1. Aging and Modified Washing Process for Polyester Fabrics - Environmental ImpactAna Šaravanja, Tanja Pušić, Julija Volmajer Valh, Tihana Dekanić, 2024, izvirni znanstveni članek Opis: Aging and washing factors have a direct influence on changing the properties of textile products, e.g., causing a release of textile fragments in the washing process. In this study, polyester fabrics were exposed to artificial aging under controlled conditions. Using a modified washing process, polyester fabrics were subjected to 10 washing cycles before and after the aging process. To monitor the influence of aging and the modified washing process on the polyester fabrics, the physical, structural and morphological properties of the fabrics and the composition of the collected wastewater were analyzed. The results indicate a slight degradation and increased defragmentation of the polyester fabric due to the processes used. Aging caused the phenomenon of “annealing”, photo-oxidative degradation, and the local thickening of the individual fibers. Aging and washing processes influence the change in tensile strength properties. An analysis of zeta potential and BET results confirmed that the aging process results in surface modifications that depend on the time of exposure. The physico-chemical characterization and microscopic analysis of the wastewater revealed various fragments and short, detached fibrils. The results confirmed that both aging and washing significantly affect the properties of polyester fabrics and the composition of the wastewater resulting from the washing process. The relevance of this research to environmental matters is emphasized through the parameters chosen, which reveal the influence of aging on polyester fabric characteristics and the contamination detected in wash wastewater. In conclusion, several avenues for future research have been identified, including lowering washing temperatures, choosing more appropriate detergents, and adjusting standard washing protocols. Ključne besede: polyester fabric, artificial aging, washing process, wastewater, defragmentation Objavljeno v DKUM: 20.12.2024; Ogledov: 0; Prenosov: 4
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2. Influence of cross-linkers on the wash resistance of chitosan-functionalized polyester fabricsTanja Pušić, Tea Bušac, Julija Volmajer Valh, 2024, izvirni znanstveni članek Opis: This study investigates the wash resistance of polyester fabrics functionalized with chitosan,
a biopolymer known for its biocompatibility, non-toxicity, biodegradability and environmentally
friendly properties. The interaction of chitosan with synthetic polymers, such as polyester, often
requires surface treatment due to the weak natural affinity between the two materials. To improve
the interaction and stability of chitosan on polyester, alkaline hydrolysis of the polyester fabric was
used as a surface treatment method. The effectiveness of using cross-linking agents 1,2,3,4-butane
tetracarboxylic acid (BTCA) and hydroxyethyl methacrylate (HEMA) in combination with ammonium
persulphate (APS) to improve the stability of chitosan on polyester during washing was investigated.
The wash resistance of polyester fabrics functionalized with chitosan was tested after 1, 5 and
10 washes with a standard ECE detergent. Staining tests were carried out to evaluate the retention of
chitosan on the fabric. The results showed that polyester fabrics functionalized with chitosan without
cross-linkers exhibited better wash resistance than the fabrics treated with crosslinkers.
Ključne besede: polyster, functionalization, chitosan, cross-linkers, stability, washing Objavljeno v DKUM: 10.09.2024; Ogledov: 55; Prenosov: 15
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3. Eco friendly functional finishes of polyester fabric using keratin from wool and feather wastesLidija Fras Zemljič, Maja Čolnik, Darinka Fakin, Tanja Pušić, Vanessa Wendy Bračko, Tjaša Kraševac Glaser, Mojca Škerget, 2024, izvirni znanstveni članek Opis: This research showcases the use of hydrothermally extracted solutions from poultry feathers and wool as ecofriendly and versatile textile finishes. These solutions, derived from waste biomass containing the keratin
biopolymer, were obtained through environmentally conscious hydrothermal degradation processes. Initially,
the study focused on analysing the chemical parameters and properties of both dialysed and non-dialysed solutions extracted from feathers and wool. The investigation tracked primarily the presence of keratin within these
solutions. Upon application to polyester textiles as the reference material, the presence of these solutions on the
fabric surface was confirmed successfully. A thorough physicochemical analysis of the treated textiles involved
various analytical techniques. These encompassed surface composition analysis via X-ray Photoelectron Spectroscopy (XPS) and Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), assessment of wettability through Contact Angle measurements, determination of surface charge using surface zeta
potential, and examination of the thermal and flame-retardant properties via Differential Scanning Calorimetry
(DSC), Thermogravimetric Analysis (TGA), and calorimetric tests. In addition, the colour, UV radiation transmission and antioxidant activity were evaluated using standard tests.
The remarkable effects of the treatment have been observed in the exceptional antioxidative action, fire
resistance, UV protection and enhanced hydrophilicity of these innovative multifunctional textiles. This
approach holds significant implications across research, economics and society, enriching Material Science by
deepening the understanding of materials and their multifaceted properties. Moreover, it promotes resource
efficiency, opens new sustainable textile market prospects, and contributes to social impact by supporting
environmental sustainability, engaging communities and ensuring health and safety benefits. Ključne besede: poultry feathers and wool, hydrothermal extraction, polyester, finishing, green, multifunctionality Objavljeno v DKUM: 03.09.2024; Ogledov: 43; Prenosov: 20
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4. Extending the protection ability and life cycle of medical masks through the washing processJulija Volmajer Valh, Tanja Pušić, Mirjana Čurlin, Ana Knežević, 2023, izvirni znanstveni članek Opis: The reuse of decontaminated disposable medical face masks can contribute to reducing the environmental burden of discarded masks. This research is focused on the effect of household and laboratory washing at 50 °C on the quality and functionality of the nonwoven structure of polypropylene medical masks by varying the washing procedure, bath composition, disinfectant agent, and number of washing cycles as a basis for reusability. The barrier properties of the medical mask were analyzed before and after the first and fifth washing cycle indirectly by measuring the contact angle of the liquid droplets with the front and back surface of the mask, further by measuring air permeability and determining antimicrobial resistance. Additional analysis included FTIR, pH of the material surface and aqueous extract, as well as the determination of residual substances—surfactants—in the aqueous extract of washed versus unwashed medical masks, while their aesthetic aspect was examined by measuring their spectral characteristics. The results showed that household washing had a stronger impact on the change of some functional properties, primarily air permeability, than laboratory washing. The addition of the disinfectant agent, didecyldimethylammonium chloride, contributes to the protective ability and supports the idea that washing of medical masks under controlled conditions can preserve barrier properties and enable reusability. Ključne besede: medical masks, washing, detergent, didecyldimethylammonium chloride, air permeability, antimicrobial activity, residuals Objavljeno v DKUM: 15.03.2024; Ogledov: 333; Prenosov: 31
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5. Sustainability-oriented surface modification of polyester knitted fabrics with chitosanTanja Pušić, Tea Bušac, Kristina Šimić, Mirjana Čurlin, Ana Šaravanja, Katia Grgić, Julija Volmajer Valh, 2024, izvirni znanstveni članek Opis: The existing research deals with the process of modifying polyester knitted fabrics and polyester/cotton knitted fabrics with chitosan and the stability of functionalized surface with chitosan in the washing process according to a standard and an innovative washing procedure. The current research concept aims to evaluate the degree of progressivity and progressiveness: the modification of polyester knitted fabrics with chitosan and an innovative washing process. The polyester and polyester/cotton fabrics modified with chitosan were characterized by a staining test, microscopic analysis, zeta potential measurement, and pilling tendency of the knitted fabrics before and after five and ten washing cycles with reference detergent ECE A. The results of the zeta potential measurement of knitted fabrics functionalized with chitosan confirmed cationization of the polyester and polyester/cotton fabric with chitosan. The presence of chitosan on the washed knitted fabrics in reduced quantities is demonstrated by the staining test, the colour strength (K/S), and the zeta potential values. The staining test and surface charge of the tested knitted fabrics confirmed the research hypothesis regarding the degree of progressivity of the modification of polyester and polyester/cotton knitted fabrics with chitosan and the sustainability of the innovative washing process. The streaming potential proved to be a favorable method for monitoring the stability of chitosan in the washing process in combination with a staining test with the selected dye Remazol Red RB. Ključne besede: knitted fabrics, polyester, polyester/cotton, chitosan, washing, surfaces Objavljeno v DKUM: 05.02.2024; Ogledov: 285; Prenosov: 25
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6. Primerjava primarnih učinkov pranja pri uporabi različnih postopkov pranja bolnišničnih tekstilijSabina Fijan, Sonja Šostar-Turk, Tanja Pušić, 2006, izvirni znanstveni članek Opis: S primarnimi učinki pranja tekstilij ugotavljamo čistilno moč pranja oz. sposobnost odstranjevanja madežev po enem ciklu pranja. Primarne in sekundarne učinke pranja (mehanske in fizikalno-kemijske modifikacije površine vlaken) uporabljamo za ugotavljanje kakovosti postopka pranja, vendar le kot pogoj za higieno bolnišničnih tekstilij. Osnovni namen pranja bolnišničnih tekstilij je vrnitev umazanih, okuženih tekstilij v čisto, sveže in razkuženo stanje brez pretiranih poškodb na tekstilijah za nadaljnjo uporabo. Izbrali smo pet najpogosteje uporabljenih programov pranja bolnišničnih tekstilij (programi pranja pižam, tekstilij s sumom okuženosti, brisač, operacijskih tekstilij in tetrapodlog) in ugotavljali primarne učinke pranja z EMPA-tkanino, artikel 103 z osmimi standardnimi madeži (beljen bombaž, saje/olje, kri, kakav, kri/mleko/saje, žveplovo barvilo, surov bombaž, rdeče vino). Ugotovili smo, da je kakovost pranja primerna v vseh preverjenih postopkih pranja. Ključne besede: tekstilije, bolnišnične tekstilije, pranje, učinki primarnega pranja, parametri kakovosti Objavljeno v DKUM: 31.08.2017; Ogledov: 1120; Prenosov: 176
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