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1.
Study of crosslinking efficiency of cotton cellulose by different physical-chemical methods and genetic programming
Olivera Šauperl, Miran Brezočnik, 2006, original scientific article

Abstract: We have investigated the crosslinking effect of unmercerized and mercerized cotton celluose crosslinked with different BTCA mass fractions in the impregnation bath. Crosslinking efficiency was analyzed using FT-IR spectroscopy, water retention capacity method, tensiometry and the methylene blue method. On the basis of the experimental data which was obtained with theseparate physical-chemical methods, different prediction models for crosslinking efficiency was developed. Modelling was taken out with the genetic programming method. Research shows good accordance of the experimentaldata with the genetic models.
Keywords: textile fibres, cotton, cellulose, crosslinking, FTIR spectroscopy, methylene blue method, water retention capacity, tensiometry, genetic programming
Published: 30.05.2012; Views: 1397; Downloads: 52
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2.
The interaction ability of cellulosic materials as a function of fine structure and Helmholtz surface energy
Tatjana Kreže, Karin Stana-Kleinschek, Volker Ribitsch, Zdenka Peršin, Majda Sfiligoj-Smole, 2005, original scientific article

Abstract: Many chemical or physical modification processes significantly influence the accessibility of fiber forming polymers by causing structural changes. The wettability and sorption ability improvements of polymeric materials are major tasks during finishing processes. Different pre-treatment processes are used in order to improve the accessibility of dissociable groups, hydrophilicity, dyeability, and whiteness. These are usually alkaline purification, chemical bleaching and mercerization. In a previous paper we presented the data for structural characteristics (density, crystallinity index, molecular orientation, void volume, diameter and the specific inner surface of void, etc.) of untreated regenerated cellulose fibers (viscose, modal and lyocell) [41]. We now compare the influence of different pre-treatment processes on fiber structure and the accessibility of the chemical groups of these fibers. In order to improve the accessibility, two pre-treatment processes were used: chemical bleaching of fibers and tensionless alkali treatment. The influence of these pre-treatment processes on the structure parameters was evaluated using viscosity measurements (determination of polymerization degree (DIN 54 270)) and iodine sorption ability measurements according to the Schwertassek method (determination of crystallinity index) [13, 16]. The reactivity and accessibility in a polar environment was determined using tensiometry. Contact angles between the fibers and liquids of different polarities were determined using the powder contact angle method and calculated from a modified Washburn equation [26, 28]. The surface free (Helmholtz) energy of differently treated fibers was determined from the contact angle data using the Owens-Wendt-Raeble-Kaelble approximation [30, 33, 35]. The differences in the accessibility of raw and pre-treated regenerated cellulose fibers obtained using tensiometry are compared with the results of the conventional method used to determine moisture adsorption (DIN 54 351, DIN 53 802). In regard to raw fibers, viscose shows the most hydrophilic characteristic: adsorbs the highest amount of moisture, has the fastest penetration velocities (Fig. 6), the smallest contact angle, and the highest SFE (Fig. 8). Modal fibers have the largest contact angle, the lowest SFE, and they adsorb the smallest amount of water vapor. Pre-treatments increase the sorption ability and the surface free (Helmholtz) energy while they decrease the contact angle. This makes the material more accessible to water and chemicals used in the finishing processes although the crystallinity index increases. The main modification in polymer properties caused by the treatments is an increase in the fiber SFE caused by an increase of the fiber surfaces because of swelling in the alkaline medium (washing, slack-mercerization), and due to an increase of accessible OH- and COOH-groups (bleaching). This enables the formation of an increased number of hydrogen bridges between the water molecules and the OH- and COOH-groups. Our investigations confirm the results published earlier thatthe main property necessary for the proper sorption behavior of cellulose materials are the accessible, less ordered regions and not the degree of crystallinity.
Keywords: regenerated cellulose fibers, fiber pre-treatment, iodine sorption, cristallinity, tensiometry, contact angle, Helmholtz surface energy, water adsorption
Published: 01.06.2012; Views: 1843; Downloads: 47
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3.
Hydrophilic/hydrophobic characteristics of different cellulose fibres monitored by tensiometry
Zdenka Peršin, Karin Stana-Kleinschek, Tatjana Kreže, 2002, original scientific article

Abstract: Wettability and sorptivity improvements for different textile materials are the major tasks during textile finishing. In order to improve the sorption characteristics of a cellulose fabric, different pre-treatment processes are applied, usually washing, bleaching and mecerisation. Differences in the sorption properties of untreated and pretreated (washed and bleached) regenerated cellulose fibres were obtained using tensiometry and compared with the classical method for determining moisture adsorption. Results show that compared to raw fibres, viscose fibres have the highest moisture and the smallest contact angle whilst modal fibres have the biggest contact angle. Pretreatment increases the sorption abilities and makes the material more accessible to chemicals used in the finishing process. Using the conventional method, it can be confirmed that fibres with the highest moisture have the smallest contact angle (tensiometry).
Keywords: textile materials, regenerated cellulose fibres, sorption, pretreatment, tensiometry
Published: 05.07.2017; Views: 361; Downloads: 68
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