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Synthesis and characterisation of hydroxylammonium fluorochromate
Matjaž Kristl, Mihael Drofenik, Ljubo Golič, Amalija Golobič, 2003, original scientific article

Abstract: Reactions in the system $Cr – NH_3OHF – HF – H_2O$ were investigated. Green crystals of a new compound with the formula $(NH_3OH)_3CrF_6$ have been isolated from the water solution and characterized by chemical analysis. The compound crystallizes as triclinic, P-1, with cell parameters: a = 6.5461(2) Å, b = 6.9347(2) Å, c = 9.4072(3) Å, α = 86.772(1)°, β = 83.804(1)°, γ = 70.283(1)°. The effective magnetic moment, $µ_{eff}$ = 3.82 BM, was calculated from magnetic susceptibility measurements in the temperature range 80-290 K. The thermal decomposition of the compound was studied by TG and DSC analysis. $(NH_3OH)_3CrF_6$ decomposes above 125 °C in three steps and the residue has been identified by X-ray powder diffraction as $α – Cr_2O_3$.
Keywords: inorganic chemistry, structural chemistry, crystalline structure, coordination compounds, synthesis, inorganic reactions, thermal decomposition, characterization of compounds, TG, DSC, X-ray diffraction, chromium complexes, hydroxylammonium fluoro chromates, crystals
Published in DKUM: 25.08.2017; Views: 1893; Downloads: 114
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The multilevel MINLP optimization approach to structural synthesis: the simultaneous topology, material, standard and rounded dimension optimization
Stojan Kravanja, Simon Šilih, Zdravko Kravanja, 2005, original scientific article

Abstract: The paper describes the simultaneous topology, material, standard and rounded dimension optimization of mechanical structures, performed by the Mixed-Integer Non-linear Programming (MINLP) approach. Beside the generation of an MINLP mechanical superstructure, the development of a general multilevel MINLP formulation for a mechanical superstructure is presented. The consideration of the discrete materials as well as standard and particularly rounded dimensions in structural synthesis significantly increases the combinatorics of the discrete optimization, which as a result may become too difficult to solve. A Linked Multilevel Hierarchical Strategy (LMHS) has been introduced for the solving of such large combinatorial problems. In order to decrease the effect of non-convexities, the Modified Outer-Approximation/Equality-Relaxation (OA/ER) algorithm has been applied. Four numerical examples of different complexities are presented to illustrate the proposed multilevel MINLP optimization approach: the optimization of two steel trusses, a composite I beam and a hydraulic steel roller gate Intake gate, erected in Aswan II, Egypt.
Keywords: structural optimization, structural synthesis, MINLP, topology opitmization, material optimization, discrete variable optimization, multilevel MINLP strategy, truss, composite beam, roller gate
Published in DKUM: 01.06.2012; Views: 2803; Downloads: 107
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