Iskanje po katalogu digitalne knjižnice

Opis: The Ni/Y2O3 catalyst showed high catalytic activity. Based on this, the aim of this study was to create Ni/Y2O3 nanocomposites powder with two innovative technologies, Ultrasonic Spray Pyrolysis (USP) and lyophilisation. In the USP process, thermal decomposition of the generated aerosols in an N2/H2 reduction atmosphere caused a complete decomposition of the nickel (II) nitrate to elemental Ni, which became trapped on the formed Y2O3 nanoparticles. The Ni/Y2O3 nanocomposite particles were captured via gas washing in an aqueous solution of polyvinylpyrrolidone (PVP) in collection bottles. PVP was chosen for its ability to stabilise nano-suspensions and as an effective cryoprotectant. Consequently, there was no loss or agglomeration of Ni/Y2O3 nanocomposite material during the lyophilisation process. The Ni/Y2O3 nanocomposite powder was analysed using ICP-MS, SEM-EDX, and XPS, which showed the impact of different precursor concentrations on the final Ni/Y2O3 nanocomposite particle composition. In a final step, highly concentrated Ni/Y2O3 nanocomposite ink (Ni/Y2O3 > 0.140 g/mL) and test coatings from this ink were prepared by applying them on a white matte photo paper sheet. The reflection curve of the prepared Ni/Y2O3 nanocomposite coating showed a local maximum at 440 nm with a value of 39% reflection. Given that Ni is located on the surface of the Ni/Y2O3 nanocomposite in the elemental state and according to the identified properties, tests of the catalytic properties of this coating will be performed in the future.
Ključne besede: Ultrasonic Spray Pyrolysis (USP), lyophilisation, Ni/Y2O3 nanocomposite, characterisation, coatings
Objavljeno v DKUM: 20.03.2025; Ogledov: 0; Prenosov: 6
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Opis: This study demonstrates the successful synthesis of Ni/Y2O3 nanocomposite particles through the application of ultrasound-assisted precipitation using the ultrasonic spray pyrolysis technique. They were collected in a water suspension with polyvinylpyrrolidone (PVP) as the stabiliser. The presence of the Y2O3 core and Ni shell was confirmed with transmission electron microscopy (TEM) and with electron diffraction. The TEM observations revealed the formation of round particles with an average diameter of 466 nm, while the lattice parameter on the Ni particle’s surface was measured to be 0.343 nm. The Ni/Y2O3 nanocomposite particle suspensions were lyophilized, to obtain a dried material that was suitable for embedding into a polylactic acid (PLA) matrix. The resulting PLA/Ni/Y2O3 composite material was extruded, and the injection was moulded successfully. Flexural testing of PLA/Ni/Y2O3 showed a slight average decrease (8.55%) in flexural strength and a small decrease from 3.7 to 3.3% strain at the break, when compared to the base PLA. These findings demonstrate the potential for utilising Ni/Y2O3 nanocomposite particles in injection moulding applications and warrant further exploration of their properties and new applications in various fields.
Ključne besede: ultrasound spray pyrolysis, Ni/Y2O3, lyophilization, PLA, extrusion, injection moulding
Objavljeno v DKUM: 05.04.2024; Ogledov: 199; Prenosov: 22
Celotno besedilo (3,29 MB)
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Ključne besede: rapid antigen tests, recycling, characterization, nanogold, plastic
Objavljeno v DKUM: 12.02.2024; Ogledov: 383; Prenosov: 6

Opis: The article includes the study and reconstruction of a fluid bed device with the purpose of separating the granular material from the grinding process of rapid antigen tests. The following techniques were performed, with the purpose of characterisation of the ground particles: sieve analysis, X-ray fluorescence spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and transmission electron microscopy. The paper includes experimental testing of a simplified separation process with zeolite spheres and paper strips, supported by a numerical model. The flow conditions’ impact on the behaviour and interactions of particles of the considered problem were simulated using coupled computational fluid dynamics (CFD) and the discrete element method (DEM) approach. The separation process of zeolite spheres and paper strips was found to be efficient. The simulation results showed the appropriate behaviour of the particles during the process. We explained the results’ deviations, and we also presented the shortcomings and possible improvements. Further research is required to define the adequacy of the process, while using actual ground material of rapid antigen tests.
Ključne besede: rapid antigen tests, nanomaterials, fluidised bed, computational fluid dynamics, discrete element method, characterisation
Objavljeno v DKUM: 05.01.2024; Ogledov: 378; Prenosov: 57
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Opis: Gold nanoparticles (AuNPs) have now been used in skin care creams for several years, with marketed anti-aging, moisturizing, and regenerative properties. Information on the harmful effects of these nanoparticles is lacking, a concern for the use of AuNPs as cosmetic ingredients. Testing AuNPs without the medium of a cosmetic product is a typical method for obtaining this information, which is mainly dependent on their size, shape, surface charge, and dose. As these properties depend on the surrounding medium, nanoparticles should be characterized in a skin cream without extraction from the cream’s complex medium as it may alter their physicochemical properties. The current study compares the sizes, morphology, and surface changes of produced dried AuNPs with a polyvinylpyrrolidone (PVP) stabilizer and AuNPs embedded in a cosmetic cream using a variety of characterization techniques (TEM, SEM, DLS, zeta potential, BET, UV–vis). The results show no observable differences in their shapes and sizes (spherical and irregular, average size of 28 nm) while their surface charges changed in the cream, indicating no major modification of their primary sizes, morphology, and the corresponding functional properties. They were present as individually dispersed nanoparticles and as groups or clusters of physically separated primary nanoparticles in both dry form and cream medium, showing suitable stability. Examination of AuNPs in a cosmetic cream is challenging due to the required conditions of various characterization techniques but necessary for obtaining a clear understanding of the AuNPs’ properties in cosmetic products as the surrounding medium is a critical factor for determining their beneficial or harmful effects in cosmetic products.
Ključne besede: gold nanoparticles, ultrasonic spray pyrolysis, freeze drying, characterization, creams
Objavljeno v DKUM: 19.04.2023; Ogledov: 769; Prenosov: 79
Celotno besedilo (5,34 MB)
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