1. The curing of diallylterephthalate determination of the kinetic triplet A, Ea,app, ƒ(α) using the isoconversional methodDušan Klinar, Janvit Golob, Matjaž Krajnc, 2003, izvirni znanstveni članek Opis: Allyl polymers are important materials for the production of high performance ophthalmic lenses by free-radical bulk polymerization in the casting process. Isoconversional model-free analysis was applied to the isothermal and nonisothermal curing of diallylterephthalate performed by DSC at different sets of heating rates. The results of the kinetic analysis in a form of kinetic triplet $(Ea, A, ƒ(α))$ present the variation of the Arrhenius parameters with the calculation method, reaction extent, process mode and heating rates applied. This variation is a sign of the complex and multi-step reaction mechanism. Such a mechanism was approximated with one step $(1-α)^n$ reaction model. With the isokinetic relationship - IKR (compensation effect) in the form of $lnA=aEa,app+b$ it was found out that the isothermal and nonisothermal IKR lines converge to different singular points. From the correlation procedure with the experimental data isothermal narrowest point – NPI was selected as a common point. The curing process in the isothermal and nonisothermal process conditions, respectively, was successfully simulated with the obtained kinetic parameters. The possible alternative reaction paths and the partial diffusion control of the curing process are the reasons for the limiting usage of the model-free kinetic analysis method. This method was mainly used as a preliminary step for further analysis with other methods.
Ključne besede: DSC, DAT, curing kinetics, compensation effect
Objavljeno v DKUM: 29.08.2017; Ogledov: 1309; Prenosov: 102
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2. Scale-up research in a dual fluidized bed gasification processMiha Narobe, Janvit Golob, Jernej Mele, Mihael Sekavčnik, Andrej Senegačnik, Dušan Klinar, 2015, izvirni znanstveni članek Opis: A successful co-gasification of plastics and biomass was achieved in the 100 kW dual fluidized bed (DFB) gasification pilot plant. The results of a pilot plant experiment were used as a sound basis for scale-up prediction to 750 kW semiindustrial DFB plant. By an eightfold increase of mass and heat flows a rather simplified co-gasification process was predicted. Namely, the losses occurring in gasification plants are expected to be relatively smaller in larger plants. The effect of decreased losses was studied with an equilibrium model. Three different situations were simulated with the following fixed values of losses: 70 kW, 115 kW and 160 kW. The model showed an increase in fuel conversion when losses were reduced.
Ključne besede: gasification, simulation, dual fluidized bed reactor, scale up
Objavljeno v DKUM: 25.08.2017; Ogledov: 1007; Prenosov: 324
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3. Multiple-effect evaporation in aluminosilicate technologyDušan Klinar, Janvit Golob, 2001, strokovni članek Opis: The article presents an engineering approach to the development of an alternative production with the existing equipment. Zeolite production is becoming an alternative to the old »Bayer« process for aluminum hydrate production. By applying appropriate know-how old equipment was used for an economically as well as ecologically acceptable production. In this equipment adaptation among other production steps the multistage evaporation battery was the most critical part of the process. We applied semi empirical approach on the basis of Z. Rant ideas to find heat transfer coefficients and to determine which equipment elements are more relevant for efficient performance and need serious maintenance.
Ključne besede: chemical engineering, evaporation in silicate technology, bauxite alumina production, evaporators, process optimization, heat transfer, heat flow, empirical equations, heat transfer coefficients, zeolites
Objavljeno v DKUM: 24.08.2017; Ogledov: 1314; Prenosov: 100
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