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1.
The conversion of pistachio and walnut shell waste into valuable components with subcritical water
Maja Čolnik, Mihael Irgolič, Amra Perva, Mojca Škerget, 2024, original scientific article

Abstract: Pistachio and walnut shells accumulate in large quantities as waste during food processing and represent a promising lignocellulosic biomass for the extraction of valuable components. Subcritical water technology was used as an environmentally friendly technique to study the extraction of active ingredients and other valuable degradation products from walnut and pistachio waste. Subcritical water extraction (SWE) was carried out under different process conditions (temperature (150–300 ◦C) and short reaction times (15–60 min)) and compared with conventional extraction using different organic solvents (acetone, 50% acetone and ethanol). The extracts obtained from pistachio and walnut shell waste are rich in various bioactive and valuable components. The highest contents of total phenols (127.08 mg GA/g extract at 300 ◦C for 15 min, from walnut shells), total flavonoids (10.18 mg QU/g extract at 200 ◦C for 60 min, from pistachio shells), total carbohydrates (602.14 mg TCH/g extract at 200 ◦C for 60 min, from walnut shells) and antioxidant activity (91% at 300 ◦C, for 60 min, from pistachio shells) were determined when the extracts were obtained via subcritical water. High contents of total phenols (up to 86.17 mg GA/g extract) were also determined in the conventional extracts obtained with ethanol. Using the HPLC method, sugars and their valuable derivatives were determined in the extracts, with glucose, fructose, furfurals (5-hydroxymethylfurfural (5-HMF) and furfural) and levulinic acid being the most abundant in the extracts obtained by subcritical water. The results show that subcritical water technology enables better exploitation of biowaste materials than conventional extraction methods with organic solvents, as it provides a higher yields of bioactive components such as phenolic compounds and thus extracts with high antioxidant activity, while at the same time producing degradation products that are valuable secondary raw materials.
Keywords: pistachio shells, walnut shells, subcritical water extraction, conventional extraction, waste biomass, valuable compounds, sugars, furfurals
Published in DKUM: 01.07.2025; Views: 0; Downloads: 10
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2.
Specific fertilization practices reveal important insights into the complex interaction between microbes and enzymes in soils of different farming systems
Maša Kozmos, Ana Štuhec, Eva Tratnik, Tomaž Langerholc, 2024, original scientific article

Abstract: The interaction of microorganisms and their enzyme activity is one of the key indicators for a comprehensive measurement of soil health. The aim of this study was to determine significant correlations between different soil microorganisms and enzyme activities of β-glucosidase, N-acetyl-glucosaminidase, urease, arylamidase, phosphatase, acid phosphatase, alkaline phosphatase, and arylsulfatase after supplementation with standard fertilizer, spent mushroom substrate and composed fertilizer in soils from conventional–integrated, organic and biodynamic farming. Samples were grouped according to the farming system and fertilization for all seasons. The biodynamic farm was the least affected by the different fertilizations, except for standard fertilization. Standard fertilizer caused negative correlations between the actinomycetes and the arylsulfatase in organic and biodynamic farms. The same fertilization affected the actinomycetes/phosphatase relationship differently, regardless of the basic soil structure. Actinomycetes correlated positively with acid phosphatase and urease in conventional–integrated and biodynamic farms after spent mushroom substrate, respectively. Arylamidase activity in relation to total microorganisms responded to fertilization with standard fertilizer and spent mushroom substrate independently of the basic soil structure. Fertilization can influence the soil microbe/enzyme relationships in different soils. Regardless of the basic soil structure, some of these relationships could be important indicators for further studies.
Keywords: agriculture, conventional-integrated, organic, biodynamic, fertilization, soil microorganisms, soil enzyme activity
Published in DKUM: 17.04.2025; Views: 0; Downloads: 4
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Prices of conventional and renewable energy as determinants of sustainable and secure energy development : regression model analysis
Sandi Knez, Goran Šimić, Anica Milovanović, Sofia Starikova, Franc Željko Županič, 2022, original scientific article

Abstract: Background The prices of energy resources are important determinants of sustainable energy development, yet associated with significant unknowns. The estimates of the impact of prices of energy products in the domestic market (for domestic consumers) are rare—hence the importance and novelty of this research. Therefore, the main goal of the paper is to assess the impact of domestic prices of gasoline, gas, coal, and solar energy on sustainable and secure energy future. Methods The research includes 14 countries (of which 7 are developed and 7 are developing countries) and a period of 5 years (2014–2018). The model also includes discrete variables: level of development (developing or developed), and the fact as to whether the country is an energy exporter or not. For the purposes of analysis, the following elements were used: Panel Data Analysis, Linear regression (with random and fixed effects), Durbin–Wu–Hausman test, and Honda test, with the use of R-studio software for statistical computing. Results The research showed that the biggest negative impact on energy sustainability was recorded by an increase in the price of coal and the smallest one by an increase in the price of solar energy. An increase in the price of gasoline has a positive impact, while an increase in the price of gas has no impact. The basic methodological result showed that the fixed effects linear model is more accurate than the random effect model. Conclusions The results of the paper, important as a sustainable energy policy recommendation, showed that the impact of changes in energy product prices is significantly greater in developing countries, but that the status of the country as an energy exporter has no significance. In addition, the paper points to the need to intensify the research on the assessment of the impact of energy product prices for domestic consumers on their ability to pay that price, because with a certain (so far undefined) increase in energy product prices, a certain group of domestic consumers moves into a category that is not in line with sustainable energy development and is extremely undesirable in every respect—energy poverty.
Keywords: sustainable energy development, conventional energy prices, solar prices, developing countries, R-studio
Published in DKUM: 26.06.2024; Views: 133; Downloads: 17
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6.
6th International Conference En-Re Energy & Responsibility : Book of Extended Abstracts
2024

Abstract: In the context of escalating climate challenges, the EnRe conference is dedicated to exploring pathways to climate neutrality and the sustainable green transition. The conference is focused on the development and implementation of innovations supporting the transformation of energy systems, industrial systems, and living systems, all with the goal of creating a sustainable future with net-zero emissions. The conference brings together experts, researchers, policymakers, and business leaders to share their experiences, research, and visions. The aim of the conference is to foster collaboration and exchange of ideas, and to collectively develop comprehensive approaches and strategies for achieving climate neutrality. This conference is not just a knowledge exchange, but also a platform for encouraging concrete actions that will ensure a greenerand more sustainable future for our next generations to come.
Keywords: alternative energy systems, dynamic tariffing, electrical machines and drives, energy conversions, financing energy projects, nuclear energy, conventional energy systems, climate changes - climate pan, mathematical methods in engineering, micro and nano energy, low-carbon technologies and strategies, renewable energy technologies heating and cooling systems, smart buildings, cities and networks, policies and strategies for renewable energy sources, energy efficiency and the climate
Published in DKUM: 17.05.2024; Views: 332; Downloads: 73
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7.
International transmission of conventional and unconventional monetary policy and financial stress shocks from the euro area to Russia
Silvo Dajčman, Alenka Kavkler, Sergey Merzlyakov, Sergey E. Pekarski, Dejan Romih, 2022, original scientific article

Abstract: This paper studies the international transmission of the euro area´s monetary policy and financial stress to Russia. The results show that financial stress in the euro area damages Russian economic activity and stock prices, but not its trade balance. The contractionary euro area monetary policy shock decreases Russian GDP, leads to real appreciation of the euro against the Russian rouble, damages Russian stock prices, but does not significantly affect the trade balance between countries. We also found that the Central Bank of the Russian Federation adjusts to monetary policy shocks in the euro area.
Keywords: conventional monetary policy, unconventional monetary policy, financial stress, Russia, international transmission
Published in DKUM: 26.09.2023; Views: 419; Downloads: 47
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8.
A comparison between conventional triaxial and plane-strain compression on a particulate system using 3D DEM
Mahmud Sazzad, Kiichi Suzuki, 2012, original scientific article

Abstract: Granular materials such as sand are subjected to different stress paths depending on the in-situ conditions. For example, a granular system under the foundations experiences conventional triaxial compression (CTC), while it experiences plane-strain compression (PSC) in the case of the embankment of roads. Due to the difference in the stress paths, the behavior of granular materials also becomes different. This paper aims at comparing the behavior of granular materials under CTC and PSC conditions using the 3D discrete-element method (DEM). An isotropically compressed dense sample consisting of 8000 spheres was prepared numerically using periodic boundaries. The CTC and PSC tests were simulated using the same isotropically compressed dense sample to compare and explore the macro- and micro-mechanical responses of granular materials without any bias from the initial fabric of the numerical sample. Qualitatively, the simulated stress-strain responses are consistent with that observed in the experimental studies. The dilatancy index is found to be independent of the stress paths used in the present study. The b value (defined as b = (σ2 − σ3)/(σ1 − σ3) where σ1, σ2 and σ3 are the stresses in the x1 -, x2 - and x3 - directions, respectively) - axial strain curve has a close similarity with the stress ratio - axial strain curve for the PSC test. The evolution of the coordination number and the sliding contact fraction is independent of the stress paths. A link between the macro- and micro-quantities is observed and a unique macro-micro relationship is noticed, regardless of the stress paths applied in this study.
Keywords: conventional triaxial compression, plane-strain compression, micro response, DEM
Published in DKUM: 13.06.2018; Views: 1237; Downloads: 74
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9.
Influence of process parameters on the extraction of flavanones from mandarin peel
Katja Makovšek, Željko Knez, Mojca Škerget, 2012, original scientific article

Abstract: Flavanones are an important group of flavonoids that are characteristic for citrus. In the present work isolation of flavanones from mandarin peel was performed by conventional extraction using water, ethanol, acetone and aqueous solutions of acetone and ethanol. The extracts were analysed on the content and composition of flavanones. Furthermore the DPPH radical scavenging activity of extracts was determined. Finally, the influence of extraction parameters (particle size, extraction temperature, extraction time,material to solvent ratio, number of extraction stages and type of solvent) on the yield and the efficiency of extraction were determined by Plackett-Burman experimental design. The results showed that 70% aqueous solution of acetone was the most efficient solvent for isolation of flavanones from mandarin peel. The main flavanones present in the obtained extracts were hesperidin (HES) and narirutin (NRT). The number of extraction stages influenced the yield of extraction, type of solvent influenced the hesperidin extraction efficiency and particle size of material influenced the narirutin extraction efficiency.
Keywords: conventional extraction, mandarin peel, flavanone, hesperidin, narirutin, Plackett-Bauman experimental design
Published in DKUM: 10.07.2015; Views: 1659; Downloads: 85
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10.
Thermodynamic and physical properties for high pressure process design
Maša Knez Marevci, 2014, doctoral dissertation

Abstract: The thesis is comprised of three main categories. The first part of dissertation covers investigations of phase equilibria of compounds from natural materials in conventional and also non conventional supercritical fluids. In details, the impact of pressure and/or temperature on the system behaviour (miscibility, solubility, phase inversion) is investigated, quantitative and qualitative analyses to evaluate and identify compounds contained after performing preliminary extraction experiments from different natural tissues are presented. The impact of operating parameters (pre-treatment of the raw material with SFE; different extraction solvents: propane, CO2, non conventional SCFs; different extraction temperatures and pressures) on extraction kinetics is observed. Following substances were taken into consideration: vanillins, caffeine, carnosoic acid extract and lecithin. Second part of dissertation covers studies of phase equilibria of the systems bio oil/gas, which is crucial in biorefinery process design. In this part of dissertation, which covers studies of phase equilibria of binary and ternary systems, the impact of pressure and/or temperature on the system behaviour (miscibility, solubility, phase inversion) for binary system bio oil/supercritical fluid (bio oil/CO2) and (bio oil/H2) was studied. Additionally, phase behaviour of ternary systems of (bio oil/diesel/CO2) and (bio oil/tail water/CO2) under the impact of pressure and/or temperature is observed. These data are of a high importance for bio refineries as an important part of necessary sustainable development. In recent years, studies on biodiesel synthesis have focused on development of process intensification technologies to resolve some of these issues. Fundamental data to design fractionation process of components of bio oil are crucial for an efficient hydrogenation process of bio oil. In the third part of dissertation observation of phase equilibria and determination of the parameters like diffusion coefficient, density and viscosity for the systems polymer/CO2 at elevated pressures is investigated. An overview of different methods applied to determine the parameters like diffusion coefficient, density and viscosity of the systems polymer (PEG)/CO2 at elevated pressures is offered. Observation of phase equilibria of the binary system PEG/CO2, determination of the impact of pressure and/or temperature on the system behaviour (miscibility, solubility, phase inversion), determination of thermodynamically and physically properties of the system with new applicative methods and finally, comparison of the results obtained by different methods is provided. The interfacial tension (IFT) at the (PEG)/CO2 interface has been determined by using an experimental technique developed to study the interfacial interactions of the liquids in equilibrium with gas in a glass-windowed equilibrium cell by the means of Capillary Rise (CR) method. Advantages and disadvantages of methods that were applied are exposed and discussed.
Keywords: phase equilibria, natural materials, conventional and non conventional supercritical fluids, extraction, bio oil, data for biorefinery process design, systems polymer (PEG)/CO2, diffusion coefficient, density, viscosity, surface tension, Capillary Rise (CR) method.
Published in DKUM: 28.10.2014; Views: 2968; Downloads: 420
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