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1.
Removal of vat and disperse dyes from residual pad liquors
Vera Golob, Alenka Ojstršek, 2005, original scientific article

Abstract: The efficiency of three wastewater treatment techniques, coagulation/flocculation, adsorption and ultrafiltration, has been studied for the removal of vat and disperse dyes from residual pad liquors. Three inorganic coagulants Al2(SO4)3 18H2O, FeSO4 7H2O, FeCl3 6H2O and commercial cationic flocculant, as individuals and in combination, were tested for the coagulation/flocculation methods. Granular activated carbon was used as an adsorbent in the adsorption technique. Ultrafiltration was performed using a polyethersulfone membrane with a molecular weight cut-off of 10 kDa. Dye removal was evaluated as the difference between concentrations of dyes in pad liquors before and after a particular treatment using absorbance measurements.The obtained results indicated over 90% of dye removal using appropriate coagulants and only 40% using activated carbon. The best results, dye removal over 98%, were achieved using the ultrafiltration technique.
Keywords: textile dyeing, disperse dyes, wastewater, decoloration, wastewater treatment, coagulation, flocculation, adsorption, ultrafiltration, vat dyes
Published: 01.06.2012; Views: 1478; Downloads: 81
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2.
Wastewater treatment after reactive printing
Sonja Šostar-Turk, Marjana Simonič, Irena Petrinić, 2005, original scientific article

Abstract: Membrane filtration of wastewater after textile printing with reactive dyes isdescribed. The wastewater from a Slovenian factory, whose output is approx. 80% reactive dyes printed and dyed on cotton, was studied. In particular, the presence of urea, sodium alginate, oxidation agent and reactive dyes, used forthe printing paste preparation, in the wastewater was studied. Chemical analyses of actual, non-purified, wastewater showed that many Slovenian regulations were exceeded. The study of membrane filtration is based on a pilot wastewater treatment plantČ ultrafiltration (UF) and reverse osmosis (RO) units. The quality of the wastewater was improved by ultrafiltration, butits effluent still does not conform to the specification of concentration limits for emission into water. Permeate coming from RO meets the required specification and, therefore, could be re-used in the washing process of printed textiles.
Keywords: textile printing, reactive dyes, wastewater treatment, membrane filtration, pilot plant
Published: 01.06.2012; Views: 1963; Downloads: 67
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3.
Ultrasound in textile dyeing an the decolouration/mineralization of textile dyes
Simona Vajnhandl, Alenka Majcen Le Marechal, 2005, review article

Abstract: In recent decades ultrasound has established an important place in different industrial processes such as the medical field, and has started to revolutionize environmental protection. The idea of using ultrasound in textile wet processes is not a new one. On the contrary there are many reportsfrom the 1950s and 1960s describing the beneficial effects of ultrasound in textile wet processes. The aim of this paper is to review some fundamentals of ultrasound, its broad application and gather some new researchand studies regarding ultrasound application in textile wet processes,with the emphasis on textile dyeing and the decolouration/mineralization of textile wastewaters.
Keywords: textile industry, textile dyes, wastewater, decoloration, degradation, ultrsound
Published: 01.06.2012; Views: 1107; Downloads: 32
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4.
Efficiency of the coagulation/flocculation method for the treatment of dyebath effluents
Vera Golob, Aleksandra Vinder, Marjana Simonič, 2005, original scientific article

Abstract: Textile dyeing processes are among the most environment-unfriendly industrial processes, because they produce coloured wastewaters that are heavily polluted with dyes, textile auxiliaries and chemicals. The coagulation/flocculation method was studied as a wastewater treatment technique for the decolourization of residual dyebath effluents after dyeing cotton/polyamide blends using reactive and acid dyes. It was discovered that acombination of aluminium sulphate and a cationic organic flocculant yields an effective treatment for residual dyebath wastewaters since almost complete decolourization was achieved, TOC, COD, AOX, BOD and the anionic surfactants were reduced and the biodegradability was increased.
Keywords: textile industry, reactive dyes, acid dyes, wastewater, čiščenje odpadnih vodwastewater treatment, flocculation, coagulation, ecological analyses, wastewater decoloration, Jar-tests
Published: 01.06.2012; Views: 1572; Downloads: 70
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5.
6.
The use of constructed wetland for dye-rich textile wastewater treatment
Tjaša Griessler Bulc, Alenka Ojstršek, 2008, original scientific article

Abstract: The objective of the present paper was to examine the treatment efficiency of constructed wetlands (CW) for the dye-rich textile wastewater with special focus on colour reduction. Preliminary, a series of dynamic experiments were performed in the CW model packed with gravel, sand, and zeolitic tuff on three synthetically-prepared wastewaters using chemically differ dyestuffs, auxiliaries and chemicals, in order to investigate the potential of low-cost materials as media for textile dye-bath wastewater treatment. The obtained results evidence that applied CW model reduces colour by up to 70%, and COD and TOC by up to 45%. Based on these results, the pilot CW with vertical (VF) and horizontal flow (HF) was constructed near textile factory mainly for cotton and cotton/PES processing with intention to treat real textile wastewater in-situ. It was designed for 1 m3/d, covering 80 m2, packed with sand and gravel, and planted with Phragmites australis. The average treatment efficiency of the CW for the selected pollution parameters were: COD 84%, BOD5 66%, TOC 89%, Ntotal 52%, Norganic 87%, NH4-N -331%, sulphate 88%, anion surfactant 80%, total suspended solids (TSS) 93%, and colour 90%, respectively. The results unequivocally proved that the CW could offer an optimal solution to meet the environmental legislation as well as requirements for effective and inexpensive textile wastewater treatment.
Keywords: coloured textile wastewater, constructed wetland, Phragmites australis
Published: 01.06.2012; Views: 1095; Downloads: 66
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7.
Case study of the sonochemical decolouration of textile azo dye Reactive Black 5
Simona Vajnhandl, Alenka Majcen Le Marechal, 2007, original scientific article

Abstract: The decolouration and mineralization of reactive dye C.I. Reactive Black 5, a well-known representative of non-biodegradable azo dyes, by means of ultrasonic irradiation at 20, 279 and 817 kHz has been investigated with emphasis on the effect of various parameters on decolouration and degradation efficiency. Characterization of the used ultrasound systems was performed using calorimetric measurements and oxidative species monitoring using Fricke and iodine dosimeter. Experiments were carried out with low frequency probe type, and a high-frequency plate type transducer at 50, 100 and 150 W of acoustic power and within the 5-300 mgžL initial dye concentration range. Decolouration, as well as radical production, increased with increasing frequency, acoustic power, and irradiation time. Any increase in initial dye concentration results in decreased decolouration rates. Sonochemical decolouration was substantially depressed by the addition of 2-methyl-2-propanol as a radical scavenger, which suggests radical-induced reactions in the solution. Acute toxicity to marine bacteria Vibrio fischeri was tested before and after ultrasound irradiation. Under the conditions employed in this study, no toxic compounds were detected after 6 h of irradiation. Mineralization of the dye was followed by TOC measurements. Relatively low degradation efficiency (50% after 6 h of treatment) indicates that ultrasound is rather inefficient in overall degradation, when used alone.
Keywords: textile industry, wastewater treatment, textile dyeing, reactive dyes, azo dyes, decoloration, ultrasound, degradation, decoloration kinetics, oxidizing species
Published: 01.06.2012; Views: 1386; Downloads: 67
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8.
Residual dyebath purification using a system of constructed wetland
Alenka Ojstršek, Darinka Fakin, Danijel Vrhovšek, 2007, original scientific article

Abstract: A constructed wetland model, comprising two different substrate mixtures, was used to purify textile dyebath wastewater. Three laboratory prepared wastewaters containing three commercial dyes of different classes and chemicalconstitution (one vat and two reactive dyes), different chemicals (NaOH, NaCl) and auxiliaries (migration inhibitor, sequestering, defoaming andwetting agents) were employed. Purifying efficiency was verified by measuring pollution parameters, such as absorbance, pH, total organic carbon (TOC), chemical oxygen demand (COD) and electrical conductivity (EC). It was found that the constructed wetland model reduced dye concentration by up to 70%, lowered the TOC and COD values up to 88%, electrical conductivity up to 60% and pH from 12 to 7.6.
Keywords: textile dyeing, reactive dyes, vat dyes, wastewater treatment, constructed wetland model, biological treatment, purification
Published: 01.06.2012; Views: 1336; Downloads: 67
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9.
The applicability of an advanced oxidation process for textile finishing wastestreams & fate of persistent organic pollutants
Julija Volmajer Valh, Alenka Majcen Le Marechal, Boštjan Križanec, Simona Vajnhandl, 2012, original scientific article

Abstract: The trend of sustainable use of available water resources encourages textile finishing enterprises to implement efficient wastewater treatment technologies that enable water recycling, and not just itćs discharging into the local wastewater treatment plants (WWTP). This paper presents the results obtained from the H2O2/UV treatment of wastewater from Slovene textile finishing company. Laboratory scale decolouration experiments were performed on the most representative wastewater samples, collected in three months period. In general 80 % decolouration and 86 % total organic carbon (TOC) reduction was achieved. On the other hand, the use of ultraviolet (UV) radiation to degrade and destroy organic pollutants in textile wastewater could lead to the formation of toxic dioxins and dioxin-like compounds, groups of persistent organic pollutants, especially due to the presence of halogenated compounds in textile finishing processes. For these reasons, textile wastewater samples were analysed for any content of dioxins before and after the treatment with H2O2/UV.
Keywords: tekstilne odpadne vode, napredni oksidacijski procesi, H2O2/UV, dioksini, textile wastewater, advanced oxidation processes, H2O2/UV, ecological parameters, dioxins
Published: 10.07.2015; Views: 883; Downloads: 33
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10.
Multivariate analysis and chemometric characterisation of textile wastewater streams
Darja Kavšek, Tina Jerič, Alenka Majcen Le Marechal, Simona Vajnhandl, Adriána Bednárová, Darinka Brodnjak-Vončina, 2013, original scientific article

Abstract: The aim of this work was to design a quick and reliable method for the evaluation and classification of wastewater streams into treatable and non-treatable effluents for reuse/recycling. Different chemometric methods were used for this purpose handling the enormous amount of data, and additionally to find any hidden information, which would increase our knowledge and improve the classification. The data obtained from the processes description, together with the analytical results of measured parameters' characterising the wastewater of a particular process, enabled us to build a fast-decision model for separating different textile wastewater outlets. Altogether 49 wastewater samples from the textile finishing company were analysed, and 19 different physical chemical measurements were performed for each of them. The resulting classification model was aimed at an automated decision about the choice of treatment technologies or a prediction about the reusability of wastewaters within any textile finishing or other company having similar characteristics of wastewater streams.
Keywords: textile finishing wastewater, chemometrics, multivariate data analysis, wastewater treatment
Published: 10.07.2015; Views: 1059; Downloads: 33
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