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Abstract: This paper presents a study of PVC-P waterproofing membrane Specimens. The Specimens were taken from different segments of a flat roof after a service life of 11 years. The reason for analysing the condition of the Specimens was the apparent degradation of the waterproofing, which no longer guaranteed the watertightness of the roof. The analysis of the performance of the Specimens was based on the control of the mechanical properties, which were compared with the declared values. The mechanical properties of the degraded PVC-P waterproofing membranes with a polyester mesh backing, which are prescribed by the standards, do not usually deviate from the declared properties. This often poses a problem for liability and warranty claims due to the poor quality of the waterproofing membrane. There may be several causes of degradation of PVC-P. For this reason, in this paper, we present the possibility of controlling the properties of PVC-P waterproofing membranes using cyclic dynamic fatigue, microstructure analysis using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results show that the cause of the deterioration of the PVC-P waterproofing membranes is often related to dehydrochlorination of the polymer. However, the deterioration of the mechanical properties of the PVC-P waterproofing membranes can be successfully demonstrated by cyclic dynamic fatigue.
Keywords: environmental impact of polymers, durability, polymer degradation
Published in DKUM: 13.03.2025; Views: 0; Downloads: 5
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Abstract: This bachelor thesis depicts the chemical degradation of polyurethane and melamine formaldehyde, which are representatives of thermosets. A high–pressure reactor was used to perform chemical degradation. The effectiveness of the chemical degradation of the selected thermosets was monitored by measuring pH, total organic carbon (TOC) and total nitrogen (TN) of the liquid residues. The remaining solid material was characterized by infrared spectroscopy and the mass loss was determined. Using these analytical methods, it was concluded that the chemical degradation depends on the temperature and the duration of the reactions as well as the reaction medium. It was found that “white liquor” is a more effective medium for the chemical degradation of polyurethane and melamine formaldehyde than water.
Keywords: chemical degradation, polyurethane, melamine formaldehyde, FTIR
Published in DKUM: 22.10.2024; Views: 0; Downloads: 0

Keywords: hydrothermal degradation, waste packing, tetra pak, subcritical water, subcritical waste, chemical recycling, one-stage process, two-stage process, product analysis
Published in DKUM: 16.07.2024; Views: 88; Downloads: 26
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Keywords: assays, degradation, porosity, scaffolds, 3D printing
Published in DKUM: 09.04.2024; Views: 238; Downloads: 800
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Abstract: In this doctorial dissertation subcritical water processes of lignocellulosic biomass to obtain value-added compounds are studied. The doctorial dissertation is divided into four main parts. In the first and second part of dissertation, model compounds (standards of cellulose and sugars and chestnut tannins) were primarly used in order to better understand processes of real biomass material. The degradation of cellulose and different sugars was performed in batch reactor with subcritical water. The different reaction temperatures and times were used. The main phases, such as water-soluble fraction, acetone-soluble fraction and solid residue were separated and analysed. The analysis of water-soluble phase was done by HPLC equipped with UV and RI detector, while acetone-soluble phase of cellulose was analysed by GC-MS. Total sugar content was determined by the phenol-sulphuric acid colorimetric method. The properties of char, obtained using cellulose as a treated material, such as: specific surface area, pore volume and pore diameter were determined by gas adsorption method. A water-soluble phase mainly consists of sugar monomers and monomer degradation products such as 5-hydroxymethylfurfural (5-HMF), furfural, erythrose, sorbitol, 1,6-anhydroglucose, glycolaldehyde, glycerlaldehyde, 1,3-dihydroxyacetone, pyruvaldehyde, formic, levulinic, lactic, oxalic and succinic acids, while acetone-soluble phase, referred to also as bio-oil, consists of furans, phenols, carboxylic acids, aldehydes, ketones and high molecular compounds. The reaction mechanism of cellulose and sugars in subcritical water has been proposed based on the obtained results. Furthermore, the results from cellulose and sugar hydrothermal degradation were utilized in further work to determine which industrially interesting products could be obtained by hydrothermal processing of paper waste in subcritical water. The optimum conditions ( temperature and reaction time), which gave us the highest yield of base chemicals (furfural, 5-HMF, levulinic acid) were determined. Sweet chestnut (Castanea Sativa) bark contains high level of tannins and various phenolic compounds which can be utilized in pharmaceutical, cosmetic, nutritional and medical purposes. The sweet chestnut tannins extract and sweet chestnut bark were used as materials highly rich in bioactive compounds for subcritical water processes which are presented in the second part of doctorial dissertation, respectively. The spectrophotometric methods were used to determine total tannins, phenols and carbohydrates content and antioxidant activity. The identified compounds were ellagic and gallic acid, ellagitannins (vescalagin, castalagin, 1-o-galloyl castalagin, vescalin and castalin), sugars (maltose, glucose, fructose and arabinose) and sugar derivatives (5-HMF, furfural and levulinic acid). The results obtained from hydrothermal hydrolysis were compared to results from acid hydrolysis. Finally, the optimization of reaction parameters of subcritical water processes has been done aiming to obtain the product highly rich in ellagic acid. Subcritical water extraction of horse chestnut (Aesculus hippocastanum) parts such as seeds, seed shell, bark and leaves was described in the third chapter of dissertation. The detected compounds in extracts, such as escins, esculin, fraxin, phenolic compounds (chlorogenic, neochlorogenic and gallic acids) and furfurals (5-hydroxymethyfurfural, furfural, and methylfufrual) are quantified using HPLC. The last part of dissertation proposes extraction of cocoa shell using green technologies (supercritical CO2 and subcritical water extraction) and also conventional methods (Soxhlet extraction with hexane and extraction with 50 % acetone) to obtain bioactive compounds in order to compare the results. The detected compouns were methylxanthines, phenolic compounds, sugars, fatty acids.
Keywords: Subcritical water, biomass, biowaste, extraction, hydrothermal degradation, hydrolysis, bioactive compounds.
Published in DKUM: 16.10.2020; Views: 1774; Downloads: 177
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