1. Editorial on the special issue entitled “Towards a sustainable and recyclable future with wood and wood-based composites”Klementina Pušnik Črešnar, Olivija Plohl, 2025, other scientific articles Abstract: Water hammer phenomena in pipelines can induce significant transient pressure surges, leading to structural failures and operational inefficiencies. This study presents a comparative analyzis of two numerical approaches for simulating water hammer: a one-dimensional (1D) inviscid model with added friction based on the Euler equations and the method of characteristics, and a three-dimensional (3D) viscous model utilizing the Navier-Stokes equations in OpenFOAM. Benchmarking problems are solved first, then both methods are used to study a 3.4 km long DN400 pipeline subject to sudden pump failure by analyzing pressure surges, cavitation, and water column separation. The 1D model effectively predicts transient pressure waves and cavitation conditions with minimal computational cost, while the 3D model provides a detailed representation of multiphase flow dynamics, including cavitation bubble growth and collapse via the volume of fluid method. To mitigate adverse effects, a dynamic combination air valve is introduced, and its effectiveness in reducing pressure surges and cavitation is demonstrated. The results highlight the trade-offs between computational efficiency and accuracy in modelling water hammer events and underscore the importance of protective measures in pipeline systems. Keywords: wood-based material, renewable resources, recycling, new materials Published in DKUM: 09.12.2025; Views: 0; Downloads: 14
Full text (120,97 KB) This document has many files! More... |
2. Review of magnetic nanomaterials for the electrochemical sensing of antibioticsJosip Radić, Lidija Fras Zemljič, Sara Perša, Olivija Plohl, 2025, review article Abstract: Antimicrobial resistance (AMR) is increasing worldwide. This is due to the widespread and often uncontrolled release of antibiotics into surface water, drinking water, and the food chain. The traces of antibiotics (ng/L to μg/L) bioaccumulate, disrupt ecosystems, and accelerate AMR, yet regulatory monitoring remains inadequate. Sensitive analytical methods for the detection and quantification of antibiotics at trace levels in complex matrices are therefore essential. Conventional techniques, i.e., liquid or gas chromatography, mass spectrometry, and capillary electrophoresis, offer high accuracy but are associated with costly instrumentation, lengthy workflows, and extensive sample preparation. Electrochemical sensors based on advanced nanomaterials, particularly magnetic nanoparticles (MNPs), have attracted considerable interest due to their advantages in sensitivity and selectivity, wide linear dynamic ranges, extremely low limits of detection (LOD) and quantification (LOQ), low instrument cost, and rapid response. This review provides a critical overview of recent advances in MNP-based electrochemical platforms for antibiotic detection. The focus is on wet-chemical synthesis routes, modification approaches, and strategies for integrating magnetic nanocomposites into electrodes. Synergistic improvements through hybrid architectures are emphasized, combining MNPs with carbon nanomaterials, biopolymers, metal–organic frameworks, and molecularly imprinted polymers. Trends over the last five years have shown that applications in environmental monitoring, food safety, and drinking water are increasing. We summarize the key performance metrics, outline the current technical bottlenecks, such as long-term stability and large-scale manufacturing, and provide an outlook for the future. Taken together, these developments position MNP-based electrochemical sensors as versatile, highly effective tools for curbing antibiotic pollution and slowing the advancement of AMR. Keywords: electrochemical sensor, antibiotics̀ determination, magnetic nanomaterials, material chemistry, nanocomposites, antimicrobial resistance, food safety, environmental sensing Published in DKUM: 04.12.2025; Views: 0; Downloads: 2
Full text (3,13 MB) This document has many files! More... |
3. Sinteza in uporaba magnetnih nanodelcev, funkcionaliziranih s polisaharidom, za adsorpcijo strateških kovin : magistrsko deloLaura Furman, 2025, master's thesis Abstract: Strateške kovine, med katere spada tudi baker, predstavljajo ključne surovine v sodobni industriji, zlasti pri razvoju elektronskih in električnih naprav. Zaradi omejenih naravnih virov in naraščajočega povpraševanja postaja njihovo pridobivanje iz sekundarnih virov, kot so elektronski in električni odpadki (e-odpadki), vse pomembnejše. Ena izmed obetavnih metod na tem področju je magnetna nanohidrometalurgija (MNHM), ki združuje hidrometalurške postopke z nanotehnologijo in temelji na adsorpciji kovinskih ionov z uporabo funkcionaliziranih magnetnih nanodelcev.
V magistrskem delu smo sintetizirali magnetne nanodelce (MNPs), funkcionalizirane z λ-karagenanom (λ-CARR), naravnim polisaharidom, z namenom učinkovite adsorpcije strateških kovin iz vodnih raztopin, kjer adsorpcijska mesta predstavljajo sulfatne skupine. Kristalno strukturo nanoadsorbenta smo okarakterizirali z rentgensko praškovno difrakcijo (XRD), njegovo morfologijo in velikost pa določili s transmisijsko elektronsko mikroskopijo (TEM). Površinsko kemijo magnetnih nanodelcev, prevlečenih z λ-CARR, smo kvalitativno analizirali s Fourierjevo transformacijsko infrardečo spektroskopijo (ATR-FTIR), ter podrobneje z rentgensko fotoelektronsko spektroskopijo (XPS). Z dinamičnim sipanjem svetlobe (DLS) in meritvami ζ-potenciala smo ovrednotili velikost delcev in njihov površinski naboj. Količino vezanega polisaharida na površini nanodelcev smo določili s termogravimetrično analizo (TGA), magnetne lastnosti pa preverili z vibracijskim vzorčnim magnetometrom (VSM).
Razviti magnetni polisaharidni nanoadsorbent (MNPs@CARR) je pokazal potencial za odstranjevanje bakrovih ionov. Preučili smo vpliv različnih parametrov na adsorpcijsko učinkovitost, in sicer: maso adsorbenta, pH-vrednost raztopine, začetno koncentracijo Cu²⁺, kontaktni čas, temperaturo ter možnosti regeneracije in ponovne uporabe adsorbenta. Koncentracijo bakrovih ionov smo določali s kolorimetrično metodo s pomočjo fotometra. Kot optimalne pogoje za odstranjevanje Cu²⁺ z MNPs@CARR smo določili: γ (Cu2+) = 1,3 mg L−1, V= 20 mL, pH=6, T = 298 K, 20 mg adsorbenta, kontaktni čas=2 h, pri čemer smo dosegli 84,6 % učinkovitost odstranjevanja. Pri teh pogojih je MNPs@CARR po štirih ciklih regeneracije ohranil približno 60 % začetne adsorpcijske zmogljivosti. Rezultati nakazujejo, da je sintetiziran nanomaterial primeren za trajnostno obdelavo in predelavo strateških in kritičnih kovin (Al, Sr, B) iz sekundarnih virov, kot so tiskana vezja mobilnih telefonov. Keywords: magnetni polisaharidni nanoadsorbent, strateške kovine, baker, predelava kovin, e-odpadki, magnetna nanohidrometalurgija, trajnostno ravnanje z viri Published in DKUM: 02.10.2025; Views: 0; Downloads: 54
Full text (5,05 MB) |
4. Fragmentacija različnih polimernih materialov v tleh : magistrsko deloDalia Ladić, 2025, master's thesis Abstract: Raziskava obravnava fragmentacijo netkanih materialov PET (polietilen tereftalat), MER (melaminska epoksi smola) in viskoze, PET vlažilnih robčkov, PLA (polimlečna kislina) folije, PET in rPET (reciklirani polietilen tereftalat) folij ter HDPE (polietilen visoke gostote) in rHDPE (reciklirani polietilen visoke gostote) plastenk v kontroliranih okoljskih pogojih v tleh. Vzorci so bili izpostavljeni tlem 1, 3 in 6 mesecev ter analizirani z gravimetričnimi meritvami, optično mikroskopijo, FTIR spektroskopijo, termogravimetrično analizo (TGA) in goniometrijo za oceno hidrofilnosti/hidrofobnosti površine pred in po fragmentaciji. Rezultati kažejo, da netkani materiali v obliki vlaken, zlasti MER in PET vlakna, fragmentirajo bistveno hitreje kot folijski in embalažni materiali zaradi večje specifične površine in hidrofilnosti. Med folijami se PLA razgrajuje hitreje kot PET, rPET pa nekoliko hitreje kakor PET. Ugotovitve tega dela bistveno prispevajo k razvoju trajnostnih polimernih materialov in nadaljnjim strategijam za obvladovanje plastičnih odpadkov. Študija predstavlja pomemben prispevek k razumevanju obnašanja analizirane (bio)plastike kakor tudi razumevanju sprememb njihovih lastnosti po izpostavljenosti naravnim realnim sistemom. Keywords: Mikroplastika, fragmentacija, polimerni materiali, netkani materiali, degradacija v tleh Published in DKUM: 15.09.2025; Views: 0; Downloads: 14
Full text (4,82 MB) |
5. Metallisation of textiles and protection of conductive layers: An overview of application techniquesAlenka Ojstršek, Olivija Plohl, Selestina Gorgieva, Manja Kurečič, Urška Jančič, Silvo Hribernik, Darinka Fakin, 2021, review article Abstract: The rapid growth in wearable technology has recently stimulated the development of
conductive textiles for broad application purposes, i.e., wearable electronics, heat generators, sensors,
electromagnetic interference (EMI) shielding, optoelectronic and photonics. Textile material, which
was always considered just as the interface between the wearer and the environment, now plays
a more active role in different sectors, such as sport, healthcare, security, entertainment, military,
and technical sectors, etc. This expansion in applied development of e-textiles is governed by a
vast amount of research work conducted by increasingly interdisciplinary teams and presented
systematic review highlights and assesses, in a comprehensive manner, recent research in the field of
conductive textiles and their potential application for wearable electronics (so called e-textiles), as
well as development of advanced application techniques to obtain conductivity, with emphasis on
metal-containing coatings. Furthermore, an overview of protective compounds was provided, which
are suitable for the protection of metallized textile surfaces against corrosion, mechanical forces,
abrasion, and other external factors, influencing negatively on the adhesion and durability of the
conductive layers during textiles’ lifetime (wear and care). The challenges, drawbacks and further
opportunities in these fields are also discussed critically. Keywords: metallization, conductive textiles, e-textiles, coatings techniques, protective coatings, durability Published in DKUM: 16.06.2025; Views: 0; Downloads: 5
Full text (10,68 MB) This document has many files! More... |
6. New approach for adsorptive removal of the antibiotic ciprofloxacin: carboxymethyl-dextran-functionalised magnetic iron oxide nanomaterialsErik Mihelič, Lidija Fras Zemljič, Marjana Simonič, Sašo Gyergyek, Alenka Vesel, Silvo Hribernik, Matej Bračič, Ivan Anžel, Olivija Plohl, 2025, original scientific article Abstract: Antibiotic residues in environmental media pose a significant health, social and economic problem and require effective removal strategies. This study presents a novel approach for the removal of the antibiotic ciprofloxacin from water sources using magnetic iron oxide nanoparticles (MNPs) synthesised by co-precipitation, and subsequently functionalised with the polysaccharide carboxymethyl-dextran (CMD). The prepared nanoadsorbent was characterised extensively by various physicochemical analyses, to evaluate its morphology, crystal structure, surface chemistry, electrokinetic properties, thermogravimetric properties and magnetic features. These analyses confirmed the successful functionalisation of the MNPs with CMD highlighting its potential for effective adsorption applications. The stability of CMD coating on MNPs was evaluated in terms of total carbon content, an important, yet often overlooked factor. The adsorption performance of MNPs@CMD for ciprofloxacin was investigated systematically by studying the effects of adsorbent dosage, pH, initial ciprofloxacin concentration, ionic strength, adsorption time and kinetics, temperature, and reusability. Under optimal conditions, nanoadsorbent exhibited a satisfactory maximum adsorption capacity of 14.71 mg/g, and maintained a removal eff iciency of 79 % after four cycles, with minimal desorption of CMD layer on the MNPs. These findings demonstrate the potential of this magnetic polysaccharide nanoadsorbent for effective removal of ciprofloxacin from aqueous environments, enabling magnetic recovery and reuse. Keywords: Carboxymethyl-dextran-MNPs, ciprofloxacin, adsorption Published in DKUM: 26.05.2025; Views: 0; Downloads: 17
Full text (10,76 MB) This document has many files! More... |
7. A review of electro conductive textiles utilizing the dip-coating technique: Their functionality, durability and sustainabilityAlenka Ojstršek, Laura Jug, Olivija Plohl, 2022, review article Abstract: The presented review summarizes recent studies in the field of electro conductive textiles
as an essential part of lightweight and flexible textile-based electronics (so called e-textiles), with the
main focus on a relatively simple and low-cost dip-coating technique that can easily be integrated
into an existing textile finishing plant. Herein, numerous electro conductive compounds are discussed, including intrinsically conductive polymers, carbon-based materials, metal, and metal-based
nanomaterials, as well as their combinations, with their advantages and drawbacks in contributing
to the sectors of healthcare, military, security, fitness, entertainment, environmental, and fashion,
for applications such as energy harvesting, energy storage, real-time health and human motion
monitoring, personal thermal management, Electromagnetic Interference (EMI) shielding, wireless
communication, light emitting, tracking, etc. The greatest challenge is related to the wash and wear
durability of the conductive compounds and their unreduced performance during the textiles’ lifetimes, which includes the action of water, high temperature, detergents, mechanical forces, repeated
bending, rubbing, sweat, etc. Besides electrical conductivity, the applied compounds also influence
the physical-mechanical, optical, morphological, and comfort properties of textiles, depending on
the type and concentration of the compound, the number of applied layers, the process parameters,
as well as additional protective coatings. Finally, the sustainability and end-of-life of e-textiles are
critically discussed in terms of the circular economy and eco-design, since these aspects are mainly
neglected, although e-textile’ waste could become a huge problem in the future when their mass
production starts. Keywords: electro conductive textiles, dip-coating, characterization, functional features, durability, sustainability, recyclability Published in DKUM: 27.03.2025; Views: 0; Downloads: 9
Full text (3,34 MB) This document has many files! More... |
8. Significant fragmentation of disposable surgical masks—enormous source for problematic micro/nanoplastics pollution in the environmentAlen Erjavec, Olivija Plohl, Lidija Fras Zemljič, Julija Volmajer Valh, 2022, original scientific article Abstract: The pandemic of COVID-19 disease has brought many challenges in the field of personal
protective equipment. The amount of disposable surgical masks (DSMs) consumed increased dramatically, and much of it was improperly disposed of, i.e., it entered the environment. For this reason,
it is crucial to accurately analyze the waste and identify all the hazards it poses. Therefore, in the
present work, a DSM was disassembled, and gravimetric analysis of representative DSM waste was
performed, along with detailed infrared spectroscopy of the individual parts and in-depth analysis
of the waste. Due to the potential water contamination by micro/nanoplastics and also by other
harmful components of DSMs generated during the leaching and photodegradation process, the
xenon test and toxicity characteristic leaching procedure were used to analyze and evaluate the
leaching of micro/nanoplastics. Micro/nanoplastic particles were leached from all five components
of the mask in an aqueous medium. Exposed to natural conditions, a DSM loses up to 30% of its mass
in just 1 month, while micro/nanoplastic particles are formed by the process of photodegradation.
Improperly treated DSMs pose a potential hazardous risk to the environment due to the release of
micro/nanoparticles and chloride ion content. Keywords: DSM, micro/nanoparticles, leaching, artificial weathering, environmental pollution Published in DKUM: 26.03.2025; Views: 0; Downloads: 6
Full text (3,75 MB) This document has many files! More... |
9. First insights into the antiviral activity of chitosan-based bioactive polymers towards the bacteriophage Phi6: physicochemical characterization, inactivation potential, and inhibitory mechanismsOlivija Plohl, Katja Fric, Arijana Filipić, Polona Kogovšek, Magda Tušek-Žnidarič, Lidija Fras Zemljič, 2022, original scientific article Abstract: The outbreak of the worrisome coronavirus disease in 2019 has caused great concern
among the global public, especially regarding the need for personal protective equipment with
applied antiviral agents to reduce the spread and transmission of the virus. Thus, in our research,
chitosan-based bioactive polymers as potential antiviral agents were first evaluated as colloidal
macromolecular solutions by elemental analysis and charge. Three different types of low and high
molecular weight chitosan (LMW Ch, HMW Ch) and a LMW Ch derivative, i.e., quaternary chitosan
(quart-LMW Ch), were used. To explore their antiviral activity for subsequent use in the form of
coatings, the macromolecular Chs dispersions were incubated with the model virus phi6 (surrogate
for SARS-CoV-2), and the success of virus inactivation was determined. Inactivation of phi6 with
some chitosan-based compounds was very successful (>6 log), and the mechanisms behind this
were explored. The changes in viral morphology after incubation were observed and the changes in
infrared bands position were determined. In addition, dynamic and electrophoretic light scattering
studies were performed to better understand the interaction between Chs and phi6. The results
allowed us to better understand the antiviral mode of action of Chs agents as a function of their
physicochemical properties. Keywords: bacteriophage phi6, bioactive polysaccharide biomaterials, chitosans, antiviral activity, dynamic and electrokinetic light scattering, charge, biointerfaces Published in DKUM: 26.03.2025; Views: 0; Downloads: 5
Full text (4,27 MB) This document has many files! More... |
10. Morphological, surface and thermal properties of polylactic acid foils, melamine-etherified resin, and polyethylene terephthalate fabric during (bio)degradation in soilOlivija Plohl, Alen Erjavec, Lidija Fras Zemljič, Alenka Vesel, Maja Čolnik, Mojca Škerget, Yee Van Fan, Lidija Čuček, Gregor Trimmel, Julija Volmajer Valh, 2023, original scientific article Keywords: plastic materials, (bio)degradation, soil, surface chemistry, thermal properties, surface zeta potential Published in DKUM: 28.02.2025; Views: 0; Downloads: 12
Full text (10,81 MB) |