage sludge (SS) was investigated for the first time. The co-HTC was performed at 250 C and atreatment time of 5 h. The effects of the mass ratio of the feedstocks (1:1, 1:3 and 3:1) on the properties of the HTC products were investigated using various analytical methods (NMR, XRD, 3D-EEM, FTIR, etc.). The co-HTC of SS with oil cakes resulted in improved fuel properties of the hydrochar and an increase in C content from 36.9 to 53.7 wt%, and an increase in the higher heating value (HHV) from 14.8 to 23.6 MJ/kg. The combination with HC gave hydrochars with a higher HHV and higher C content than the combination with PC. The hydrochar yield varied in the range of 39.4–55.3 wt%. NMR analysis revealed a higher proportion of aliphatic (~60 %) than aromatic compounds (~35 %) in the hydrochars, as well as a high content of orthophosphate and unsaturated fatty acids. The liquid fractions were rich in nutrients and organic compounds, but toxic to aquatic organisms. The hydrochars and liquid fractions performed well in the germination test with plant species.
Ključne besede: hydrothermal co-carbonization, sewage sludge, vegetable oil industry residues, hydrochar, liquid fraction, valorisation
Objavljeno v DKUM: 17.01.2025; Ogledov: 0; Prenosov: 16
Celotno besedilo (8,68 MB)

Ključne besede: thermal pre-treatment, pyrolysis, industrial sewage sludge, thermogravimetric analysis, kinetic analysis, thermodynamic analysis
Objavljeno v DKUM: 10.05.2024; Ogledov: 258; Prenosov: 15
Celotno besedilo (3,46 MB)
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