Topochemical modification of cotton fibres with carboxymethyl celluloseLidija Fras Zemljič
, Peer Stenius
, Janne Laine
, Karin Stana-Kleinschek
, 2008, original scientific article
Abstract: The research reported in this paper demonstrates that the capacity of cotton fibres to adsorb cationic surfactants as well as the rate of the adsorption process can be increased by adsorbing carboxymethyl cellulose (CMC) onto the fibre surfaces; in addition, the adsorption can be restricted to the fibre surface. CMC was deposited by means of adsorption from an aqueous solution. The adsorption of N-cetylpyridinium chloride (CPC) from an aqueous solution onto the CMC-modified fibres was measured using UVspectrometric determination of the surfactant concentration in the solution. Adsorption onto the cotton fibres was studied in a weakly basic environment (pH 8.5) where cotton fibres are negatively charged and the CPC ion is positively charged. Modification of the fibres by adsorption of CMC introduces new carboxyl groups onto the fibre surfaces, thereby increasing the adsorption capacity of the fibres for CPC. The initial rate of adsorption of CPC increased proportionally with the amountof charge; however, this rate slowed down at high degrees of coverage onfibres with a high charge. The adsorption of cationic surfactant to the anionic surface groups was stoichiometric, with no indication of multilayer oradmicelle formation. It was evident that the acidic group content of the fibres was the primary factor determining cationic surfactant adsorption to these fibres.
Keywords: textile fibres, cotton fibres, modification, carboxymethyl cellulose, acid groups, charge increase, conductiometric titration, phenol-sulphuric acid test, practical applications
Published: 01.06.2012; Views: 1389; Downloads: 87
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Characterization of amino groups for cotton fibers coated with chitosanLidija Fras Zemljič
, Simona Strnad
, Olivera Šauperl
, Karin Stana-Kleinschek
, 2009, original scientific article
Abstract: The adsorption of chitosan onto cellulose cotton fibers introduces antimicrobial properties, mainly created by the amount and location of amino groups. Therefore, it is important to be able to analyze both parameters, especially in a heterogeneous system, namely cotton fibers coated with chitosan. In this research, three different analytical techniques were applied to determine amino groups of cotton fibers coated with chitosan. The number of positively charged groups was determined indirectly by the spectrophotometric method using Acid Orange 7 dye, and the use of polyelectrolyte titration. In addition, the chemical surface composition regarding non-modified, as well as modified cotton fibers (coated with chitosan), was investigated using X-ray Photoelectron Spectroscopy (XPS). The results from a combination of these methods show that chitosan treatment introduces more than 14 mmol/kg of accessible amino groups onto the cotton fibers. The results were in good agreement with the results of XPS. The use of spectrophotometric and titration methods in combination with XPS appears to be a very useful tool for identifying the formation of amino groups in modified cotton fibers and their surfaces.
Keywords: cotton, cellulose, oxidation, chitosan, amino-groups, titration, XPS
Published: 01.06.2012; Views: 1290; Downloads: 124
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Adsorption and antibacterial activity of soluble and precipitated chitosan on cellulose viscose fibersLidija Fras Zemljič
, Tijana Ristić
, Tina Tkavc
, 2012, original scientific article
Abstract: The aim and novelty of this work was to compare the adsorption of totally-soluble chitosan (acidic solution) against the adsorption of precipitated chitosan, onto cellulose fibers. The influences of both these chitosan-adsorption procedures on a final amino groupćs content in functionalized cellulose fibers were studied, using potentiometric titration and the conventional spectrophotometric C.I. Acid Orange 7 method. Surface modification and adsorption of chitosan were, in addition, monitored by determining XPS spectra. The antimicrobial activities of both chitosan- functionalised cellulose fibers were examined, in regard to pathogen bacteria and fungus.
Keywords: functionalized viscose, chitosan solution, precipitates, potentiometric titration, spectrophotometry, antimicrobial activity
Published: 01.06.2012; Views: 1715; Downloads: 326
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