1. Energetska izraba odpadnih rožmarinovih tropin : magistrsko deloUroš Filipič, 2021, magistrsko delo Opis: Podjetje Vitiva proizvodnja in storitve, d.d. je eden izmed večjih proizvajalcev izvlečkov iz rožmarina v Evropi. Končni produkt so rastlinski izvlečki rožmarina in drugih rastlin uporaba katerih je primerna v prehrambni industriji, prehrani za živali, v farmacevtskih izdelkih in v kozmetiki. Proizvodnja poteka s pomočjo ekstrakcij v različnih topilih, kjer najprej rožmarin ekstrahirajo z organskim topilom (aceton, etanol, metanol, voda), nato pa ekstrakt in tropine ločijo z nadtlačno filtracijo ter zberejo v zbirnem kontejnerju. Kot stranski produkt procesa nastajajo rožmarinove tropine.
Glavna tematika magistrskega dela je raziskati primernost rožmarinovih tropin za zgorevanje v kotlu z namenom izrabe energije te biomase. V eksperimentalnem delu magistrske naloge smo opazovali čas do vžiga goriva, čas od pojavitve do ugasnitve plamena. Prav tako smo ob zaključku eksperimenta analizirali maso pepela. Testirali smo različne kombinacije vlažnih tropin z lesnimi peleti in enake kombinacije vlažnih tropin z lesnimi sekanci, enako smo ponovili z rožmarinovimi tropinami, ki smo jih predhodno povsem posušili.
Z dovajanjem toplote za vžig od spodaj v laboratoriju, so se nam vžgala prav vsa goriva in vse kombinacije goriv z izjemo samo vlažnih rožmarinovih tropin.
Analiza rezultatov je pokazala, da bi za obstoječi kotel na podjetju Vitiva proizvodnje in storitve d.d., ki je konstruiran za suha goriva, bilo primerno kuriti predhodno posušene odpadne rožmarinove tropine kot same ali v kakršnikoli kombinaciji z lesnimi sekanci ali z lesnimi peleti.
Ključne besede: Energetska izraba, odpadne rožmarinove tropine, kurilna naprava, zgorevanje
Objavljeno v DKUM: 27.09.2021; Ogledov: 1256; Prenosov: 75
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2. Isolation and concentration of natural antioxidants with high-pressure extractionMajda Hadolin Kolar, Andreja Rižner Hraš, Davorin Bauman, Željko Knez, 2004, izvirni znanstveni članek Opis: In present work, the purification of crude rosemary extract with supercritical fluids is presented. Carbon dioxide was used as a solvent. The crude extract was prepared from rosemary with conventional extraction process. The supercritical CO2 extraction of crude extracts was performed at pressures 10 and 20 MPa and temperatures 35 and 60 °C. The best results were obtained at pressure 10 MPa and temperature 35 °C. The content of carnosic acid in the samples before and after high pressure extraction was identified by high performance liquid chromatography. The content of carnosic acid in purified extract is higher compared to crude extract. The antioxidative efficiency of extracts was determined by measuring peroxide value. Activity ofpurified rosemary extracts is higher compared to crude extracts.
Ključne besede: chemical processing, high pressure technology, extraction, CO2, natural antioxidants, rosemary extract, food additives
Objavljeno v DKUM: 01.06.2012; Ogledov: 2664; Prenosov: 114
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3. Postopek za pripravo koncentriranih ekstraktov na osnovi rožmarinske kisline in njihova uporaba : številka patenta SI 21460 A, datum objave: 31.10.2004; št. prijave P-200300106 z dne 23.04.2003Davorin Bauman, Majda Hadolin Kolar, Matevž Kmet, Andreja Rižner Hraš, Željko Knez, 2004, patent Ključne besede: kemijska procesna tehnika, visokotlačna tehnologija, ekstrakcija, rožmarinska kislina
Objavljeno v DKUM: 01.06.2012; Ogledov: 3103; Prenosov: 78
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4. Phenols, proanthocyanidins, flavones and flavonols in some plant materials and their antioxidant activitiesMojca Škerget, Petra Kotnik, Majda Hadolin Kolar, Andreja Rižner Hraš, Marjana Simonič, Željko Knez, 2005, izvirni znanstveni članek Opis: Methanol extracts prepared from five plant materials native to the Mediterranean area, namely olive tree (Olea europaea) leaf, St. John's wort (Hypericum perforatum), hawthorn (Crataegus laevigata), oregano (Origanum vulgare) and laurel leaf (Lauris nobilis), were examined for their phenolic components. Total phenolic content was determined by the Folin-Ciocalteu method. The content of proanthocyanidins in acid-hydrolysed extracts was determined spectrophotometrically. The contents of free flavones (apigenin andluteolin) and flavonols (kaempferol, myricetin and quercetin) were determined by HPLC analysis. The time of hydrolysis of flavones, flavonols andproanthocyanidins was optimised. Antioxidant activities of apigenin, luteolin, kaempferol, myricetin, quercetin and of plant extracts were examined. Antioxidative activities were studied in sunflower oil at 98 °C, by measuring peroxide value, and in an aqueous emulsion system of -carotene and linoleic acid by measuring the absorbance of the sample. Among flavones and flavonols investigated, only myricetin inhibited oxidation of sunflower oil. All other flavones and flavonols showed pro-oxidative activity. Oppositely, in the emulsion system, only apigenin showed pro-oxidative activity while otherflavones and flavonols and plant extracts inhibited oxidation of -carotene.
Ključne besede: chemical processing, extraction, plant material, fenolic content, hidrolysis, antioxidants, flavones, flavonols, proanthocyanidines, oils, emulsions
Objavljeno v DKUM: 01.06.2012; Ogledov: 2745; Prenosov: 125
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